Please wait a minute...
材料导报  2026, Vol. 40 Issue (7): 25040217-8    https://doi.org/10.11896/cldb.25040217
  无机非金属及其复合材料 |
电解锰渣资源综合利用研究现状及展望
肖星宇1, 何德军1,2,*, 陈梦君1, 刘恢2
1 西南科技大学环境与资源学院,四川 绵阳 621010
2 中南大学冶金与环境学院,长沙 410083
Research Status and Prospects on Comprehensive Utilization of Electrolytic Manganese Residue
XIAO Xingyu1, HE Dejun1,2,*, CHEN Mengjun1, LIU Hui2
1 School of Environment and Resource, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China
2 School of Metallurgy and Environment, Central South University, Changsha 410083, China
下载:  全 文 ( PDF ) ( 6284KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 电解锰渣产生量大,综合利用率低,其大宗资源化利用是制约电解锰行业可持续绿色发展的关键难题。目前,电解锰渣的资源综合利用主要集中在低端建材产品方面,产品附加值低。随着建材市场的萎靡,电解锰渣资源化逐渐向多元化和高附加值方向转型。本文系统梳理了电解锰渣的特征及危害,从电解锰渣排放及利用、综合利用相关法规政策和标准三方面总结了电解锰渣综合利用基本现状,重点概述了电解锰渣在有价资源综合回收、制备玻璃陶瓷-陶粒、制备建筑与路用材料、用于生态修复及其他方面国内外最新研究进展,总结了电解锰渣综合利用存在的问题,并针对性地提出了建议,指出有价资源的高效回收、制备高附加值大宗建材产品、生态环境修复、类土壤生态回归等是未来电解锰渣综合利用的重要发展方向。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
肖星宇
何德军
陈梦君
刘恢
关键词:  电解锰渣  资源回收  综合利用  高附加值  生态修复    
Abstract: Electrolytic manganese residue (EMR) poses significant challenges, including a large production volume and a low comprehensive utilization rate. The bulk resource utilization of EMR is a key issue that constrains the sustainable and green development of the electrolytic manganese industry. Currently, the comprehensive resource utilization of EMR primarily focuses on low-end building materials, which offer low added value. In light of the downturn in the building materials market, the resource utilization of EMR is gradually shifting towards diversification and the production of high value-added products. This paper systematically reviews the characteristics and hazards of EMR, summarizes the current status of its comprehensive utilization from three perspectives: the emission and utilization of EMR, relevant regulations, policies, and standards for comprehensive utilization, and highlights the latest research progress, both domestically and internationally, regarding the comprehensive recovery of valuable resources from EMR, the preparation of glass ceramics-ceramsite, the development of building and road materials, and its applications in ecological restoration and other areas. The issues surrounding the comprehensive utilization of EMR are summarized, and targeted suggestions are provided. It is emphasized that the efficient recovery of valuable resources, the synthesis of high value-added bulk building materials, ecological environment restoration and the transformation of EMR into soil-like materials for ecological reuse are crucial development directions for the future comprehensive utilization of EMR.
Key words:  electrolytic manganese residue    resource recovery    comprehensive utilization    high value-added    ecological restoration
发布日期:  2026-04-16
ZTFLH:  X75  
基金资助: 国家自然科学基金(52404432); 国家资助博士后研究人员计划(GZC20233147)
通讯作者:  *何德军,博士,广西大学资源环境与材料学院副教授、硕士研究生导师。目前主要从事工业固体废物无害化和资源化利用、工业固体废物制备新型胶凝材料等方面的研究。whuthdj@163.com   
作者简介:  肖星宇,西南科技大学环境与资源学院硕士研究生,在陈梦君教授、何德军副教授的联合指导下进行工业固体废物无害化与资源化技术研究。目前主要研究领域为电解锰渣建材资源化。
引用本文:    
肖星宇, 何德军, 陈梦君, 刘恢. 电解锰渣资源综合利用研究现状及展望[J]. 材料导报, 2026, 40(7): 25040217-8.
