锂离子电池钒系电极材料的研究进展

doi:10.11896/cldb.20060110

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Abstract To improve the performance of lithium ion batteries, the electrode materials are a key point. Vanadium has rich variable valence state, and the vanadium-based electrode materials are under a variety of structures with layered-structure, spinel and anti-spinel structure. Vanadium-based electrode materials have the properties of higher theoretical specific capacity, various synthesis methods and cost-effective. The application of vanadium-based compounds have attracted extensive attention in lithium ion battery electrode materials. However, it is still lack of a systematic summary of vanadium-based electrode materials. This paper reviews the structure and electrochemical performance of promising electrode mate-rials for lithium ion batteries of vanadium-based electrode materials, which mainly include vanadium oxide, lithium-free vanadate, lithium-containing vanadate and lithium vanadium phosphate. Methods for synthesis of vanadium-based electrode materials are summarized, including solid phase synthesis, sol-gel synthesis, hydrothermal synthesis, carbothermal reduction synthesis, and liquid phase precipitation synthesis. The methods to optimize the defects of vanadium electrode materials by controlling of nano-crystallization, morphology and composite are also concluded. Finally, an outlook on potential breakthroughs for vanadium-based electrode materials will be provided.

Key words： lithium vanadium compound lithium-ion battery cathode material anode material

Published: 30 November 2021

CLC number:

TM912

Fund:Key Project of Sichuan Vanadium and Titanium Industry Development Research Center (2018VTCY-Z-01), the Major Project of Sichuan Provincial Department of Education (18ZA0062), and the Science and Technology Department Project of Sichuan Province (2019ZDZX0025).

About author:: Hao Wang received his B.E. degree in material forming and control engineering from the Engineering & Technical College of Chengdu University of Technology in 2018. He is currently pursuing his master's degree at the College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, and under the supervision of professor Junfeng Li. His research has focused on amorphous cathode materials for lithium-ion batteries.
Junfeng Li received his B.E. degree in inorganic nonmetallic materials from Sichuan University in 2000. He received his M.E. degree in materials from Chengdu University of Technology in 2005, and received his Ph.D. degree in biomedical engineering from Sichuan University in 2009. He is currently a full professor in Chengdu University of Technology. He is mainly engaged in research work related to the development and application of new materials. His research interests include rare earth luminescence and catalytic materials, lithium ion battery electrode materials, bone repair materials. In recent years, he has published 100 scientific research papers and applied for 30 national invention patents.

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	WANG Hao
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Cite this article:

WANG Hao,LI Junfeng,MA Yue, et al. Review of Vanadium-based Electrode Materials for Lithium Ion Batteries[J]. Materials Reports, 2021, 35(21): 21127-21142.

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http://www.mater-rep.com/EN/10.11896/cldb.20060110 OR http://www.mater-rep.com/EN/Y2021/V35/I21/21127

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