INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Research Status and Progress of Molecular Sieves Prepared by Resource Utilization of Coal Gangue Solid Waste |
LI Yaqing, SONG Hang, DENG Jun, ZHANG Yutao, LIU Qinghe*, GUO Qiang
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College of Safety Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, China |
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Abstract As a solid waste generated from coal mining, coal gangue has not been effectively utilized and thus resulted in a great waste of resources. In the dual-carbon background, resourceful utilization and higher value application of coal gangue and reducing the waste of resources have become the crucial issue for coal mines to reduce carbon emission. Consequently, the latest research on using coal gangue, which is set as the silica-aluminum based material, to prepare molecular sieve has been comprehensively summarized and analyzed. Firstly, the characteristics and potential hazards of coal gangue are introduced in detail. Secondly, the methods and influencing factors for preparation of molecular sieves using coal gangue are comprehensively summarized and analyzed. Potential applications of molecular sieves prepared from coal gangue in the fields of low carbon conversion, gas purification, heavy metal treatment and soil improvement are discussed as well. Finally, the development trend of molecular sieves prepared from coal gangue is forecasted. This paper aims to provide reference for developing more efficient preparation methods and expanding more applications of gangue-based molecular sieves.
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Published: 10 August 2025
Online: 2025-08-13
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1 Zhou J M. The study on modification and adsorption mechanism of NaA zeolite synthesized from coal gangue. Master's Thesis, Shanghai University, China, 2020 (in Chinese). 周建民. 煤矸石制备NaA分子筛的改性及其吸附机理研究. 硕士学位论文, 上海大学, 2020. 2 Huang X M, Rao J L, Du K. Mining Safety & Environmental Protection, 2023, 50(6), 92 (in Chinese). 黄学满, 饶吉来, 杜凯. 矿业安全与环保, 2023, 50(6), 92. 3 Li Q H. Applied Chemical Industry, 2023, 52(5), 1576 (in Chinese). 李启辉. 应用化工, 2023, 52(5), 1576. 4 Zhang L, Liu C J, Chen Y, et al. Mining Safety & Environmental Protection, 2025, 52(1), 160 (in Chinese). 张蕾, 刘春江, 陈雅, 等. 矿业安全与环保, 2025, 52(1), 160. 5 Li J, Wang J. Journal of Cleaner Production, 2019, 239, 117946. 6 Feng L H, Chen L F, Li Y C, et al. Multipurpose Utilization of Mineral Resources, http:∥kns.cnki.net/kcms/detail/51.1251.TD.20231120.1215.010.html (in Chinese). 冯来宏, 陈良发, 李义朝, 等. 矿产综合利用, http:∥kns.cnki.net/kcms/detail/51.1251.TD.20231120.1215.010.html.. 7 Shang H J, Zhang S H, Zhao D, et al. Chemical Industry and Engineering Progress, 2011, 30(S1), 407 (in Chinese). 尚会建, 张少红, 赵丹, 等. 化工进展, 2011, 30(S1), 407. 8 Zhou X, Shevate R, Huang D, et al. Nature Communications, 2023, 14(1), 7255. 9 Rimaz S, Kosari M, Zarinejad M, et al. Journal of Materials Science, 2022, 1. 10 Wang X Y, Niu Y X. Industrial Minerals & Processing, 2023, 52(11), 18 (in Chinese). 王小云, 牛艳霞. 化工矿物与加工, 2023, 52(11), 18. 