XIAO Xingyu, HE Dejun, CHEN Mengjun, LIU Hui. Research Status and Prospects on Comprehensive Utilization of Electrolytic Manganese Residue. Materials Reports, 2026, 40(7): 25040217-8.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25040217  或          https://www.mater-rep.com/CN/Y2026/V40/I7/25040217
1 He D, Chen M, Liu H, et al. Construction and Building Materials, 2024, 425, 135990.
2 Yang T, Xue Y, Liu X, et al. Process Safety and Environmental Protection, 2022, 157, 509.
3 Zuo Z, Tao Y, Yang J, et al. Construction and Building Materials, 2025, 463, 140081.
4 He D, Shu J, Wang R, et al. Journal of Hazardous Materials, 2021, 418, 126235.
5 He S, Jiang D, Hong M, et al. Journal of Cleaner Production, 2021, 306, 127224.
6 Gao H, He L, Yue B, et al. Journal of Safety and Environment, 2024, 24(1), 280(in Chinese).
高红, 何莉莉, 岳波, 等. 安全与环境学报, 2024, 24(1), 280.
7 Fu Y, Qiao H, Feng Q, et al. Construction and Building Materials, 2023, 401, 132901.
8 Deng Y, Shu J, Chen M, et al. Chemical Industry and Engineering Progress, 2022, 41(4), 2161(in Chinese).
邓亚玲, 舒建成, 陈梦君, 等. 化工进展, 2022, 41(4), 2161.
9 Wang J, Ma J, Bai J, et al. China Manganese Industry, 2022, 40(1), 1(in Chinese).
汪军, 马洁晨, 柏继松, 等. 中国锰业, 2022, 40(1), 1.
10 Wang J, Hu W, Li D, et al. Northern Horticulture, 2019(17), 72.
王加真, 胡万明, 李大勇, 等. 北方园艺, 2019(17), 72(in Chinese).
11 Fu X, Xiao X, Tan D, et al. Environmental Science & Technology, 2024, 47(3), 179(in Chinese).
付晓辛, 肖雪, 谭道永, 等. 环境科学与技术, 2024, 47(3), 179.
12 Shen H. China Manganese Industry, 2007, 25(2), 46(in Chinese).
沈华. 中国锰业, 2007, 25(2), 46.
13 Lan J, Sun Y, Guo L, et al. Journal of Alloys and Compounds, 2019, 811, 151973.
14 Shu J, Chen M, Wu H, et al. Journal of Hazardous Materials, 2019, 376, 212.
15 Wang D, Wang Q, Xue J. Resources, Conservation & Recycling, 2020, 154, 104645.
16 Fang M. Research on recovery process of soluble manganese and ammonium sulfate from electrolytic manganese slag. Master’s Thesis, Guangxi University, China, 2014(in Chinese).
房苜茹. 电解锰渣中可溶锰和硫酸铵回收工艺研究. 硕士学位论文, 广西大学, 2014.
17 Li X, Li X, Yang J, et al. Journal of Hazardous Materials, 2024, 472, 134430.
18 Wen Q, Liu B, Zhang J, et al. Separation and Purification Technology, 2024, 332, 125648.
19 Zhang H, Fang S, Fu J, et al. Bulletin of the Chinese Ceramic Society, 2023, 42(6), 2071(in Chinese).
张欢欢, 方双明, 付娟, 等. 硅酸盐通报, 2023, 42(6), 2071.
20 Chang J, Srinivasakannan C, Sun X, et al. Green Process Synth, 2020, 9(1), 2.
21 Zhao Z, Wang R, Shu J, et al. Minerals Engineering, 2022, 189, 107862.
22 Lan J, Sun Y, Chen X, et al. Bioresource Technology, 2021, 319, 124056.
23 Luo J, Peng Z, Zhang J, et al. Journal of Environmental Chemical Engineering, 2025, 13(2), 115427.
24 Sun C, Zhang Y, Yang Y, et al. Journal of Water Process Engineering, 2024, 63, 105405.
25 Xiang H, Yang Z, Liu S, et al. ACS ES&T Engineering, 2023, 3(10), 13.
26 Sun N, Chen X, Zhang Y. Hydrometallurgy of China, 2024, 43(1), 39(in Chinese).
孙宁宁, 陈喜平, 张雅琪. 湿法冶金, 2024, 43(1), 39.
27 Shu J, Lin F, Chen M, et al. Hydrometallurgy, 2020, 193, 105311.
28 Zhou Y, Wu S, Liu R, et al. Journal of Water Process Engineering, 2022, 45, 102532.
29 Li X, Zhou M, Chen F, et al. ACS Sustainable Chemistry & Engineering, 2021, 9(24), 8069.
30 Rao S, Sun J, Wang D, et al. Separation and Purification Technology, 2023, 308, 122937.
31 Song M, Zhang J, Li Y, et al. Environmental Science & Technology, 2019, 42(8), 31(in Chinese).
宋谋胜, 张杰, 李勇, 等. 环境科学与技术, 2019, 42(8), 31.
