硅酸锆基包裹型无机陶瓷色料研究进展

doi:10.11896/cldb.24110027

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (20071KB)
Export: BibTeX | EndNote (RIS)

Abstract Ceramic pigmentsrefer to coloring materials used in ceramic production, which are generally prepared with encapsulating inorganic, non-metallic ceramic pigments with transparent and thermally stable zirconium silicate. Zirconium silicate-based encapsulated pigments are produced by encapsulating inorganic non-metallic colorants with transparent, thermally stable zirconium silicate, forming a uniform and stable dispersion system. This process allows the pigments to maintain vibrant hues while also possessing excellent weather resistance and chemical stability. Therefore, it is an effective strategy for producing highly colored, cost-effective, and environmentally friendly ceramic pigments. This article reviewed the encapsulation structure and coloring mechanisms of zirconium silicate-based pigments, summarized the preparation methods and color properties of different encapsulated pigments, such as C@ZrSiO₄ black pigment, CdS_xSe_1-x@ZrSiO₄ red pigment, Fe₂O₃@ZrSiO₄ red pigment, Ce₂S₃@ZrSiO₄ red pigment, TiN@ZrSiO₄ yellow pigment, and FeNbO₄@ZrSiO₄ yellow pigment. Additionally, gave a detailed introduction to the applications of zirconium silicate-based encapsulated pigments in some fields such as high-temperature ceramic glazes, solar NIR reflective tiles, ceramic inkjet printing. Finally, we prospect the future development directions.

Key words： zirconium silicate package color material ceramic inorganic chromaticity value

Published: 10 November 2025 Online: 2025-11-10

CLC number:

TQ174

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	PENG Yiyuan
	CHEN Ting
	ZHOU Haochen
	ZHAO Mengdi
	LI Youpeng
	XIE Zhixiang

Cite this article:

PENG Yiyuan,CHEN Ting,ZHOU Haochen, et al. Research Progress on Zirconium Silicate-based Encapsulated Inorganic Ceramic Colorants[J]. Materials Reports, 2025, 39(21): 24110027-6.

URL:

https://www.mater-rep.com/EN/10.11896/cldb.24110027 OR https://www.mater-rep.com/EN/Y2025/V39/I21/24110027