11 Liu T. Study on heavy metal adsorption and soil improvement of coal gangue-based LTA materials. Master's Thesis, Shaanxi University of Science and Technology, China, 2023 (in Chinese). 刘甜. 煤矸石基LTA材料对水体重金属吸附和土壤改良的研究. 硕士学位论文, 陕西科技大学. 2023. 12 Zhu L, Gu W Z, He Z W, et al. Coal Science and Technology, 2025, 53(6), 104 (in Chinese). 朱磊, 古文哲, 何志伟, 等. 煤炭科学技术, 2025, 53(6), 104. 13 Zhang H L, Zhao M F, Jiang X L, et al. Acta Chimica Sinica, 2024, 82(5), 527 (in Chinese). 张华林, 赵梦飞, 江晓亮, 等. 化学学报, 2024, 82(5), 527. 14 Pane I, Hansen W. Cement and Concrete Research, 2005, 35(6), 1155. 15 Wang A G,Pan Y H,Zhao J,et al. Journal of Building Engineering ,2025,99,111526. 16 Lavrinenko A A, Svechnikova N Y, Konovnitsyna N S, et al. Solid Fuel Chemistry, 2018, 52, 406. 17 Li Y F,Liu S H,Guan X M,et al. Construction and Building Materials ,2021,301,124114. 18 Zhang L,Zhu D,Marani A. et al. Case Studies in Construction Materials,2025,23,e04930. 19 Guan H B,Yu J Y,Kibugenza,et al. Scientific Reports ,2022,12,16369. 20 Xu B,Chen J,Wang K. et al,Nanomaterials,2025,15(5),321. 21 Zhao R, Zhang X, Su Y, et al. Chemical Engineering Journal, 2020, 380, 122432. 22 Zhang X, Zhao R, Zhang N, et al. Applied Catalysis B, Environmental, 2020, 263, 118316. 23 Bian Z, Feng Y, Li H, et al. Environmental Research, 2020, 190, 109984. 24 Pu T,Li Y P,Yang X J,et al. Separation and Purification Technology,2025,377,134453. 25 Zhou J, Zheng F, Li H, et al. Chemical Engineering Journal, 2020, 381, 122698. 26 Ahmaruzzaman M. Progress in Energy and Combustion Science, 2010, 36(3), 327. 27 Lu X, Shi D, Chen J. Environmental Earth Sciences, 2017, 76, 1. 28 Xu W. Study on preparation, modification and crystal form control of coal gangue based molecular sieve. Master's Thesis. Anhui University of Science and Technology, China, 2024(in Chinese) 徐玮. 煤矸石基分子筛的制备、改性及晶型调控研究. 硕士学位论文, 安徽理工大学, 2024. 29 Přech J. Catalysis Reviews, 2018, 60(1), 71. 30 Martínez C, Corma A. Coordination Chemistry Reviews, 2011, 255(13), 1558. 31 Parsonage J. A study of the effect of Si, Al ratio and ion-exchange on the ability of the zeolite ZSM to adsorb common analgesics from waste water. Master's Thesis, University of Central Lancashire, United Kingdom, 2017. 32 Hajializadeh A, Ansari M, Foroughi M M, et al. Iranian Journal of Chemistry and Chemical Engineering, 2022, 41(2), 368. 33 Coudert F X, Kohen D. Chemistry of Materials, 2017, 29(7), 2724. 34 Chen J L, Lu X W, Zhang M M, et al. Chinese Journal of Environmental Engineering, 2014, 8(9), 3625 (in Chinese). 陈建龙, 卢新卫, 张萌萌, 等. 环境工程学报, 2014, 8(9), 3625. 35 Zhang B C, Zhang Z P, Zhao W H, et al. Coal Technology, 2023, 42(11), 252 (in Chinese). 张博超, 张洲朋, 赵文豪, 等. 煤炭技术, 2023, 42(11), 252. 36 Vilà-Nadal L, Cronin L. Nature Reviews Materials, 2017, 2(10), 1. 37 Oschatz M, Antonietti M. Energy & Environmental Science, 2018, 11(1), 57. 38 Liu T, Guo J K, Zhang L, et al. Journal of Agro-Environment Science, 2023, 42(2), 443 (in Chinese). 刘甜, 郭军康, 张蕾, 等. 农业环境科学学报, 2023, 42(2), 443. 39 Han X, Bai X Y, Liu J. Zhejiang Chemical Industry, 2023, 54(6), 33 (in Chinese). 韩旭, 白晓艳, 刘佳. 浙江化工, 2023, 54(6), 33. 40 Zhu T, Yuan B, Hao W X, et al. Clean Coal Technology, 2022, 28(1), 58 (in Chinese). 竹涛, 苑博, 郝伟翔, 等. 洁净煤技术, 2022, 28(1), 58. 