| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Research Progress on Capture and Conversion of Fluorinated Greenhouse Gases |
| LI Ating, ZHAO Wenbo, XU Zhiyong*
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| College of Chemical Engineering, Kunming University of Science and Technology, Kunming 650000, China |
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Abstract Fluorinated greenhouse gases (F-gases) play a critical role in the electronics and semiconductor industry as well as in refrigeration and electrical insulation applications. However, these gases typically exhibit high global warming potentials (GWPs), meaning even small emissions can cause severe long-term climatic impacts. Therefore, the capture of F-gases is essential for achieving sustainable development in the semiconductor industry. Conventional capture methods, such as cryogenic condensation and membrane separation, face challenges including low efficiency and high energy consumption. In recent years, novel porous materials, such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs), hydrogen-bonded organic frameworks (HOFs), porous organic cages (POCs) and ionic liquids (ILs) have demonstrated significant potential for F-gases capture. Additionally, catalytic conversion methods are new approaches for the subsequent treatment of F-gases. This review comprehensively summarizes recent advances in the separation, capture, and catalytic conversion technologies for F-gases. It highlights the advantages of functionalized MOFs based on pore engineering and composite material design, analyzes the mechanisms and challenges in the absorption of F-gases using fluorinated ionic liquids, and explores the potential and existing issues of catalytic conversion methods for treating F-gases.
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Published: 25 April 2026
Online: 2026-05-06
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2026, Vol. 40 
