预氧化在高性能钠离子电池用硬炭制备改性中发挥的作用

doi:10.11896/cldb.24090241

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Abstract Sodium-ion batteries have become the preferred choice for next-generation high-efficiency energy storage systems due to advantages such as excellent safety performance as well as low cost. Hard carbon, as its unique commercially available anode material with benefits such as high first efficiency and good cycling stability, is synthesized from a series of modification treatments through precursors. Among the numerous modification means, pre-oxidation treatment is an effective pretreatment strategy for the preparation of high-performance hard carbon due to its simplicity and high efficiency, including gas-phase oxidation, liquid-phase oxidation, solid-phase oxidation, and other forms. However, due to the complex molecular structures of different hard carbon precursors corresponding to different oxidation mechanisms, the unclear molecular structure evolution and its mechanism of action on the hard carbon structure hinder the design of high-performance hard carbon. In this review, we focus on the evolution of different hard carbon precursors in the process of synthesizing hard carbon through preoxidation, and discuss in detail several mechanisms of preoxidation on the structural evolution of hard carbon. And we review the role of preoxidation in the preparation and modification of hard carbon for high-performance sodium-ion batteries from the perspective of three common hard carbon precursors, namely, mineral, biomass and synthetic molecules, which provides some references to the selection of preoxidation modes of different molecular structures.

Key words： lithium/sodium ion batteries hard carbon peroxidation structural evolution

Published: Online: 2025-10-27

CLC number:

O613.71

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	Articles by authors
	HUI Gongling
	ZHANG Jinhao
	XIE Wei
	XIN Zhi
	MAO Yixuan
	CHEN Chengmeng

Cite this article:

HUI Gongling,ZHANG Jinhao,XIE Wei, et al. The Role of Pre-oxidation in the Preparation and Modification of Hard Carbon for High-performance Sodium-ion Batteries[J]. Materials Reports, 2025, 39(20): 24090241-13.

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https://www.mater-rep.com/EN/10.11896/cldb.24090241 OR https://www.mater-rep.com/EN/Y2025/V39/I20/24090241

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