41 Zheng Y, Zhou J, Ma Z, et al. Materials, 2023, 16(12), 4338. 42 Zheng Y S. Experimental study on preparation of ZSM molecular sieve from Fuxin coal gangue. Master's Thesis, Liaoning Technical University, China, 2023 (in Chinese). 郑云生. 阜新煤矸石制备ZSM分子筛试验研究. 硕士学位论文, 辽宁工程技术大学, 2023. 43 Gao J, Lin Q, Yang T, et al. Chemosphere, 2023, 341, 139741. 44 Li H P. Construction and catalytic performannce of functional ZSM composites synthesized from coal gangue. Master's Thesis, Inner Mongolia University, China, 2019 (in Chinese). 李海鹏. 基于煤矸石合成ZSM复合功能材料及催化性能研究. 硕士学位论文, 内蒙古大学, 2019. 45 Zhu M, Jin G L. Chemical World, 2003(1), 8 (in Chinese). 朱明, 金国林. 化学世界, 2003(1), 8. 46 Yan Z L, Wang X R, Li H Q, et al. Bulletin of the Chinese Ceramic Society, 2017, 36(3), 778 (in Chinese). 闫振雷, 王兴瑞, 李会泉, 等. 硅酸盐通报, 2017, 36(3), 778. 47 Ma X, Ding C, Yang H, et al. Materials, 2023, 16(11), 3896. 48 Jin S L, Cheng Y, Zhong L J. China Ceramics, 2009, 45(7), 17 (in Chinese). 金世良, 成岳, 钟立军. 中国陶瓷, 2009, 45(7), 17. 49 Wang H, Zhang Q, Song C Y. Fly Ash Comprehensive Utilization, 2001, (5), 24 (in Chinese). 王华, 张强, 宋存义. 粉煤灰综合利用, 2001, (5), 24. 50 Liang Z S, Gao Q, Liu H W, et al. Journal of Southeast University(Natural Science Edition), 2020, 50(4), 741 (in Chinese). 梁止水, 高琦, 刘豪伟, 等. 东南大学学报(自然科学版), 2020, 50(4), 741. 51 Teng T T, Lu X W. Chinese Journal of Synthetic Chemistry, 2017, 25(9), 763 (in Chinese). 滕庭庭, 卢新卫. 合成化学, 2017, 25(9), 763. 52 Wu T, Du M L, Si Y C, et al. Bulletin of the Chinese Ceramic Society, 2015, 34(5), 1348 (in Chinese). 吴涛, 杜美利, 司玉成, 等. 硅酸盐通报, 2015, 34(5), 1348. 53 Xing B, Shao H Q, Zhao X M, et al. Journal of Liaoning Normal Colleges(Natural Science Edition), 2020, 22(4), 100 (in Chinese). 邢波, 邵华全, 赵晓梅, 等. 辽宁师专学报(自然科学版), 2020, 22(4), 100. 54 Guo L, Li P, Tian H L, et al. Applied Chemical Industry, 2016, 45(9), 1726 (in Chinese). 郭丽, 李平, 田红丽, 等. 应用化工, 2016, 45(9), 1726. 55 Kong D S, Wu H, Lian M L. Bulletin of the Chinese Ceramic Society, 2019, 38(9), 2999 (in Chinese). 孔德顺, 吴红, 连明磊. 硅酸盐通报, 2019, 38(9), 2999. 56 Kong D S, Li L, Fan J X, et al. Bulletin of the Chinese Ceramic Society, 2013, 32(6), 1052 (in Chinese). 孔德顺, 李琳, 范佳鑫, 等. 硅酸盐通报, 2013, 32(6), 1052. 57 Yue H, Yu Z M, Ren Q S. Coal Technology, 2017, 36(9), 318 (in Chinese). 岳虎, 郁钟铭, 任青山. 煤炭技术, 2017, 36(9), 318. 58 Yang J L, Du M L, Yang X G, et al. China Coal, 2019, 45(12), 71 (in Chinese). 杨建利, 杜美利, 杨小刚, 等. 中国煤炭, 2019, 45(12), 71. 59 Li X, Fan W Y, Sun J L, et al. Metal Mine, 2014, 28(1), 17 (in Chinese). 李侠, 范雯阳, 孙建岭, 等. 金属矿山, 2015(11), 179. 60 Jin Y J, Wu H M, Guan J G, et al. Tianjin Chemical Industry, 2014, 28(1), 17 (in Chinese). 金玉家, 吴红梅, 管景国, 等. 天津化工, 2014, 28(1), 17. 61 Chen Y Q, Zi C M, Peng Z X, et al. Coal Chemical Industry, 2019, 47(1), 56 (in Chinese). 陈亿琴, 訾昌毓, 彭昭霞, 等. 煤化工, 2019, 47(1), 56. 62 Omisanya N O, Folayan C O, Aku S Y, et al. Advances in Applied Science Research, 2012, 3(6), 3746. 63 Yu C Z, Wang Y L, Chang S. Light Metals, 2011(8), 15 (in Chinese). 于存贞, 王延玲, 常升. 轻金属, 2011(8), 15. 64 Burton A. Catalysis Reviews, 2018, 60(1), 132. 65 Liu X, Wang Y, Cui X, et al. Powder Technology, 2013, 243, 184. 66 Ge Q L. Coal and Chemical Industry, 2023, 46(7), 110 (in Chinese). 葛启隆. 煤炭与化工, 2023, 46(7), 110. 