金属卤化物钙钛矿材料自掺杂研究进展

doi:10.11896/cldb.24020097

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Abstract In recent years, numerous research has demonstrated that self-doping enables precise modulation of the conductivity type (p-type or n-type) in organic-inorganic metal halide perovskite materials, leading to improved light absorption and charge carrier transport, ultimately resulting in enhanced power conversion efficiency of solar cells. Furthermore, the sequential deposition of perovskite layers with different doping types has facilitated the development of novel bilayer perovskite homojunction/heterojunction (P-P junction) solar cells. When compared to conventional pe-rovskite solar cells, P-P junction solar cells exhibit an additional built-in electric field within the photoactive layer, which efficiently promotes the transmission of carrier, effectively reducing non-radiative recombination. Additionally, the inherent bipolar charge transport characteristics of perovskite materials allow them to function as both electron and hole transport layers. Consequently, the introduction of P-P junctions obviates the need for separate transport layers, thereby optimizing device architecture and simplifying fabrication processes. These advancements provide a promising direction for the further development of perovskite solar cells. This paper focuses on organic-inorganic metal halide perovskite materials, providing detailed insights into the methods employed to regulate self-doping types. It also comprehensively reviews the applications of self-doped perovskites in solar cells, elucidates the physical mechanisms and influencing factors associated with self-doped P-P junction solar cells, and concludes with a summary and outlook on the current technological challenges and future prospects in this field.

Key words： perovskite self-doping P(N)-type perovskite P-P heterostructure (homojunction)

Published: 10 April 2025 Online: 2025-04-10

CLC number:

TK514

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	Articles by authors
	CHEN Xu
	LIAO Jing
	TAN Li
	LI Haijin

Cite this article:

CHEN Xu,LIAO Jing,TAN Li, et al. Research Progress of Self-doping in Metal Halide Perovskite Materials[J]. Materials Reports, 2025, 39(7): 24020097-9.

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https://www.mater-rep.com/EN/10.11896/cldb.24020097 OR https://www.mater-rep.com/EN/Y2025/V39/I7/24020097

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