重氮盐化学构筑量子缺陷:碳纳米管的高效共价功能化

doi:10.11896/cldb.25030181

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Abstract As one-dimensional quantum materials, single-walled carbon nanotubes (SWCNTs) exhibit unique electrical and optical properties. By introducing sp³ defects into the sp² lattice of semiconductor SWCNTs, traditionally undesirable crystal defects can be transformed into molecular focal points that modulate the coupling of electrons, excitons, phonons, and spins. These quantum defects hold significant potential for applications in room-temperature single-photon sources, near-infrared II bioimaging, and chemical sensing. However, current synthesis research is largely confined to solution-based systems, with limited exploration of synthesis on solid-state films, which are crucial for applications in optoelectronic devices, photonic systems, and quantum networks. This study focuses on three core areas: film preparation, in-situ defect synthesis on these films, and their characterization. This work utilized potassium iodide to reduce aryl diazonium salts for functionalizing and modifying SWCNTs, systematically controlling reaction time and reactant concentration to achieve consistent functionalization effects. The method is simple, fast, and efficient, requiring no additional light, electrical, or thermal conditions. The enhanced D peaks in Raman spectra and the emergence of new emission peaks in fluorescence spectra confirm the successful synthesis of quantum defects. The research successfully demonstrates the synthesis of quantum defects on films, contributing to the advancement of their applications in bioimaging, sensors, and quantum technologies.

Key words： single-walled carbon nanotubes (SWCNTs) diazo chemistry quantum defects solid-phase systems

Published: 10 March 2026 Online: 2026-03-10

CLC number:

TB383

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	ZHAO Yuqing
	YIN Taishan
	HUANG Zhongjie

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ZHAO Yuqing,YIN Taishan,HUANG Zhongjie. Quantum Defects Constructed by Diazonium Salt Chemistry: Efficient Covalent Functionalization of Carbon Nanotubes[J]. Materials Reports, 2026, 40(5): 25030181-6.

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https://www.mater-rep.com/EN/10.11896/cldb.25030181 OR https://www.mater-rep.com/EN/Y2026/V40/I5/25030181

1 Utsumi S, Ujjain S K, Takahashi S, et al. Nature Nanotechnology, 2024, 19(7), 1007.
2 Williams M G, Gao F, BenDhiab I, et al. Langmuir, 2017, 33(5), 1121.
3 Tan Y F, Hii L W, Lim W M, et al. Scientific Reports, 2024, 14(1), 30098.
4 Gifford B J, Kilina S, Htoon H, et al. Accounts of Chemical Research, 2020, 53(9), 1791.
5 Lee Y, Trocchia S M, Warren S B, et al. ACS Nano, 2018, 12(10), 9922.
6 Setaro A, Adeli M, Glaeske M, et al. Nature Communications, 2017, 8(1), 14281.
7 Mevellec J Y, Bergeret C, Cousseau J, et al. Journal of the American Chemical Society, 2011, 133(42), 16938.
8 Schirowski M, Abellán G, Nuin E, et al. Journal of the American Che-mical Society, 2018, 140(9), 3352.
9 Yu B, Naka S, Aoki H, et al. ACS Nano, 2022, 16(12), 21452.
10 Bahr J L, Yang J, Kosynkin D V, et al. Journal of the American Chemical Society, 2001, 123(27), 6536.
11 Piletsky S S, Keblish E E, Heller D A. Nano Letters, 2025, 25(6), 2480.
12 Liang H, Zhu M, Ye H, et al. Analytica Chimica Acta, 2021, 1186, 339086.
13 Zhu Z, Pan X, He Y. Polymer Chemistry, 2024, 15(8), 775.
14 Georgakilas V, Bourlinos A, Gournis D, et al. Journal of the American Chemical Society, 2008, 130(27), 8733.
15 Powell L R, Kim M, Wang Y. Journal of the American Chemical Society, 2017, 139(36), 12533.
16 Qu H, Han Y, Fortner J, et al. Journal of the American Chemical Society, 2024, 146(33), 23582.
17 Settele S, Schrage C A, Jung S, et al. Nature Communications, 2024, 15(1), 706.
18 Wang A, Ye J, Humphrey M G, et al. Advanced Materials, 2018, 30(17), 1705704.
19 He X, Htoon H, Doorn S K, et al. Nature Materials, 2018, 17(8), 663.
20 Saha A, Gifford B J, He X, et al. Nature Chemistry, 2018, 10(11), 1089.
21 Gong X, Kwak S Y, Cho S Y, et al. ACS Sensors, 2023, 8(11), 4207.
22 Li H, Sims C M, Kang R, et al. Carbon, 2023, 204, 475.
23 Li H, Gordeev G, Garrity O, et al. ACS Nano, 2019, 13(2), 2567.
24 Fagan J A, Khripin C Y, Silvera Batista C A, et al. Advanced Materials, 2014, 26(18), 2800.
25 Zheng M, Diner B A. Journal of the American Chemical Society, 2004, 126(47), 15490.
26 He X, Gao W, Xie L, et al. Nature Nanotechnology, 2016, 11(7), 633.
27 Sebastian F L, Becker F, Yomogida Y, et al. ACS Nano, 2023, 17(21), 21771.
28 Dilawar Sharma N, Singh J, Vijay A. Journal of Applied Physics, 2018, 123(15), 132.
29 Chaunchaiyakul S, Yano T, Khoklang K, et al. Carbon, 2016, 99, 642.
30 Laudenbach J, Schmid D, Herziger F, et al. Carbon, 2017, 112, 1.
31 Zhang K, Wang J, Zou J, et al. Carbon, 2018, 138, 188.
32 Kalbac M, Kavan L. Carbon, 2010, 48(3), 832.
33 Piao Y, Meany B, Powell L R, et al. Nature Chemistry, 2013, 5(10), 840.