METALS AND METAL MATRIX COMPOSITES |
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Research Progress of Co-free Eutectic High Entropy Alloys |
XUE Yunlong1,*, TIAN Kangkang1, LIU Hulin1, WU Yuanting1, YUAN Liang2, GAO Zhongtang3
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1 Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science and Technology, Xi’an 710021, China 2 College of Light Industry Science and Engineering, Shaanxi University of Science and Technology, Xi’an 710021, China 3 College of Mechanical Engineering, Xi’an University of Science and Technology, Xi’an 710054, China |
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Abstract Eutectic high entropy alloys have received wide attention because of their good comprehensive mechanical properties and casting processability, but the existing eutectic high entropy alloys usually contain the rare precious metal Co, which leads to high cost of the alloys and is not conducive to the strategic security and stable development of the country due to Co being a globally strategically scarce resource. Therefore, it is of great theoretical significance and application value to develop Co-free eutectic high entropy alloys. Based on the current research status of Co-free eutectic high entropy alloys, this paper introduces the composition design method of such alloys, focuses on FCC+enhanced-phase alloy system, BCC+enhanced-phase alloy system and other alloy systems, and analyzes in depth the design ideas, microstructure and mechanical pro-perties of the different alloy systems, and explores the problems and development trend of such materials, and finally proposes references for the development and application of Co-free eutectic high entropy alloys. This paper may provide reference for the development and application of Co-free eutectic high entropy alloys.
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Published:
Online: 2025-05-29
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1 Yeh J W, Chen S K, Lin S J, et al. Advanced Engineering Materials, 2004, 6(5), 299. 2 Lu Y, Dong Y, Guo S, et al. Scientific Reports, 2014, 4(1), 6200. 3 Xu T T, Lu Y P, Cao Z Q, et al. Journal of Materials Engineering and Performance, 2019, 28(12), 7642. 4 Qiu Y X, Zhang A J, Xin B B, et al. Tribology, 2023, 43(12), 1381 (in Chinese). 邱玉新, 张爱军, 辛本斌, 等. 摩擦学学报, 2023, 43(12), 1381. 5 Zuo G. Natural Resource Economics of China, 2023, 36(9), 4 (in Chinese). 左更. 中国国土资源经济, 2023, 36(9), 4. 6 Li Y W, Chang K K, Wang P S, et al. Materials Science and Engineering of Powder Metallurgy, 2012, 17(1), 1 (in Chinese). 李一为, 常可可, 王培生, 等. 粉末冶金材料科学与工程, 2012, 17(1), 1. 7 Wu M X, Wang S B, Huang H J, et al. Materials Letters, 2020, 262, 127175. 8 Talluri G, Murty B S, Maurya R S. Scripta Materialia, 2024, 249, 116178. 9 Lu Y P, Jiang H, Guo S, et al. Intermetallics, 2017, 91, 124. 10 Ye X C, Xiong J Y, Wu X, et al. Scripta Materialia, 2021, 199, 113886. 11 Ye X C, Lei H F, Liu X W, et al. Materials Letters, 2023, 343, 134395. 12 Jiang H, Han K M, Gao X X, et al. Materials & Design, 2018, 142, 101. 13 Jiao W N, Miao J, Lu Y, et al. Journal of Alloys and Compounds, 2023, 941, 168975. 14 Chanda B, Das J. Journal of Alloys and Compounds, 2019, 798, 167. 15 Huang W, Martin P, Zhuang H L. Acta Materialia, 2019, 169, 225. 16 Xue J T, Huang J T, Liu G T, et al. Vacuum, 2024, 225, 113290. 