67 Chen L. Synthesis of NaA zeolite from coal gangue and adsorption of F- and PO43- in simulated waste water. Master's Thesis, Inner Mongolia Normal University, China, 2020 (in Chinese). 陈乐. 煤矸石合成NaA沸石及对模拟含氟、含磷废水的吸附性能研究. 硕士学位论文, 内蒙古师范大学, 2020. 68 Han J, Ha Y, Guo M, et al. Ultrasonics Sonochemistry, 2019, 59, 104703. 69 Georgiadis A G, Charisiou N D, Goula M A. Catalysts, 2020, 10(5), 521. 70 Zhang G Q, Song S B, Wang X R, et al. Chemical Industry and Engineering Progress, 2024, 43(5), 2311 (in Chinese). 张国卿, 宋舒波, 王兴瑞, 等. 化工进展, 2024, 43(5), 2311. 71 Hou W X. Synthesis and catalytic performance of b-oriented ZSM zeolite/coal gangue materials with multiporous. Master's Thesis, China University of Mining and Technology, China, 2018 (in Chinese). 侯文心. b轴取向ZSM分子筛/煤矸石多孔材料的合成及其催化性能评价. 硕士学位论文, 中国矿业大学, 2018. 72 Li H P. Construction and catalytic performannce of functional ZSM composites synthesized from coal gangue. Master's Thesis, Inner Mongolia University, China, 2019 (in Chinese). 李海鹏. 基于煤矸石合成ZSM复合功能材料及催化性能研究. 硕士学位论文, 内蒙古大学, 2019. 73 Li H P, Cheng R Q, Liu Z L, et al. Science of the Total Environment, 2019, 683, 638. 74 Zhang M M. Study on the adsorption performance of X-type zeolite synthesized from coal gangue and it's Fenton catalytic performance of metal-loaded catalyst. Master's Thesis, Inner Mongolia Normal University, China, 2022 (in Chinese). 张淼森. 煤矸石合成X型沸石吸附性能及其金属负载型催化剂的芬顿催化性能研究. 硕士学位论文, 内蒙古师范大学, 2022. 75 Cui M R, Zhen Q, Bu N J. Journal of Functional Materials, 2015, 46(17), 171236 (in Chinese). 崔明日, 甄强, 布乃敬. 功能材料, 2015, 46(17), 171236. 76 Li X L, Wei Y S, Li Q C, et al. Environmental Science and Technology, 2018, 31(1), 11 (in Chinese). 李秀玲, 韦岩松, 李青翠, 等. 环境科技, 2018, 31(1), 11. 77 Liu X Y. The preparation and modification of coal gangue based porous silica materials and its application of CO2 adsorption. Master's Thesis, Inner Mongolia University of Technology, China, 2018 (in Chinese). 刘肖瑶. 煤矸石基多孔硅材料的制备、改性及吸附二氧化碳性能的研究. 硕士学位论文, 内蒙古工业大学, 2018. 78 Du H. studies on the preparation and modification of coal gangue based porous silica materials and its application of CO2 adsorption. Master's Thesis, Inner Mongolia University of Technology, China, 2019 (in Chinese). 杜宏. 煤矸石基介孔硅材料的制备、改性及吸附二氧化碳性能的研究. 硕士学位论文, 内蒙古工业大学, 2019. 79 Wu Y. Studies on preparation of coal gangue-based porous silicate nanomaterials and its adsorption of CO2. Master's Thesis, Inner Mongolia University of Technology, China, 2020 (in Chinese). 吴宇. 煤矸石基多孔硅纳米材料的制备及吸附CO2的研究. 硕士学位论文, 内蒙古工业大学, 2020. 80 Quan C, Wang F D, Guo A J, et al. Journal of China Coal Society, 2024, 49(S1), 375. (in Chinese). 全翠, 王福栋, 郭爱军, 等. 煤炭学报, 2024, 49(S1), 375. 81 Ren G K. Chinese Journal of Environmental Engineering, 2014, 8(4), 1533 (in Chinese). 任根宽. 环境工程学报, 2014, 8(4), 1533. 82 Wang Q,Jiang R L,Liu C. New Chemical Materials,2012,40(7),129(in Chinese). 王茜,蒋荣立,刘超. 化工新型材料,2012,40(7),129. 83 Chen L R, Zhang N, Du M Z, et al. Industrial Water Treatment, 2014, 34(7), 45 (in Chinese). 陈莉荣, 张娜, 杜明展, 等. 工业水处理, 2014, 34(7), 45. 84 Wang S Y, Wang X L, Zang Y. Applied Chemical Industry, 2019, 48(5), 1071 (in Chinese). 王思阳, 王晓丽, 臧晔. 应用化工, 2019, 48(5), 1071. 