| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Application of Distribution of Relaxation Times Technique in Solid Oxide Fuel Cells |
| TAN Ting1,*, LI Chunsheng2, WANG Guanxu2, LIU Cailing2, WANG Jiarong2, YANG Zheng1,*
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1 PetroChina Shenzhen New Energy Research Institute Company Limited, Shenzhen 518000, Guangdong, China
2 CNPC Jichai Power Company Limited, Jinan 250000, China |
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Abstract Solid oxide fuel cells (SOFCs), as efficient energy storage and conversion systems, are poised to gradually change traditional energy utilization methods. However, due to the complexity of electrochemical reactions in SOFC electrodes, gaining a deep understanding of the reaction processes and analyzing degradation mechanisms remain challenging. Advanced analysis techniques are required to address this issue. The distribution of relaxation times (DRT) has recently garnered significant attention as a precise analysis tool for the electrochemical characteristics of SOFC systems. By deconvoluting electrochemical impedance spectroscopy (EIS) data, the DRT technique extracts time-scale characteristics of the electrochemical system, identifies appropriate equivalent circuits, and quantifies key physical parameters. This provides valuable guidance for selecting and optimizing electrode materials and microstructures. This review outlines the principles and analytical process of the DRT technique, while showcasing its practical applications and advantages in the separation and attribution of electrode polarization, as well as in the analysis of cell degradation in the SOFC field.
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Published:
Online: 2025-09-24
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2025, Vol. 39 
