POLYMERS AND POLYMER MATRIX COMPOSITES |
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Research Progress on the Application of Nano Conductive Fillers in Conductive Adhesives |
LI Ping1,2,*, NI Yanrong1,2, LI Chengbin1,2, ZHOU Ruizhe1,2, XU Sishang1
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1 School of Cable Engineering, Henan Institute of Technology, Xinxiang 453003, Henan, China 2 Henan Key Laboratory of Cable Structure and Materials, School of Cable Engineering, Henan Institute of Technology, Xinxiang 453003, Henan, China |
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Abstract Conductive adhesive, composed of a resin matrix and conductive fillers, is an advanced microelectronic component connection material. With its advantages of environmental protection, low curing temperature, and simple application process, it has been widely used in microelectronic fields such as liquid crystal panels, chip components, printed circuits, and thin-film transistors. However, the higher resistivity inherent in traditional conductive adhesives has impeded its further enhancements in performance. The incorporation of nanoscale conductive fillers with distinctive size and surface effects in the conductive adhesive can effectively reduce its resistivity and simultaneously improve its mechanical properties, thereby emerging as a pivotal technique for enhancing the performance of these adhesives. This paper deeply explores the advancements in the application of carbon-based, silver-based, conductive polymer-based and composite nano-fillers within conductive adhesives. The effects of filler types, morphologies, and surface properties on the performance of conductive adhesives were analyzed, and the mechanisms of electrical conductivity were elucidated. Furthermore, The future development direction of conductive adhesives and their fillers were proposed. These should provide theoretical guidance and practical reference for the technological innovation and industrial application of conductive adhesives.
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Published: 10 August 2025
Online: 2025-08-13
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1 Zhang F, Tang N, Jiang Q, et al. Polymer Composites, 2024, 45(7), 5781. 2 Wu Y, Li X, Yu L, et al. Resources, Conservation and Recycling, 2022, 181, 106261. 3 Ayalasomayajula M, Ravi Khurana M, Chaudhary P S. Journal of Electronic Packaging, 2024, 1. 4 Tulugan K, Zhang Y, Zhou J P, et al. Materials Letters, 2024, 365, 136431. 5 Kim M, Butler M F, Pramudya I, et al. Chemistry of Materials, 2019, 31(20), 8358. 6 Lai Y, Zhu S, Li J, et al. Journal of Industrial and Engineering Chemistry, 2023, 121, 77. 7 Sun Z, Li J, Yu M, et al. Chemical Engineering Journal, 2022, 446, 137319. 8 Pozarycki T A, Zu W, Wilcox B T, et al. Advanced Functional Materials, 2024, 2313567. 9 Yu J, Wan R, Tian F, et al. Small, 2024, 20(19), 2308778. 10 Sun Y K, Zhu Z X, Wang T, et al. Materials Reports, 2023, 37(5), 221(in Chinese). 孙怡坤, 朱召贤, 王涛, 等. 材料导报, 2023, 37(5), 221. 11 Zhang W, Liu J, Zhang L, et al. International Journal of Adhesion and Adhesives, 2022, 114, 102988. 12 Park J, Oh W, Park H, et al. Applied Surface Science, 2019, 484, 732. 13 Cheng N, Sun Z, Yu X, et al. Physical Chemistry Chemical Physics, 2023, 25(14), 10022. 14 Saleh R, Schütt S, Barth M, et al. Micromachines, 2022, 13(8), 1240. 15 Lee Sanchez W A, Li J W, Chiu H T, et al. Polymers, 2022, 14(14), 2950. 16 Wang X, Liu R, Luo J. Journal of Materials Chemistry C, 2023, 11(12), 3997. 