32 Zhang J, Li R, Nie D, et al. Ceramics International, 2023, 49(13), 22492.
33 Ran L, Liu S, Lan L. Non-metallic Mines, 2020, 43(2), 92(in Chinese).
冉岚, 刘少友, 兰琳琳. 非金属矿, 2020, 43(2), 92-94.
34 Ye F, Cheng H, Xu L, et al. Norganic Chemicals Industry, 2018, 50(10), 62(in Chinese).
叶芬, 成昊, 徐丽, 等. 无机盐工业, 2018, 50(10), 62.
35 Wang J, Han F, Yang B, et al. Frontiers in Chemistry, 2022, 10, 989087.
36 Ke X, Chen X, Wang T, et al. Journal of Environmental Chemical Engineering, 2024, 12(2), 112419.
37 Liang Q, Xue F, Huang X, et al. Inorganic Chemicals Industry, 2025, 57(8), 102(in Chinese).
梁庆阳, 薛菲, 黄绪泉, 等. 无机盐工业, 2025, 57(8), 102.
38 Yang Z, Lu X, Wang J, et al. Materials (Basel), 2025, 18(2), 368.
39 Zhan X, Wang L, Wang J, et al. Waste Management, 2022, 153, 264.
40 Ye D, Xu Z, Zhao Y, et al. Materials Reports, 2022, 36(11), 89(in Chinese).
叶东东, 徐子芳, 赵怡梵, 等. 材料导报, 2022, 36(11), 89.
41 Wang J, Long G, Dong R, et al. Journal of Railway Science and Engineering, 2023, 20(4), 1382(in Chinese).
王继林, 龙广成, 董荣珍, 等. 铁道科学与工程学报, 2023, 20(4), 1382.
42 Yu C, Duan N, Cui K. Sintering and Pelletizing, 2025, 50(1), 126(in Chinese).
鱼彩红, 段楠, 崔葵馨. 烧结球团, 2025, 50(1), 126.
43 Zhan S, Han F, Wang Y. Bulletin of the Chinese Ceramic Society, 2017, 36(5), 1766(in Chinese).
赵世珍, 韩凤兰, 王亚光. 硅酸盐通报, 2017, 36(5), 1766.
44 He W, Li R, Zhang Y, et al. Construction and Building Materials, 2022, 326, 126672.
45 Li C, Xu Y, Zhu W, et al. Nonferrous Metals (smelting part), 2025(5), 136(in Chinese).
李成, 许晔, 朱文云, 等. 有色金属(冶炼部分), 2025(5), 136.
46 Zhang X, Liu F, Zhu J, et al. Bulletin of the Chinese Ceramic Society, 2021, 40(5), 1610(in Chinese).
张歆, 刘方, 朱健, 等. 硅酸盐通报, 2021, 40(5), 1610.
47 Tian Y, Luo Q, Feng Q, et al. Journal of Building Engineering, 2024, 94, 109974.
48 Li Q, Liu Q, Peng B, et al. Construction and Building Materials, 2016, 106, 236.
49 Sun M, Li J, Lyu Y, et al. Bulletin of the Chinese Ceramic Society, 2019, 38(12), 3746(in Chinese).
孙朋, 李佳欣, 吕莹, 等. 硅酸盐通报, 2019, 38(12), 3746.
50 Zhang X, Gao Y, Wang P, et al. Bulletin of the Chinese Ceramic Society, 2023, 42(4), 1363(in Chinese).
张先伟, 高永红, 王平, 等. 硅酸盐通报, 2023, 42(4), 1363.
51 Yang H, Wang J, Wang H, et al. Non-metallic Mines, 2019, 42(3), 13(in Chinese).
杨洪友, 王家伟, 王海峰, 等. 非金属矿, 2019, 42(3), 13.
52 Song M, Zhang J, Yang H, et al. New Building Materials, 2019, 46(9), 133(in Chinese).
宋谋胜, 张杰, 杨欢, 等. 新型建筑材料, 2019, 46(9), 133.
53 Zhang X. Modification and performance study of fly ash manganese slag geopolymer grouting material. Master’s Thesis, Anhui University of Science and Technology, China, 2024(in Chinese).
张翔. 粉煤灰复配电解锰渣制备地质聚合物的改性及耐久性能研究. 硕士学位论文, 安徽理工大学, 2024.
54 Tan B, Liu Q, Chen P. Journal of Wuhan University of Technology, 2021, 43(8), 51(in Chinese).
谭波, 刘琦, 陈平. 武汉理工大学学报, 2021, 43(8), 51.
