合金中化学短程有序的研究进展

doi:10.11896/cldb.25010164

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Abstract Chemical short-range ordering (CSRO), characterized by localized deviations from random atomic arrangements in alloys, serves as a critical structural determinant that governs both microstructural evolution and macroscopic material performance. The precise manipulation of CSRO to enhance alloy properties has emerged as a central challenge in advanced materials research, particularly in medium- and high-entropy alloys (M/HEAs). This review systematically consolidates recent advances in CSRO studies, encompassing fundamental principles, theoretical mo-dels, experimental characterization techniques, and computational simulation frameworks. Emphasis is placed on elucidating the interplay between CSRO and material functionality across diverse alloy systems. Innovative strategies for tailoring CSRO to achieve performance optimization are discussed, with a focus on combinatorial design principles guided by multi-scale computational approaches. Future research directions highlight the development of refined predictive models, advanced atomic-resolution characterization methods, and machine learning-driven exploration of atomic correlations. By bridging atomic-scale ordering phenomena to macroscopic property enhancement, this review aims to provide cutting-edge insights for next-generation alloy design and engineering.

Key words： chemical short-range order (CSRO) quasi-chemical model first-principles calculations machine learning imaging and non-imaging techniques

Published: Online: 2026-02-13

CLC number:

TG139

Corresponding Authors: xiaobolilxb@163.com

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	Articles by authors
	MA Jinning
	LI Xiaobo
	OU Mingyu
	XU Wenjun

Cite this article:

MA Jinning,LI Xiaobo,OU Mingyu, et al. Research Progress on Chemical Short-Range Order in Alloys[J]. Materials Reports, 2026, 40(3): 25010164-9.

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https://www.mater-rep.com/EN/10.11896/cldb.25010164 OR https://www.mater-rep.com/EN/Y2026/V40/I3/25010164