17 Guo Z J, Lu W B, Zhang Y, et al. Ceramics International, 2023, 49(8), 12054. 18 Zhang X M, Yang X L, Wang B. International Journal of Adhesion and Adhesives, 2021, 105, 102785. 19 Pourabdoli M, Sahebi Hamrah Z, Doost Mohammadi M H, et al. International Journal of Engineering, 2021, 34(8), 1819. 20 Ji Y, Miao P, Zhang R, et al. Polymer Composites, 2022, 43(12), 8761. 21 Quan S, Gan G, lei Yu X, et al. Materials Research Express, 2024, 11(5), 055002. 22 Dou J, Tang L, Mou L, et al. Composites Science and Technology, 2020, 197, 108237. 23 Li Z, Le T R, Wu Z, et al. Advanced Functional Materials, 2015, 25(3), 464. 24 Dai D, Wang Z, Yu J, et al. ACS Applied Electronic Materials, 2023, 5(12), 6621. 25 Song B, Wang X, Patel S, et al. Soft Matter, 2020, 16(29), 6765. 26 Guo J, Su C, Liu J, et al. Polymer, 2024, 300, 126959. 27 Meschi Amoli B, Hu A, Zhou N Y, et al. Journal of Materials Science:Materials in Electronics, 2015, 26, 4730. 28 Zhao Y, Katze D, Wood J, et al. Journal of Microelectronics and Electronic Packaging, 2020, 17(1), 9. 29 Lu J, Han T, Dai J. Journal of Materials Science:Materials in Electronics, 2020, 31(17), 14601. 30 Xue W. Study on anisiotropic conductive adhesive based on modified epoxy resin. Master's Thesis, Harbin Institute of Technology, China, 2020 (in Chinese). 薛伟. 基于改性环氧树脂各向异性导电胶的研究. 硕士学位论文, 哈尔滨工业大学, 2020. 31 Tang Z, Zhao M, Li N, et al. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2022, 643, 128797. 32 Zhang W W, Liu H, Liu J H, et al. China Adhesives, 2022, 31 (10), 51 (in Chinese). 张微微, 刘昊, 刘加豪, 等. 中国胶粘剂, 2022, 31 (10), 51. 33 Zhang W, Wang J, Liu H, et al. International Journal of Adhesion and Adhesives, 2023, 122, 103300. 34 Correia D S, De Sousa R J F, Gomes P N, et al. International Journal of Adhesion and Adhesives, 2024, 103795. 35 Xu C A, Qu Z, Meng H, et al. Polymer, 2021, 223, 123615. 36 Zhang W, Liu J, Liu H, et al. ACS Applied Electronic Materials, 2022, 4(11), 5387. 37 Ma H, Li Z, Tian X, et al. Journal of Electronic Materials, 2018, 47, 2929. 38 Zhang R, Lin W, Lawrence K, et al. International Journal of Adhesion and Adhesives, 2010, 30(6), 403. 39 Zhao H, Liang T, Liu B. International Journal of Adhesion and Adhesives, 2007, 27(6), 429. 40 Chen Y, He Y, Guo J, et al. International Journal of Adhesion and Adhesives, 2023, 124, 103388. 41 Li F, Chen S, Wei Y, et al. Journal of Electronic Materials, 2016, 45, 3603. 42 Zhang J, Hao S, Shang Q, et al. Journal of Materials Science:Materials in Electronics, 2015, 26, 6266. 43 Cao G, Cui H, Wang L, et al. ACS Applied Electronic Materials, 2020, 2(9), 2750. 44 Krupa I, Cecen V, Boudenne A, et al. Materials & Design, 2013, 51, 620. 45 Ho L N, Nishikawa H. Journal of Materials Engineering and Performance, 2014, 23, 3371. 46 Derakhshankhah H, Mohammad-Rezaei R, Massoumi B, et al. Journal of Materials Science:Materials in Electronics, 2020, 31, 10947. 47 Zhang Y, Liu Y Q, Zhou J P, et al. Advanced Materials, 2023, 35(47), 2307363. 48 Yuan Y, Wu H, Li J, et al. Applied Surface Science, 2021, 570, 151220. 49 Hamrah Z S, Pourabdoli M, Lashgari V A, et al. International Journal of Adhesion and Adhesives, 2022, 114, 103114. 50 Teoh H C, Yaacob K A, Saad A A, et al. Journal of Materials Science:Materials in Electronics, 2018, 29, 9861. 51 Nasr F H, Barikani M, Salehirad M. RSC Advances, 2018, 8(54), 31094. 52 Chen C, Xue Y, Li Z, et al. Chemical Engineering Journal, 2019, 369, 1150. 53 Oh Y, Suh D, Kim Y, et al. Nanotechnology, 2008, 19(49), 495602. 54 Luo J, Cheng Z, Li C, et al. Composites Science and Technology, 2016, 129, 191. 