55 Li Y, Fang Q, Guo Y, et al. Water Resources Planning and Design, 2021(12), 85(in Chinese).
李宇, 方琴, 郭玉兰, 等. 水利规划与设计, 2021(12), 85.
56 Bai M, Long G, Xie Y, et al. Bulletin of the Chinese Ceramic Society, 2022, 44(10), 3533(in Chinese).
白敏, 龙广成, 谢友均, 等. 硅酸盐通报, 2022, 44(10), 3533.
57 Lan J, Sun Y, Tian H, et al. Journal of Hazardous Materials, 2021, 411, 124941.
58 Zeng T, Xue S, Zhuang S, et al. Journal of Hazardous Materials, 2024, 482, 136560.
59 Ha Z, Ma M, Tan X, et al. Environmental Research, 2023, 234, 116607.
60 Ma M, Ha Z, Xu X, et al. Science of the Total Environment, 2023, 894, 164730.
61 Chen T, He B, Chu D, et al. Journal of Environmental Management, 2024, 370, 122601.
62 Shi S, Huang P. Water Purification Technology, 2023, 42(5), 102(in Chinese).
施沙军, 黄萍. 净水技术, 2023, 42(5), 102.
63 Li J, Ke X, Wei H, et al. Separation and Purification Technology, 2024, 332, 125778.
64 Shen H, Luo M, Wang J, et al. Chemical Engineering Journal, 2023, 472, 144915.
65 Li W, Jin H, Xie H, et al. Journal of Industrial and Engineering Che-mistry, 2023, 120, 147.
66 Li C, Zhong H, Wang S, et al. Journal of Industrial and Engineering Chemistry, 2015, 23, 344.
67 Li M, He Z, Zhong H, et al. Water Research, 2021, 200, 117266.
68 Shi Z, Zhao X, Wang Z, et al. Journal of Environmental Management, 2023, 326(Part B), 116793.
69 Zhong C, Cai X, Liu Y, et al. Journal of Cleaner Production, 2024, 436, 140504.
70 Nie Z, Li C, Tian S, et al. Separation and Purification Technology, 2022, 281, 119988.
71 Li X, Li X, Ma X, et al. Science of the Total Environment, 2024, 954, 176711.
72 Yang X, Zhu J, Liu F, et al. Inorganic Chemicals Industry, 2020, 52(9), 73(in Chinese).
杨曦, 朱健, 刘方, 等. 无机盐工业, 2020, 52(9), 73.
73 Han L, Yu Y, Xu Z, et al. Journal of Cleaner Production, 2024, 435, 140416.
[1] 王长龙, 付兴帅, 杨彩霞, 张凯帆, 白云翼, 路璐, 高占须, 郑永超, 刘治兵, 翟玉新, 刘枫. 钒钛铁尾矿制备矿山修复混凝土及性能研究[J]. 材料导报, 2025, 39(14): 24050044-6.
[2] 许丹, 于彩莲, 李芬, 杨莹, 李博琳, 芦柳, 蔺宇晨. CO2还原光催化材料研究进展[J]. 材料导报, 2024, 38(14): 23030280-8.
[3] 孙志辉, 赵帅. “双碳”背景下煤矸石高附加值功能化改性技术现状与展望[J]. 材料导报, 2023, 37(S1): 23040034-10.
[4] 李松琦, 曲家福, 胡俊蝶, 杨晓刚, 李长明. 光热催化二氧化碳还原合成高附加值化学品的研究进展[J]. 材料导报, 2023, 37(22): 22050159-8.
[5] 张峻, 解维闵, 董雄波, 杨华明. 磷石膏材料化综合利用研究进展[J]. 材料导报, 2023, 37(16): 22010110-12.
[6] 李亮星, 朱志城, 贾孟熹, 黄茜琳. 硬质合金废料电解回收钨及W(Ⅵ)在熔盐中的电化学行为[J]. 材料导报, 2022, 36(Z1): 22010043-6.
[7] 叶东东, 徐子芳, 赵怡梵, 俞欣欣, 傅宇豪. 电解锰渣陶粒共烧结温度影响机理研究[J]. 材料导报, 2022, 36(11): 21120242-6.
[8] 黄洋, 叶义成, 胡南燕, 王为琪, 张杰. 磷尾矿材料化综合利用途径研究进展[J]. 材料导报, 2021, 35(z2): 279-284.