1 Cowley J M. Physical Review, 1965, 138(5A), A1384.
2 Foroughi A, Tavakoli R. Computational Materials Science, 2020, 180, 109709.
3 Bragg W L, Williams E J. Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1934, 145(855), 699.
4 Bragg W L, Williams E J. Proceedings of the Royal Society A, 1935, 151, 540.
5 Cowley J. Physical Review, 1950, 77, 669.
6 Curtin W A, Rao Y. Acta Materialia, 2022, 226, 117621.
7 Guggenheim E A. Mixtures, Oxford University Press, UK, 1952, pp. 173.
8 Pelton A D, Degterov S A, Eriksson G, et al. Metallurgical and Materials Transactions B, 2000, 31, 651.
9 Paek M K, Jeon J, Paliwal M, et al. JOM, 2021, 73, 679.
10 Pelton A D, Chartrand P, Eriksson G. Metallurgical and Materials Transactions A, 2001, 32, 1409
11 Cui S, Wang J, Jung I H. Metallurgical and Materials Transactions A, 2022, 53(12), 4296.
12 Khanh N N. Communications in Physics, 2011, 21(3), 265.
13 Pellegatti A, Marinelli F, Mathieu J C. Journal de Physique, 1990, 51(1), 121.
14 Kotova N V, Golovata N V, Usenko N I. French-Ukrainian Journal of Chemistry, 2015, 3(2), 40.
15 Kikuchi R. Physical Review, 1951, 81(6), 988.
16 Yang C N. Journal of Chemical Physics, 1945, 13(2), 66.
17 Kikuchi R. Journal de Physique Colloques, 1977, 38 (C7), C7-307.
18 Sigli C, Sanchez J M. Acta Metallurgica, 1985, 33(6), 1097.
19 Sigli C, Sanchez J M. Acta Metallurgica, 1986, 34(6), 1021.
20 Mohri T, Sanchez J M, De Fontaine D. Acta Metallurgica, 1985, 33(7), 1171.
21 Cadeville M C, Pierron-Bohnes V, Sanchez J M, et al. Springer US, DOI:10. 1007/978-1-4613-0419-7_20.
22 Enoki M, Ohtani H. Materials Transactions , 2024, 65(9), 1025.
23 Yin B, Yoshida S, Tsuji N, et al. Nature Communications, 2020, 11(1), 2507.
24 Oates W A, Wenzl H. Scripta Materialia, 1996(5), 35.
25 Zhang F, Chang Y A, Du Y, et al. Acta Materialia, 2003, 51(1), 207.
26 Zhang J, Oates W A, Zhang F, et al. Intermetallics, 2001, 9(1), 5.
27 Zhang C, Zhu J, Bengtson A, et al. Acta Materialia, 2008, 56(19), 5796.
28 Zhang C, Zhu J, Morgan D, et al. Calphad, 2009, 33(2), 420.
29 Cao W, Zhu J, Yang Y, et al. Acta Materialia, 2005, 53(15), 4189.
30 Cao W, Chang Y A, Zhu J, et al. Intermetallics, 2007, 15(11), 1438.
31 Zhu J, Cao W, Yang Y, et al. Acta materialia, 2007, 55(13), 4545.
32 Dolezalek F. Zeitschrift für Physikalische Chemie , 1908, 64(1), 727.
33 Painter P C, Park Y, Coleman M M. Macromolecules, 1989, 22(2), 570.
34 Cui S, Wang J, You Z, et al. Intermetallics, 2020, 126, 106945.
35 Pomposo J A, Cortazar M, Calahorra E. Macromolecules, 1994, 27(1), 252.
36 Brebrick R F. Calphad, 2010, 34(4), 434.
37 Gorsse S, Hutchinson C R, Chevalier B, et al. Journal of Alloys and Compounds, 2005, 392(1-2), 253.
38 Sundman B,Chen Q, Du Y. Journal of Phase Equilibria and Diffusion, 2018, 39(5),678.
39 Jakse N, Lebacq O, Pasturel A. Physical Review Letters, 2004, 93. 207801.
40 Antonio F, Fedorov M, Jin W, et al. Entropy, 2019, 21(1), 68.
41 Bourki S, Zereg M. Russuian Journal of Physical Chemistry A, 2009, 83(13), 2195.
42 Zhu J,Zhang C,Ballard D,et al. Acta Materialia, 2009, 58(1), 180.
43 Xie Y Q, Li X B, Liu X B, et al. Transactions of Nonferrous Metals Society of China, 2015, 25(10), 2798(in Chinese).
谢佑卿, 李小波, 刘心笔, 等. 中国有色金属学报, 2015, 25(10), 2798.
44 Li X B, Xie Y Q. Acta Metallurgica Sinica, 2009, 22(4), 275(in Chinese).
李小波, 谢佑卿. 金属学报, 2009, 22(4), 275.
45 Xie Y Q, Liu X B, Li X B, et al. Transactions of Nonferrous Metals Society of China, 2015, 25(3), 885(in Chinese).
谢佑卿, 刘心笔, 李小波, 等. 中国有色金属学报, 2015, 25(3), 885.
46 Peng H J, Liu J Y, Li X B, et al. Journal of Central South University, 2023, 54(7), 2576(in Chinese).
彭红建, 刘劲远, 李小波, 等. 中南大学学报, 2023, 54(07), 2576.
47 Peng H J, Xie Y Q. Acta Metallurgica Sinica, 2008, 44(6), 764(in Chinese).
彭红建, 谢佑卿. 金属学报, 2008, 44(6), 764.
48 Jing W, Ping J, Fuping Y, et al. Nature Communications, 2022, 13(1), 1021.
49 Reinhard L, Schönfeld B, Kostorz G, et al. Physical Review B, 1990, 41(4), 1727.
50 Zhang F, Tong Y, Jin K, et al. Materials Research Letters, 2018, 6(8), 450.
51 Dubiel S M, Cieslak J. Physical Review B-Condensed Matter and Materials Physics, 2011, 83(18), 180202.
