二氧化碳电催化还原酸性体系研究进展

doi:10.11896/cldb.23040216

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Abstract Electrocatalytic conversion of CO₂ into high-value chemicals and fuels by renewable energy provides a viable approach to the global climate change and energy crisis, and its development has great potential for practical production. At present, most of the basic and neutral reaction systems studied, CO₂ is liable to interact with hydroxide (OH^-) to form carbonate or bicarbonate, resulting in CO₂ loss, lowering the energy conversion efficiency and stability of the reaction system. The above problems will be solved by the research and development of electrocatalytic CO₂ reduction reaction (CO₂RR) in acid. This review has shed light on the effects of reaction device, catalyst, reaction microenvironment on the performance of CO₂RR and the microscopic reaction mechanism systematically in acidic CO₂RR. Finally, foresight tactics are put forward for catalyst design, reaction mechanism research, reaction microenvironment regulation, and reactor design and optimization in acidic CO₂RR.

Key words： carbon dioxide electrocatalysis reduction acidic electrolytes

Published: 25 April 2024 Online: 2024-04-28

CLC number:

O646

Fund:National Natural Science Foundation of China (22022201) and the Science and Technology Projects of Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (RD2020020201).

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	Articles by authors
	SUN Yazhou
	XU Sha
	ZOU Jinhan
	WU Zhihua
	XIE Shunji

Cite this article:

SUN Yazhou,XU Sha,ZOU Jinhan, et al. Recent Developments in the Electrocatalytic Reduction of CO₂ in Acidic Environments[J]. Materials Reports, 2024, 38(8): 23040216-6.

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https://www.mater-rep.com/EN/10.11896/cldb.23040216 OR https://www.mater-rep.com/EN/Y2024/V38/I8/23040216