1 Acharjee N, Ganguly S K, Sarangi B, et al. Journal of the Australian Ceramic Society, 2023, 59(2), 303.
2 Huang G, Pan Z, Wang Y. Chemical Engineering Research and Design, 2020, 154, 86.
3 Cheng Q, Chen X, Jiang P, et al. Journal of the European Ceramic Society, 2022, 42(10), 4311.
4 Zhou W, Chen L, Zhuo S, et al. Ceramics International, 2022, 48(2), 2075.
5 Perera L, Palliyaguru L, Dhanushka L, et al. Ceramics International, 2022, 48(16), 22906.
6 Tena M, Mendoza R, Trobajo C, et al. Ceramics International, 2021, 47(21), 29888.
7 Lai F, Shi W, Hu S, et al. Ceramics International, 2023, 49(17), 28824.
8 Fortuno-Morte M, Serna-Gallén P, Beltrán-Mir H, et al. Ceramics International, 2022, 48(15), 21428.
9 Fabjan E Š, Saghi Z, Midgley P A, et al. Dyes and Pigments, 2018, 156, 108.
10 Sun Y, Yang Q, Wang H, et al. Materials Chemistry and Physics, 2018, 205, 97.
11 Zhang X, Chen T, Xu Y, et al. Journal of Sol-Gel Science and Technology, 2019, 91, 127.
12 Zhang Z C, You J L, Chen H, et al. Journal of the Chinese Ceramic Society, 2006(10), 1172(in Chinese).
张成中, 尤静林, 陈辉, 等. 硅酸盐学报, 2006(10), 1172.
13 Song K, Fan J, Li W, et al. Ceramics International, 2019, 45(17), 23444.
14 Jiang D M, Wang L J, Che X K. Preparation technology and application of zirconium oxychloride, Metallurgical Industry Press, China, 2012 (in Chinese).
蒋东民, 王力军, 车小奎. 氧氯化锆制备工艺与应用, 冶金工业出版社, 2012.
15 Chen T, Zha J, Zhang X, et al. Journal of the European Ceramic Society, 2018, 38(13), 4568.
16 Wang Q, Chang Q, Wang Y, et al. Silicon, 2018, 10, 2253.
17 Enríquez E, Reinosa J, Fuertes V, et al. Ceramics International, 2022, 48(21), 31080.
18 Peng C, Zhang C, Lv M, et al. Ceramics International, 2013, 39(6), 7247.
19 Chang Q, Wang X, Wang Y, et al. Journal of the European Ceramic Society, 2014, 34(13), 3151.
20 Jiang W H, Feng Y, Liu J M, et al. Materials Science Forum, 2013, 745, 545.
21 Chen T, Zhang X J, Xu Y Q, et al. China Ceramics, 2019, 55(12), 19 (in Chinese).
陈婷, 张筱君, 徐彦乔, 等. 中国陶瓷, 2019, 55(12), 19.
22 Lan S, Hu Q, Zhao Q, et al. Advanced Powder Technology, 2021, 32(8), 2940.
23 Zhang X J, Chen T, Jiang W H, et al. Journal of Synthetic Crystals, 2016, 45(4), 1029 (in Chinese).
张筱君, 陈婷, 江伟辉, 等. 人工晶体学报, 2016, 45(4), 1029.
24 Chen S, Cheng M, Lang Y, et al. Journal of the European Ceramic Society, 2018, 38(4), 2218.
25 Pan T, Chen T, Zhang X J, et al. Journal of Ceramics, 2016, 37(5), 525(in Chinese).
潘婷, 陈婷, 张筱君, 等. 陶瓷学报, 2016, 37(5), 525.
26 Chen T, Zhang X, Jiang W, et al. Journal of the European Ceramic Society, 2016, 36(7), 1811.
27 Chen T, Zhang X, Jiang W, et al. Advanced Powder Technology, 2020, 31(6), 2197.
28 Hosseini-Zori M, Taheri-Nassaj E, Mirhabibi A. Ceramics International, 2008, 34(3), 491.
29 Jiang W, Xu X, Chen T, et al. Dyes and Pigments, 2015, 114, 55.
30 Lv J D, Wu Q F. Bulletin of the Chinese Ceramic Society, 2017, 36(9), 3197 (in Chinese).
吕俊铎, 吴秋芳. 硅酸盐通报, 2017, 36(9), 3197.
31 Song X L, Peng L, Ding Y, et al. Journal of the Chinese Ceramic Society, 2009, 37(7), 1264 (in Chinese).
宋晓岚, 彭林, 丁意, 等. 硅酸盐学报, 2009, 37(7), 1264.
32 Song X L, Ding Y, Peng L, et al. Journal of the Chinese Ceramic Society, 2010, 38(5), 974 (in Chinese).
宋晓岚, 丁意, 彭林, 等. 硅酸盐学报, 2010, 38(5), 974.
33 Qin W, Wang K, Zhang Y. Journal of the European Ceramic Society, 2021, 41(15), 7878.
34 Chen G, Zhu Z, Liu H, et al. Journal of Rare Earths, 2013, 31(9), 891.
35 Llusar M, Calbo J, Badenes J, et al. Journal of Materials Science, 2001, 36, 153.
36 Garcıa A, Llusar M, Sorlı S, et al. Journal of the European Ceramic Society, 2003, 23(11), 1829.
37 Cannio M, Bondioli F. Journal of the European Ceramic Society, 2012, 32(3), 643.
38 Jiang W H, Yang Y H, Zhu Q X, et al. Advanced Materials Research, 2012, 412, 223.
39 Wang Y, Wang Q, Chang Q, et al. Materials Chemistry and Physics, 2019, 235, 121740.
40 Chu H L, Wang C L, Hwang W S, et al. Journal of Alloys and Compounds, 2014, 601, 307.
41 Yu Y H, Liu J L, Xiong T T. Bulletin of the Chinese Ceramic Society, 2017, 36(2), 692 (in Chinese).
喻佑华, 刘建磊, 熊甜甜. 硅酸盐通报, 2017, 36(2), 692.
42 Tang L. Preparation and properties of titanium nitride pigments encapsulated by zirconium silicate. Master’s Thesis, South China University of Technology, China, 2016 (in Chinese).
汤露. 硅酸锆包裹氮化钛色料的制备及性能研究. 硕士学位论文, 华南理工大学, 2016.
43 Piselli C, Castaldo V L, Pisello A L. Solar Energy, 2019, 192, 106.
44 Zhang Q, Yang Q, Sun Y, et al. Ceramics International, 2018, 44(11), 12621.
45 Feng G, Xie W, Jiang F, et al. Ceramics International, 2023, 49(23), 38148.
46 Tang H, Hu Q, Jiang F, et al. Ceramics International, 2019, 45(8), 10756.
47 Ullah M, Kim H J, Heo J G, et al. Journal of Ceramic Processing Research, 2019, 20, 86.
48 Zhu C, Lin W, Chen L, et al. Solar Energy Materials and Solar Cells, 2019, 199, 129.
49 Ferrari C, Muscio A, Siligardi C. Procedia Engineering, 2016, 169, 400.
50 Wu J, Li K, Xu X, et al. Materials Chemistry and Physics, 2018, 203, 193.
51 Zhang T, Wang Y, Ke S, et al. Journal of Ceramic Processing Research, 2022, 23(3), 326.
52 Cheng S, Jiang F, Feng G, et al. Ceramics International, 2023, 49(13), 22110.
53 Lei B, Qin W, Kang G, et al. Dyes and Pigments, 2015, 112, 245.