POLYMERS AND POLYMER MATRIX COMPOSITE |
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Preparation and Properties of SiO2 Mineralized Chinese Fir Composite Induced by Phenylalanine Derivatives |
DENG Zebin, LIU Jing, LAI Shenghui, LIU Da, HUANG Jinzhuo, YUAN Guangming*
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College of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China |
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Abstract Based on the principle of biomineralization, the phenylalanine derivatives serve as a template and inducer and graft it onto Chinese fir cell wall, combined with sol-gel method, inducing the ordered deposition and regulating crystalline morphology of polyhydroxy-SiO2, thereby achieving synergetic effect of enhancing the wood mechanical performance. In result, the way of inducing SiO2 mineralization of Chinese fir by phenylalanine derivatives can be divided into chemical combination (cell wall) and physical deposition (cell lumen), among them, chemical combination is that the organic film of rich in mineralization site formed through the combination of phenylalanine derivatives and Chinese fir, which can induce the nucleation, crystallization, and ordered deposition, eventually generated rod-shaped SiO2. Rod-shaped SiO2 supports effectively wood structure and diffuse the external force.The longitudinal compressive strength, bending strength, elastic modulus, compressive weight ratio and bending strength to weight ratio are 49.76 MPa, 65.14 MPa, 8 010.83 MPa, 1 777.14 N·m/kg, and 2 326.43 N·m/kg, respectively. Compared with the blank group, the values of fir increased by 54.29%, 27.20%, 20.16%, 32.26% and 9.03%, respectively.
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Published: 25 February 2025
Online: 2025-02-18
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