17 Jin X, Bi J, Zhang L, et al. Journal of Alloys and Compounds, 2019, 770, 655. 18 Liang D S, Wei C X, Ren F Z. Materials Science and Engineering:A, 2021, 806, 140611. 19 Lu Y, Zhang M D, Zhang L J, et al. Materials Science and Engineering:A, 2021, 801, 140421. 20 Lu Y. Study on microstructure and mechanical properties of Co-free CrFeNiNbx multi-principal alloy. Master’s Thesis, Yanshan University China, 2021 (in Chinese). 卢烨. CrFeNiNbx无Co多主元合金组织结构与力学性能研究. 硕士学位论文, 燕山大学, 2021. 21 Song J F, Chai Z S, Zheng J, et al. Acta Metallurgica Sinica (English Letters), 2021, 34(8), 1103. 22 Lee W H, Oh Y J, Jo M G, et al. Journal of Alloys and Compounds, 2021, 860, 158502. 23 Ye F Y, Yang J, Sun P J, et al. Chinese Journal of Lasers, 2023, 50(20), 112 (in Chinese). 叶馥宇, 杨键, 孙潘杰, 等. 中国激光, 2023, 50(20), 112. 24 Yu L E, Ye X C, Fang D, et al. Journal of Materials Research and Technology, 2022, 21, 3207. 25 Li Z, Liu C, Wang L, et al. Materials Characterization, 2023, 203, 113120. 26 Liang X Y, Chen J, Yao Y H, et al. Materials Letters, 2023, 337, 133952. 27 Ye X C, Wu X, Wang T, et al. Transactions of Materials and Heat Treatment, 2022, 43(9), 68 (in Chinese). 叶喜葱, 吴鑫, 王童, 等. 材料热处理学报, 2022, 43(9), 68. 28 Jiang Z F, Chen W P, Xia Z B, et al. Intermetallics, 2019, 108, 45. 29 Wang M Z, Wen Z Q, Liu J X, et al. Journal of Alloys and Compounds, 2022, 918, 165441. 30 Jiao W N, Li T X, Chang X X, et al. Journal of Alloys and Compounds, 2022, 902, 163814. 31 Yao C L. Composition design and microstructure research of NiAl based eutectic high-entropy alloys. Master’s Thesis, Xi’an University of Technology, China, 2021 (in Chinese). 姚成利. NiAl基共晶高熵合金的成分设计与微观组织研究. 硕士学位论文, 西安理工大学, 2021. 32 Wang L, Su Y N, Yao C L, et al. Intermetallics, 2022, 143, 107476. 33 Xue Y L, Wang Y X, Sun H H, et al. Metals and Materials International, 2023, 29(2), 564. 34 Wei Q Q, Xu X D, Shen Q, et al. Science, 2022, 8(27), 2068. 35 Wu M X, Wang S B, Xiao F, et al. Materials Science and Engineering:A, 2022, 842, 143112. 36 Wang M L, Lu Y P, Lan J G, et al. Acta Materialia, 2023, 248, 118806. 37 Hu M C, Du Y, Pei X H, et al. Tribology, 2024, 44 (5), 609 (in Chinese). 胡明川, 杜银, 裴旭辉, 等. 摩擦学学报, 2024, 44 (5), 609. 38 Chen B, Li X, Chen W, et al. Intermetallics, 2023, 155, 107829. 39 Xue Y L, Wang Y X, Sun H H, et al. The Chinese Journal of Nonferrous Metals, 2022, 32(10), 2999 (in Chinese). 薛云龙, 王玉轩, 孙浩华, 等. 中国有色金属学报, 2022, 32(10), 2999. 40 Yuan J P, Yang Y J, Duan S G, et al. Materials, 2023, 16(1), 56. 41 Li S Y. Microstructure evolution and properties of Al-Cr-Fe-Ni-M eutectic high-entropy alloys. Master’s Thesis, Shandong University of Technology, China, 2022 (in Chinese). 李肖逸. Al-Cr-Fe-Ni-M系共晶高熵合金组织演化及性能研究. 硕士学位论文, 山东理工大学, 2022. 42 Guo Y X, Shang X J, Liu Q B. Chinese Journal of Rare Metals, 2018, 42(8), 807 (in Chinese). 郭亚雄, 尚晓娟, 刘其斌. 稀有金属, 2018, 42(8), 807. 43 Yang B T, Ma L L, Zhao P P. Materials Science and Engineering:A, 2023, 863, 144524. 44 Jiao W N. Composition design and mechanical properties of CrFeNiMo(V) eutectic high entropy alloy. Master’s Thesis, Dalian University of Technology, China, 2019 (in Chinese). 焦文娜. CrFeNiMo(V)系共晶高熵合金的成分设计与力学性能研究. 硕士学位论文, 大连理工大学, 2019. 45 Liang W Z, Wu W D, Chen Y S, et al. Journal of Heilongjiang University of Science and Technology, 2021, 31(3), 373(in Chinese). 梁维中, 吴万东, 陈永生, 等. 