冷烧结技术在ZnO基压敏陶瓷中的应用及发展趋势

doi:10.11896/cldb.24110159

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Abstract ZnO-based varistor ceramics are extensively employed in the field of electronics, owing to their excellent nonlinear current-voltage characteristics, fast response speed and robust transient energy absorption capabilities. However, the high sintering temperature of commercial ZnO-Bi₂O₃ varistor ceramics leads to a series of problems such as the volatilization of secondary phases deviating from the designed composition, poor grain size uniformity, and high energy consumption, thereby falling to meet the requirements for high-end applications and the national strategies for energy conservation and environmental protection. The cold sintering process (CSP) technology proposed in recent years can achieve the densification of ceramic materials at no more than 350 ℃ under the synergistic effect of the intermediate liquid phase, uniaxial pressure and temperature. Currently, the cold sintering preparations of quaternary doped ZnO-based varistor ceramics and ZnO-organic composite varistor cera-mics have been achieved. This paper reviews the cold sintering process and its densification mechanism, the influence of preparation conditions on densification, and classifies and summarizes the application of cold sintering in ZnO-based varistor ceramics. Finally, the development trend of cold sintering technology in varistor devices is prospected.

Key words： cold sintering process ZnO-based varistor ceramics solubility inorganic-organic composite

Published: Online: 2025-10-27

CLC number:

TQ174

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	LI Lei
	JIA Yuxuan
	LI Guorong
	MAN Zhenyong
	ZHENG Liaoying

Cite this article:

LI Lei,JIA Yuxuan,LI Guorong, et al. Application and Future Trend of Cold Sintering Process in ZnO-based Varistor Ceramics[J]. Materials Reports, 2025, 39(20): 24110159-9.

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https://www.mater-rep.com/EN/10.11896/cldb.24110159 OR https://www.mater-rep.com/EN/Y2025/V39/I20/24110159

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