85 Zhang Y, Wang X L, Xia B. Journal of Inner Mongolia Normal University(Natural Science Edition), 2018, 47(3), 224 (in Chinese). 张艳, 王晓丽, 夏彬. 内蒙古师范大学学报(自然科学汉文版), 2018, 47(3), 224. 86 Chen J, Lu X. Journal of Water Reuse and Desalination, 2018, 8(1), 94. 87 Khodadadi M, Malekpour A, Ansaritabar M. Microporous and Mesoporous Materials, 2017, 248, 256. 88 Wang Q. Coal gangue synthesis 4A zeolite and its adsorption on gaseous wastewater. Master's Thesis, Shaanxi Normal University, China, 2016 (in Chinese). 王倩. 煤矸石合成4A沸石及其对含氟废水的吸附研究. 硕士学位论文, 陕西师范大学, 2016. 89 Wang X L, Zhang Y. Science of Advanced Materials, 2019, 11(2), 277. 90 Chang Z B,Yan Y N,Bai L,et al. ACS Omega,2025,9(52),51237. 91 Xiong S J, Huang X C. Contemporary Horticulture, 2017(15), 8 (in Chinese). 熊仕娟, 黄兴成. 现代园艺, 2017(15), 8. 92 Wu Z P. Energy and Energy Conservation, 2021(11), 181 (in Chinese). 吴治平. 能源与节能, 2021(11), 181. 93 Ge Q, Tian Q, Wang S, et al. Chinese Journal of Chemical Engineering, 2022, 46, 150. 94 Leggo P J, Ledésert B, Christie G. Science of the Total Environment, 2006, 363(1), 1. 95 Querol X, Alastuey A, Moreno N, et al. Chemosphere, 2006, 62(2), 171. 96 Chen Z S, Lee G J, Liu J C. Chemosphere, 2000, 41(1), 235. 97 Boisson J, Mench M, Vangronsveld J, et al. Communications in Soil Science and Plant Analysis, 1999, 30(3), 365. 98 Shi W Y,Shao H B,Li H,et al. Journal of Hazardous Materials,2009,170(1),1. 99 Trgo M, Perić J, Medvidović N V. Journal of Hazardous Materials, 2006, 136(3), 938. 100 Nissen L R, Lepp N W, Edwards R. Chemosphere, 2000, 41(1), 265. 101 Mohamed M M. Thermochimica Acta, 2001, 372(1), 75. 102 Querol X, Alastuey A, Moreno N, et al. Chemosphere, 2006, 62(2), 171. 103 Castaldi P, Santona L, Melis P. Chemosphere, 2005, 60(3), 365. 104 Yang C, Qi J S, Cui X Y, et al. Chinese Journal of Applied Chemistry, 2018, 35(4), 462 (in Chinese). 杨程, 齐金山, 崔杏雨, 等. 应用化学, 2018, 35(4), 462. 105 Zhang D M. Preparation and characterization of adsorbents for CH4/N2 adsorption separation. Master's Thesis, Taiyuan University of Techno-logy, China, 2020 (in Chinese). 张冬梅. CH4/N2分离吸附剂的制备及表征. 硕士学位论文, 太原理工大学, 2020. 106 Zhang S J. Study on the adsorption properties of NaA zeolite and the ca-talytic properties of metal-loaded catalyst. Master's Thesis, Inner Mongolia Normal University, China, 2023 (in Chinese). 张司佳. 煤矸石合成NaA型沸石的吸附性能及其金属负载型催化剂的类芬顿催化性能研究. 硕士学位论文, 内蒙古师范大学, 2023. 107 Feng K. Preparation and structural regulation of coal gangue-based zeolites and their pollutant treatment performance. Master's Thesis, Shaanxi University of Science and Technology, China, 2023 (in Chinese). 冯锴. 煤矸石基沸石的制备与结构调控及污染物处理性能研究. 硕士学位论文, 陕西科技大学, 2023. 108 Qian T, Li J. Advanced Powder Technology, 2015, 26(1), 98. 109 Murukutti M K, Jena H. Journal of Hazardous Materials, 2022, 423, 127085. 110 Park D H, Kim S S, Wang H, et al. Angewandte Chemie, 2009, 121(41), 7781. 111 Liang D S. Study of the crystalline mechanism of LTA and FAU zeolites with UV-Raman spectroscopy. Master's Thesis, Jilin University, China, 2008 (in Chinese). 梁德声. 利用紫外拉曼光谱研究LTA和FAU分子筛晶化机理. 硕士学位论文, 吉林大学, 2008. 112 Zhou H, Wang X L, Tian F. Applied Chemical Industry, 2021, 50(5), 1382 (in Chinese). 周慧, 王晓丽, 田芳. 应用化工, 2021, 50(5), 1382. |
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