黑龙江科技大学学报, 2021, 31(3), 373. 46 Ye X C, Cheng Z H, Liu C, et al. Materials Science and Engineering:A, 2022, 841, 143026. 47 Fang D, Wu X, Xu W Q, et al. Materials Science and Engineering:A, 2023, 870, 144919. 48 Wu W D. Study on microstructure and mechanical properties of CrFenNiMoNb-Y/Er eutectic high entropy alloys. Master’s Thesis, Heilongjiang University of Science and Technology, China, 2022 (in Chinese). 吴万东. CrFeNiMoNb-Y/Er共晶高熵合金微观组织与力学性能研究. 硕士学位论文, 黑龙江科技大学, 2022. 49 Luo S C. Composition design and fundamental research on selective laser melting of AlCrCuFeNix high entropy alloys. Ph. D. Thesis, Huazhong University of Science and Technology, China, 2021 (in Chinese). 骆顺存. AlCrCuFeNix高熵合金的成分设计及激光选区熔化成形基础研究. 博士学位论文, 华中科技大学, 2021. 50 Tri D V, Tieu A K, Wexler D, et al. Journal of Alloys and Compounds, 2022, 928, 167087. 51 Wang Y B, Li S Y, Chen F D, et al. Journal of Alloys and Compounds, 2023, 958, 170373. 52 Miao J W, Wang M L, Zhang A J, et al. Acta Metallurgica Sinica, 2023, 59(2), 267 (in Chinese). 苗军伟, 王明亮, 张爱军, 等. 金属学报, 2023, 59(2), 267. 53 Cheng X. Study on microstructures and properties of AlxCrFeNi quaternary component alloys. Master’s Thesis, China University of Mining and Technology, China, 2017 (in Chinese). 陈霄. AlxCrFeNi四组元合金的微观组织与性能研究. 硕士学位论文, 中国矿业大学, 2017. 54 Xiao Y K, Chang X D, Peng X H. Journal of Materials Research and Technology, 2022, 21, 4908. 55 Zhang X B. Study on BCC/B2 phase coherent precipitation of AlxCrFey Ni high entropy alloy. Master’s Thesis, North University of China, China, 2023 (in Chinese). 张小波. AlxCrFeyNi系高熵合金BCC/B2相共格析出研究. 硕士学位论文, 中北大学, 2023. 56 Fang D, Zhang A, Luo A J, et al. Special Casting & Nonferrous Alloys, 2024, 44(1), 30 (in Chinese). 方东, 张安, 罗爱娇, 等. 特种铸造及有色合金, 2024, 44(1), 30. 57 Xu Z, Li Q Y, Li W, et al. Wear, 2023, 522, 204701. 58 Wang H M, Du Y, Pei X H, et al. Acta Metallurgica Sinica, 2024, 60 (7), 937 (in Chinese). 王瀚铭, 杜银, 裴旭辉, 等. 金属学报, 2024, 60 (7), 937. 59 Zhu M, Yao L J, Liu Y Q, et al. Materials Letters, 2020, 272, 127869. 60 Xu Q, Wang Q, Li J, et al. Special Casting & Nonferrous Alloys, 2022, 42(3), 292 (in Chinese). 徐琴, 王琪, 李娟, 等. 特种铸造及有色合金, 2022, 42(3), 292. 61 Li H. Microstructure and mechanical properties of directionally solidified Ti30Ni30Fe10Hf10Nbx high-entropy alloy. Master’s Thesis, University of Science and Technology of China, China, 2021 (in Chinese). 李欢. 定向凝固Ti30Ni30Fe10Hf10Nbx高熵合金的微观结构及力学性能研究. 硕士学位论文, 2022. 62 Bai K W, Wu Z K, Lin M, et al. Acta Materialia, 2023, 243, 118512. 63 Ou W, Yuan X, Li Z, et al. Surfaces and Interfaces, 2023, 40, 103068. 64 Xu Q, Chen D Z, Wang C R, et al. Transactions of Nonferrous Metals Society of China, 2021, 31(2), 512. 65 Xu Z M. Study on the microstructure and properties of WVTaCrxTiy refractory high entropy alloy coating prepared laser cladding. Master’s Thesis, Qilu University of Technology, China, 2023 (in Chinese). 许兆敏. 激光熔覆WVTaCrxTiy难熔高熵合金涂层组织与性能研究. 硕士学位论文, 齐鲁工业大学, 2023. 66 Kuang S H. Laser cladding of BCC-based eutectic high-entropy alloy coa-tings. Master’s Thesis, Guizhou University, China, 2021 (in Chinese). 匡世华. 激光熔覆BCC基共晶高熵合金涂层研究. 硕士学位论文, 贵州大学, 2021. 67 Lee C P, Chang C C, Chen Y Y, et al. Corrosion Science, 2008, 50(7), 2053. 68 Zhu J M, Fu H M, Zhang H F, et al. Materials Science & Engineering:A, 2010, 527, 7210. |
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