55 Cao G, Hao C, Gao X, et al. ACS Omega, 2019, 4(2), 4169. 56 Luan V H, Tien H N, Cuong T V, et al. Journal of Materials Chemistry, 2012, 22, 8649. 57 Pu N W, Peng Y Y, Wang P C, et al. Carbon, 2014, 67, 449. 58 Yan Q, Zhou M, Fu H. Journal of Materials Chemistry C, 2020, 8(23), 7772. 59 Zhang R W, Moon K S, Lin W, et al. Journal of Materials Chemistry, 2010, 20(10), 2018. 60 Amoli B M, Gumfekar S, Hu A, et al. Journal of Materials Chemistry, 2012, 22, 20048. 61 Zhang X. Microelectronics Reliability, 2023, 142, 114917. 62 Yang M, Liu Y, Zhang D, et al. ACS Applied Polymer Materials, 2023, 5(4), 2760. 63 Chen S, Liu K, Luo Y, et al. International Journal of Adhesion & Adhesives, 2013, 45, 138. 64 Li C, Li Q, Long X, et al. ACS Applied Materials & Interfaces, 2017, 9(34), 29047. 65 Wang Q, Zhang S, Liu G, et al. Journal of Alloys and Compounds, 2020, 820, 153184. 66 Zhang C, Li C, Si X, et al. Materialia, 2020, 9, 100529. 67 Chen M, Wang C, Wei X, et al. The Journal of Physical Chemistry C, 2013, 117(26), 13593. 68 Shin J W, Lim H R, Cho H B, et al. Nanoscale, 2021, 13(18), 8442. 69 Shi Y, Fang J. The Journal of Physical Chemistry C, 2022, 126(46), 19866. 70 Tan D, Jiang C, Li Q, et al. Journal of Materials Science:Materials in Electronics, 2020, 31, 15669. 71 Peng P, Hu A, Huang H, et al. Journal of Materials Chemistry, 2012, 22(26), 12997. 72 Wu H P, Liu J F, Wu X J, et al. International Journal of Adhesion and Adhesives, 2006, 26(8), 617. 73 Zhang Z X, Chen X Y, Xiao F. Journal of Adhesion Science and Technology, 2011, 25(13), 1465. 74 Chen Y, Li Q, Li C, et al. Composites Part A:Applied Science and Manufacturing, 2020, 137, 106025. 75 Shirkawa H, Macdiamrid A G. Journal of the Chemical Society Chemical Communications, 1977, 578. 76 Nasajpour-Esfahani N, Dastan D, Alizadeh A, et al. Journal of Industrial and Engineering Chemistry, 2023, 125, 14. 77 Ouyang J. SmartMat, 2021, 2(3), 263. 78 Mir I A, Kumar D. The Journal of Adhesion, 2010, 86(4), 447. 79 Massoumi B, Farjadbeh F, Mohammadi R, et al. Journal of Composite Materials, 2013, 47(9), 1185. 80 Wen J, Tian Y, Mei Z, et al. RSC Advances, 2017, 7(84), 53219. 81 Cao G, Wang L, Tian Y. Journal of Materials Science:Materials in Electronics, 2020, 31(12), 9675. 82 Wen J, Tian Y, Hang C, et al. Nanomaterials, 2019, 9(7), 960. 83 Wen J, Tian Y, Hao C, et al. Journal of Materials Chemistry C, 2019, 7(5), 1188. 84 Cao G, Cai S, Zhang H, et al. Advanced Composites and Hybrid Materials, 2022, 5(3), 1730. 85 Marcq F, Demont P, Monfraix P, et al. Microelectronics Reliability, 2011, 51(7), 1230. 86 Jiang H, Zhou M B, Zhang X P. Journal of Electronic Materials, 2024, 53(3), 1272. 87 Cai S, Cao G, Chen Y, et al. European Polymer Journal, 2022, 181, 111698. 88 Cao G, Chen Y, Jiang C, et al. ACS Applied Electronic Materials, 2023, 5(2), 1164. 89 Ma H, Qiu H, Qi S. Journal of Adhesion Science and Technology, 2015, 29(20), 2233. 90 Lin W, Xi X, Yu C. Synthetic Metals, 2009, 159(7), 619. 91 Peighambardoust S J, Rikhtegar H, Mohammadzadeh Pakdel P, et al. Polymers for Advanced Technologies, 2019, 30(8), 1996. 92 Oh Y, Chun K Y, Lee E, et al. Journal of Materials Chemistry, 2010, 20(18), 3579. 93 Liu Y H, Li L, Ouyang X P, et al. Fine Chemicals, 2018, 35(9), 1466 (in Chinese). 刘银花, 李莉, 欧阳新平, 袁文辉. 精细化工, 2018, 35(9), 1466. 94 Cui H W, Li D S, Fan Q, et al. International Journal of Adhesion and Adhesives, 2013, 44, 232. 95 Lai H, Lu X, Chen S, et al. In:2010 International symposium on advanced packaging materials:microtech (APM). Cambridge, 2010, pp. 49. |
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