导电(Cu,Mn)3O4接触层在SOEC阳极侧的应用

doi:10.11896/cldb.23040278

材料导报

2024, Vol. 38

Issue (8): 23040278-4 https://doi.org/10.11896/cldb.23040278

电化学能源材料与器件

导电(Cu,Mn)₃O₄接触层在SOEC阳极侧的应用

黄旭锐¹, 余喻天^2,*, 雷金勇¹, 郝敬轩², 俞传鑫^2,3, 潘军¹, 杨怡萍¹, 廖梓豪¹, 关成志², 王建强²

1 广东电网有限责任公司广州供电局,广州 510600
2 中国科学院上海应用物理研究所,上海 201800
3 东华大学环境科学与工程学院,上海 201620

Application of Electrically-conductive (Cu, Mn)₃O₄ Contact Layer on Anode-Side of SOEC

HUANG Xurui¹, YU Yutian^2,*, LEI Jinyong¹, HAO Jingxuan², YU Chuanxin^2,3, PAN Jun¹, YANG Yiping¹, LIAO Zihao¹, GUAN Chengzhi², WANG Jianqiang²

1 Guangzhou Power Supply Bureau, Guangdong Power Grid Co., Ltd., Guangzhou 510600, China
2 Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
3 College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China

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摘要固体氧化物电解池(SOEC)中铁素体不锈钢合金连接体和电解池阳极之间存在界面接触、连接体表面氧化以及氧电极“铬毒化”等问题,是导致电解堆性能衰减的重要影响因素之一。本工作利用反应烧结工艺在连接体与阳极之间制备了多孔的(Cu,Mn)₃O₄导电接触层,形成了粘结强度高的连接体/接触层/电解池界面结构。所得试样在750 ℃下表现出优异的电性能,整个500 h测试过程半电池的面比电阻(ASR)值稳定保持在20.13～20.32 mΩ·cm²。通过微观结构表征技术证实,多孔(Cu,Mn)₃O₄接触层与相邻的电解堆部件具有良好的兼容性,并可以抑制连接体表面的氧化薄膜增长,同时阻止铬元素的迁移。(Cu,Mn)₃O₄接触层也降低了电解池与集流体之间的接触电阻,提高了电池电化学输出性能。

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	黄旭锐
	余喻天
	雷金勇
	郝敬轩
	俞传鑫
	潘军
	杨怡萍
	廖梓豪
	关成志
	王建强

关键词: 固体氧化物电解池阳极接触层 (Cu,Mn)₃O₄尖晶石反应烧结面比电阻(ASR)

Abstract: In SOEC stack, several issues including high contact resistance, oxidation of interconnect surface as well as anode‘ Cr poisoning’ exist between the interconnect and anode, which can significantly result in performance degradation for the stack. In this study, the (Cu, Mn)₃O₄-based spinel was evaluated as the SOEC anode-side contact material. A mixture of Mn and CuO was thermally converted into the spinel layer to lower the sintering temperature and enhance the performance. A simulated interconnect/contact/anode cell was fabricated to investigate the effectiveness of the reactively-sintered contact layer on the electrical performance and chemical compatibility. The tested cell exhibited extremely stable behavior with an ASR of only 20.13—20.32 mΩ·cm². While the Cr-rich oxide scale was effectively reduced, no obvious interdiffusion was observed between the contact layer and adjacent cell component at each interface. The (Cu, Mn)₃O₄ contact layer improved the electrochemical performance of the test cell, significantly reduced the contact resistance.

Key words: solid oxide electrolysis cell anode-side contact layer (Cu,Mn)₃O₄ spinel reactive sintering area-specific resistance (ASR)

出版日期: 2024-04-25 发布日期: 2024-04-28

ZTFLH:

TK91

基金资助: 南方电网公司科技项目(GZHKJXM20190109);中国科学院洁净能源先导科技专项(XDA210000);中国科学院青年创新促进会基金(E129051031)

通讯作者: *余喻天,中国科学院上海应用物理研究所工程师。2014年南昌航空大学机械系本科毕业,2020年美国田纳西理工大学博士毕业后到中国科学院上海应用物理研究所工作至今。目前主要从事高温固体氧化物电解池等方面的研究工作。发表论文十余篇,包括International Journal of Hydrogen、Journal of the Eelectrochemical Society、Solid State Ionics、Coatings、FuelCells等。yuyutian@sinap.ac.cn

作者简介: 黄旭锐,工程师。2013年华南理工大学电气工程及其自动化专业本科毕业,2016年华中科技大学电气工程专业硕士毕业后到广东电网有限责任公司广州供电局工作至今。目前主要从事电氢耦合系统、综合能源等方面的研究工作。

引用本文:

黄旭锐, 余喻天, 雷金勇, 郝敬轩, 俞传鑫, 潘军, 杨怡萍, 廖梓豪, 关成志, 王建强. 导电(Cu,Mn)₃O₄接触层在SOEC阳极侧的应用[J]. 材料导报, 2024, 38(8): 23040278-4.
HUANG Xurui, YU Yutian, LEI Jinyong, HAO Jingxuan, YU Chuanxin, PAN Jun, YANG Yiping, LIAO Zihao, GUAN Chengzhi, WANG Jianqiang. Application of Electrically-conductive (Cu, Mn)₃O₄ Contact Layer on Anode-Side of SOEC. Materials Reports, 2024, 38(8): 23040278-4.

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https://www.mater-rep.com/CN/10.11896/cldb.23040278 或 https://www.mater-rep.com/CN/Y2024/V38/I8/23040278

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