| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Principle, Process and Prospect of Monocrystalline Silicon Growth with Czochralski Method |
| WANG Zhengxing1, REN Yongsheng1,2,*, MA Wenhui1,*, LYU Guoqiang1, ZENG Yi1, ZHAN Shu3, CHEN Hui2, WANG Zhe4
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1 Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
2 Department of Materials Engineering, The University of Tokyo, Tokyo 113-8656, Japan
3 School of Computer and Information, Hefei University of Technology, Hefei 230601, China
4 State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083, China |
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Abstract With the introduction of the concept of peak carbon dioxide emission and carbon neutrality, solar energy as a renewable green energy has attracted much attention. Monocrystalline silicon is main photovoltaic material, and its quality determines the efficiency of solar cells. High-quality monocrystal silicon is required to reduce costs and increase production capacity. Czochralski (CZ) method is main preparation method for monocrystalline silicon, with high production efficiency and automation. The market share of CZ-Si exceeds 90%. At present, it is developing toward large size, N-type, flake, low oxygen, and low carbon. However, as the size of crystal rod increases, the thermal field changes become more complex, and the existing CZ process is difficult to meet the market demand. In the future, reducing the cost of kilowatt-hour electricity is still the driving force for the development of crystalline silicon photovoltaic, and the development of photovoltaic should be promoted through technological innovation, industrial standardization, cost control, and other means. In this paper, the basic principle and growth process of monocrystalline silicon using CZ are first summarized. Defect control, thermal field optimization, and oxygen content control are analyzed. Finally, the process and future prospects of developing monocrystalline silicon using CZ are presented.
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Published: 10 May 2024
Online: 2024-05-13
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| Fund:Major Science and Technology Projects in Yunnan Province (202103AA080010, 202102AB080016), the Youth Fund of the National Natural Science Foundation of China (52104303), the joint project of Yunnan Provincial Department of Science and Technology and Kunming University of Science and Technology to create “double first-class”-general project (202201BE070001-045), the Yunnan Joint Fund of the National Natural Science Foundation of China (U1702251) and the Open Fund of the State Key Laboratory of Advanced Metallurgy of University of Science and Technology Beijing(KK21-07). |
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2024, Vol. 38 