1 Zhang X, Zhang Z, Li H, et al. Advanced Energy Materials, 2022, 12(39), 2201461.
2 He M, Sun Y, Han B. Angewandte Chemie International Edition, 2022, 61(15), e202112835.
3 Xie S, Ma W, Wu X, et al. Energy & Environmental Science, 2021, 14(1), 37.
4 Lai W, Qiao Y, Zhang J, et al. Energy & Environmental Science, 2022, 15(9), 3603.
5 Ma W, He X, Wang W, et al. Chemical Society Reviews, 2021, 50(23), 12897.
6 Overa S, Ko B H, Zhao Y, et al. Accounts of Chemical Research, 2022, 55(5), 638.
7 Lees E W, Mowbray B A W, Parlane F G L, et al. Nature Reviews Materials, 2021, 7(1), 55.
8 Zhao Y, Zu X, Chen R, et al. Journal of the American Chemical Society, 2022, 144(23), 10446.
9 Vennekoetter J B, Sengpiel R, Wessling M. Chemical Engineering Journal, 2019, 364, 89.
10 Gabardo C M, O’Brien C P, Edwards J P, et al. Joule, 2019, 3(11), 2777.
11 Ooka H, Figueiredo M C, Koper M T M. Langmuir, 2017, 33(37), 9307.
12 Li J, Kornienko N. Chem Catalysis, 2022, 2(1), 29.
13 Hao Q, Liu D X, Zhong H X, et al. Chem Catalysis, DOI: 10.1016/j.checat.2023.100542.
14 Liu S, Yang H, Su X, et al. Journal of Energy Chemistry, 2019, 36, 95.
15 Monteiro M C O, Dattila F, Lopez N, et al. Journal of the American Chemical Society, 2022, 144(4), 1589.
16 Meng D L, Zhang M D, Si D H, et al. Angewandte Chemie International Edition, 2021, 60(48), 25485.
17 Huang J E, Li F W, Ozden A, et al. Science, 2021, 372(6546), 1074.
18 Li H, Li H, Wei P, et al. Energy & Environmental Science, DOI: 10.1039/d2ee03482d.
19 Bagger A, Ju W, Varela A S, et al. Chemphyschem, 2017, 18(22), 3266.
20 Jin S, Hao Z, Zhang K, et al. Angewandte Chemie International Edition, 2021, 60(38), 20627.
21 Ma X, Sun F, Qin L, et al. Chemical Science, 2022, 13(34), 10149.
22 Chen Q, Liu K, Zhou Y, et al. Nano Letters, 2022, 22(15), 6276.
23 Liu W, Bai P, Wei S, et al. Angewandte Chemie International Edition, 2022, 61(18), e202201166.
24 Ko Y J, Kim J Y, Lee W H, et al. Nature Communications, 2022, 13(1), 2205.
25 Guo X, Xu S M, Zhou H, et al. ACS Catalysis, 2022, 12(17), 10551.
26 Zhang J, Fan T, Huang P, et al. Advanced Functional Materials, 2022, 32(25), 2113075.
27 Ma W, Xie S, Zhang X G, et al. Nature Communications, 2019, 10(1), 892.
28 Nitopi S, Bertheussen E, Scott S B, et al. Chemical Reviews, 2019, 119(12), 7610.
29 Zhou Y, Che F, Liu M, et al. Nature Chemistry, 2018, 10(9), 974.
30 Jiang K, Sandberg R B, Akey A J, et al. Nature Catalysis, 2018, 1(2), 111.
31 Zheng T, Zhang M, Wu L, et al. Nature Catalysis, 2022, 5, 388.
32 Liu Z, Yan T, Shi H, et al. ACS Applied Materials & Interfaces, 2022, 14(6), 7900.
33 Bondue C J, Graf M, Goyal A, et al. Journal of the American Chemical Society, 2021, 143(1), 279.
34 Sheng X, Ge W, Jiang H, et al. Advanced Materials, 2022, 34(38), e2201295.
35 Pan B, Fan J, Zhang J, et al. ACS Energy Letters, 2022, 7(12), 4224.
36 Boutin E, Merakeb L, Ma B, et al. Chemical Society Reviews, 2020, 49(16), 5772.
37 Meshitsuka S, Ichikawa M, Tamaru K. Journal of the Chemical Society, Chemical Communications, 1974,(5), 158.
38 Lieber C M, Lewis N S. Journal of the American Chemical Society, 1984, 106(17), 5033.
39 Schneider J, Jia H, Muckerman J T, et al. Chemical Society Reviews, 2012, 41(6), 2036.
40 Han N, Wang Y, Ma L, et al. Chem, 2017, 3(4), 652.
41 Liu Y, McCrory C C L. Nature Communications, 2019, 10(1), 1683.
42 Jiang Z, Zhang Z, Li H, et al. Advanced Energy Materials, 2022, 13(6), 2203603.
43 Kortlever R, Balemans C, Kwon Y, et al. Catalysis Today, 2015, 244, 58.
44 Wang Y, Wang C, Wei Y, et al. Chemistry-A European Journal, 2022, 28(58), e202201832.
45 Qiao Y, Lai W, Huang K, et al. ACS Catalysis, 2022, 12(4), 2357.
46 Li L, Liu Z, Yu X, et al. Angewandte Chemie International Edition, DOI: 10.1002/ange.202300226.
47 Chen X Y, Chen J F, Alghoraibi N M, et al. Nature Catalysis, 2021, 4(1), 20.
48 Gu J, Liu S, Ni W, et al. Nature Catalysis, 2022, 5(4), 268.
49 Xie Y, Ou P, Wang X, et al. Nature Catalysis, 2022, 5(6), 564.
50 Zhao Y, Hao L, Ozden A, et al. Nature Synthesis, DOI: 10.1038/s44160-022-00234-x.
51 Nie W, Heim G P, Watkins N B, et al. Angewandte Chemie Internatio-nal Edition, 2023, 62(12), e202216102.
52 Zhang J, Guo C, Fang S, et al. Nature Communications, 2023, 14, 1298.
53 Cao Y, Chen Z, Li P, et al. Nature Communications, 2023, 14, 2387.
54 Cobb S J, Badiani V M, Dharani A M, et al. Nature Chemistry, 2022, 14(4), 417.