52 Gorria P, Garitaonandia J S, Barandiaran J M. Journal of Physics:Condensed Matter, 1996, 8(32), 5925.
53 Roik O S, Muratov O S, Yakovenko O M, et al. Journal of Molecular Liquids, 2014, 197, 215.
54 Zhang F X, Zhao S, Jin K, et al. Physical Review Letters, 2017, 118(20), 205501.
55 Guo W, Dmowski W, Noh J Y, et al. Metallurgical and Materials Tran-sactions A, 2013, 44, 1994
56 Wang S D, Liu X J, Lei Z F, et al. Physical Review B, 2021, 103(10), 104107.
57 Maiti S, Steurer W. Acta Materialia, 2016, 106, 87.
58 Zhang R, Zhao S, Ophus C, et al. Science Advances, 2019, 5(12), eaax2799.
59 Chen X, Wang Q, Cheng Z. et al. Nature, 2021, 592, 712.
60 Feng W, Qi Y, Wang S. Materials Research Express, 2018, 5(10), 106511.
61 Li Y, Colnaghi T, Gong Y, et al. Advanced Materials, 2024, 36(44), 2407564.
62 Lei Z, Liu X, Wu Y, et al. Nature, 2018, 563(7732), 546.
63 Moniri S, Yang Y, Ding J, et al. Nature, 2023, 624(7992), 564.
64 Moniri S, Yang Y, Yuan Y, et al. arXiv Preprint, 2023, 2305, 14123.
65 Yang Y, Yin S, Yu Q, et al. Nature Communications, 2024, 15(1), 1402.
66 Cowley J M. Journal of Applied Physics, 1950, 21(1), 24.
67 Yang T, Zhao Y L, Tong Y, et al. Science, 2018, 362(6417), 933.
68 Gault B, Schweinar K, Zhang S, et al. MRS Bulletin, 2022, 47(7), 718.
69 Li Y, Wei Y, Wang Z, et al. Nature Communications, 2023, 14(1), 7410.
70 Zhou L, Wang Q, Wang J, et al. Acta Materialia, 2022, 224, 117490.
71 Kayani S H, Park S, Kim J G, et al. Scripta Materialia, 2022, 213, 114642.
72 Tamm A, Aabloo A, Klintenberg M, et al. Acta Materialia, 2015, 99, 307.
73 Wang P, Bu Y, Liu J, et al. Materials Today, 2020, 37(5), 64.
74 Zhang Y, Stocks G M, Jin K, et al. Nature Communications, 2015, 6(1), 8736.
75 Chen S, Wang T, Li X, et al. Acta Materialia, 2022, 238, 118201.
76 Esfandiarpour A, Alvarez-Donado R, Papanikolaou S, et al. Frontiers in Materials, 2022, 9, 1046291.
77 Ding J, Yu Q, Asta M, et al. Proceedings of the National Academy of Sciences, 2018, 115(36), 8919.
78 Tamm A, Aabloo A, Klintenberg M, et al. Acta Materialia, 2015, 99, 307.
79 Sanchez J M, Ducastelle F, Gratias D. Physica A:Statistical Mechanics and Its Applications, 1984, 128(1-2), 334.
80 Daw M S, Baskes M I. Physical Review Letters, 1983, 50(17), 1285.
81 Walsh F, Asta M, Ritchie R O. Proceedings of the National Academy of Sciences, 2021, 118(13), e2020540118.
82 Gyorffy B L. Physical Review B, 1972, 5(6), 2382.
83 Soven P. Physical Review, 1967, 156(3), 809.
84 Yin S, Zuo Y, Abu-Odeh A. et al. Nature Communications, 2021, 12, 4873.
85 Shapeev A. Computational Materials Science, 2017, 139, 26.
86 Kostiuchenko T, Körmann F, Neugebauer J, et al. npj Computational Materials, 2019, 5(1), 55.
87 Shapeev A V. Multiscale Modeling & Simulation, 2016, 14(3), 1153.
88 Thompson A P, Swiler L P, Trott C R, et al. Journal of Computational Physics, 2015, 285, 316.
89 Zheng H, Fey L T W, Li X G, et al. npj Computational Materials, 2023, 9(1), 89.
90 Zhang C B, Qian C, Ye Z A, et al. Transactions of Nonferrous Metals Society of China, 2025, 35(7), 2320(in Chinese).
张楚波, 钱程, 叶子安, 等. 中国有色金属学报,2025, 35(7), 2320.
91 Weng L, Su L, Xu N, et al. Intermetallics, 2024, 165, 108132.
92 Walsh F, Asta M, Ritchie R O. Proceedings of the National Academy of Sciences, 2021, 118(13), e2020540118.
93 Chandra S, Shukla B, Srihari V, et al. Journal of Magnetism and Magnetic Materials, 2024, 610.
94 Zhao Y L, Yang T, Zhu J H, et al. Scripta Materialia, 2018, 148, 51.
95 Lei Z, Liu X, Wu Y, et al. Nature, 2018, 563(7732), 546.
96 Dasari S, Sharma A, Jiang C, et al. Proceedings of the National Academy of Sciences, 2023, 120(23), e2211787120.
97 Mo Y, Liang Y, Guo W, et al. International Journal of Plasticity, 2024, 183, 104155.
98 Zhang Z, Su Z, Zhang B, et al. Proceedings of the National Academy of Sciences, 2023, 120(15), e2218673120.
99 Su Z, Ding J, Song M, et al. Acta Materialia, 2023, 245, 118662.
100 Yang Y, Jia Z, Zhang X, et al. Materials Today, 2024, 72, 97.
101 Liu M, Aiello A, Xie Y, et al. Journal of the Electrochemical Society, 2018, 165(11), C830.