[9] 苏博文, 史公初, 廖亚龙, 张宇, 王伟, 郗家俊. 工业固体废弃物制备二氧化硅功能材料的研究进展[J]. 材料导报, 2021, 35(3): 3026-3032.
[10] 赵立杰, 张芳. 钢渣资源综合利用及发展前景展望[J]. 材料导报, 2020, 34(Z2): 319-322.
[11] 曲涛, 谷旭鹏, 施磊, 罗铭洋, 王强, 吕飞, 田源, 戴永年. 高镁硅红土镍矿开发利用研究现状[J]. 材料导报, 2020, 34(Z1): 261-267.
[12] 刘文博, 姚华彦, 王静峰, 陈传明, 刘玉亭. 铁尾矿资源化综合利用现状[J]. 材料导报, 2020, 34(Z1): 268-270.
[13] 贾敏, 杨磊. 粉煤灰盐酸法提铝后残渣的综合利用研究[J]. 材料导报, 2020, 34(Z1): 277-279.
[14] 胡贵生, 章超, 钱晨阳, 文建新. 钼尾矿资源综合利用最新研究进展概述[J]. 材料导报, 2019, 33(Z2): 233-238.
[15] 贺东风, 潘江涛, 曾凡博. 中钛型含钛高炉渣制微晶玻璃及其性能研究*[J]. 《材料导报》期刊社, 2017, 31(2): 126-129.
[1] WANG Xu, HE Xin, XIE Zhipeng, ZHANG Da, HOU Shengping, WU Yue, DONG Peng, CHEN Jiale, LIANG Feng. Application of Low Temperature Plasma in the Anode Preparation and Modification of Sodium Ion Battery[J]. Materials Reports, 2026, 40(6): 25040155 -11 .
[2] HE Geping, FU Zeguo, YANG Quan, BAO Chenhao, XU Rui, LI Mengxuan, JING Gege, GOU Wenhao. Preparation and Properties of Supercapacitor Electrode Material ZnWO4@rGO Based on Polyvinylpyrrolidone Surfactant[J]. Materials Reports, 2026, 40(6): 25040062 -8 .
[3] GAO Chenyu, WANG Yan, ZHANG Shaohui, LI Aoyang, WU Jie, HUO Yuren, LU Guannan. Modification of Waste Carbon Fiber Prepreg by Debonder and Its Effect on the Mechanical Properties and Electrical Conductivity of Concrete[J]. Materials Reports, 2026, 40(6): 25050007 -11 .
[4] LI Yibo, ZHANG Ling, LIANG Zhixia, ZHANG Donghai. Research Progress on the Expansion Performance and Char Strength of Intumescent Fire-retardant Coatings[J]. Materials Reports, 2026, 40(6): 25040263 -12 .
[5] MEI Shengqi, LIU Xiaodong, WANG Xingju, LI Xufeng, NIE Liangtao, KANG Xuejian. Fused Machine Learning Modeling of Concrete Creep with Strength Classification[J]. Materials Reports, 2026, 40(7): 24100121 -8 .
[6] ZHANG Zeming, HUANG Cunsheng, DANG Dongying, ZHANG Dewei, WANG Chuansheng. Study on the Properties of BF/EPDM Composites Modified with Sodium Carboxymethyl Cellulose[J]. Materials Reports, 2026, 40(7): 24120160 -6 .
[7] PENG Huijing, ZHANG Weimin, LI Qianming, XING Xinlong, FAN Jing. Preparation of Alkaline Titanate Material K-Ti and Its Adsorption Properties for Mn(Ⅱ)[J]. Materials Reports, 2026, 40(7): 24120197 -7 .
[8] WU Lang, PENG Lilin, WANG Zele, LI Hao, LEI Bin. Chemical Shrinkage Model and Prediction for Early-age Slag-Cement Binder Systems[J]. Materials Reports, 2026, 40(7): 25010012 -7 .
[9] PANG Xueyu, CHENG Guodong, HUANG Xianbin, BAI Yingrui, GAO Zhi, HAO Borong, LYU Kaihe, SUN Jinsheng. The Performance and Mechanisms of High-temperature Retrogression Resistance in Fly Ash and Slag-Modified Well Cementing Systems[J]. Materials Reports, 2026, 40(7): 25010110 -7 .
[10] WANG Deteng, YANG Huiyong, YU Haijiang, WANG Luyan, WANG Lianyi, LUO Ruiying, HUANG Juntong. Research Status and Prospective of Zirconium Silicate[J]. Materials Reports, 2026, 40(7): 25010149 -14 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed