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材料导报  2025, Vol. 39 Issue (21): 24090001-13    https://doi.org/10.11896/cldb.24090001
  金属与金属基复合材料 |
高温防护铱合金改性的研究进展
刘忠宇1,2, 丁晨曦1, 方镇1, 吕镖1,3, 胡振峰1, 王浩旭1,*, 柳泉2,*
1 中国人民解放军军事科学院国防科技创新研究院,北京 100071
2 沈阳理工大学材料科学与工程学院,沈阳 110159
3 中国人民解放军63723部队,山西 忻州 036300
Research Progress on Modification of Iridium Alloys for High Temperature Protection
LIU Zhongyu1,2, DING Chenxi1, FANG Zhen1, LYU Biao1,3, HU Zhenfeng1, WANG Haoxu1,*, LIU Quan2,*
1 Defense Innovation Institute, Academy of Military Science PLA China, Beijing 100071, China
2 School of Materials Science and Engineering, Shenyang Ligong University, Shenyang 110159, China
3 People’s Liberation Army Unit 63723, Xinzhou 036300, Shanxi, China
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摘要 金属铱不仅熔点高、氧渗透率极低、抗热震性能良好而且高温抗氧化性能优异,在空天装备中常被视作热端部件抵抗极端服役条件(1 800~2 200 ℃)的理想热防护涂层材料之一。然而,铱存在催化活性高、发射率低以及氧化物易挥发等问题,这会影响服役寿命,需进行合金化改性以提高整体性能。本文综述了七种二元铱合金(Ir-X,X为Al、Hf、Zr、Rh、Ta、Re或Nb)、三元铱铝基合金(Ir-Al-X,X为 Ta、Hf或Zr等)以及三元铱铌基合金(Ir-Nb-Y,Y为 Hf、Ta或Ti等)在高温抗氧化方面的研究现状。梳理并构建了上述各类铱合金的成分组织及制备工艺与高温抗氧化性能或服役寿命之间的关联;着重总结了改性后铱合金的高温抗氧化作用效果和机制,同时兼顾高温力学性能或基体、涂层及氧化物间各层界面结合强度;对比分析明确了Hf、Al、Zr以及Rh等几种极具潜力的合金化元素,为极端高温服役环境下的铱合金设计开发与工程应用提供参考依据。
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刘忠宇
丁晨曦
方镇
吕镖
胡振峰
王浩旭
柳泉
关键词:  高温抗氧化性  铱合金  合金化改性  热防护    
Abstract: Iridium metal, with many advantages such as a high melting point, exceptionally low oxygen permeability, robust thermal shock resistance, and superior high-temperature oxidation resistance, is esteemed as one of the ideal materials for thermal protective coatings on hot end components of aerospace equipment which services in extreme high-temperature environments ranging from 1 800 to 2 200 ℃. However, due to the high catalytic activity, low emissivity, and volatility of iridium, the service life of iridium is significantly shortened, necessitating modifications such as alloying to enhance its durability and performance. To this end, this paper reviewed the recent progress of Ir-Al, Ir-Hf, Ir-Zr, Ir-Rh, Ir-Ta, Ir-Re, and Ir-Nb iridium alloys, Ir-Al-X (X=Ta, Hf, and Zr) ternary iridium-aluminum-based alloys, and Ir-Nb-Y (Y=Hf, Ta, and Ti) ternary iridium-niobium-based alloys for their high-temperature oxidation resistance. Moreover this study built the correlation between the composition and organization of the above iridium alloys and their high-temperature oxidation resistance or service life. It emphatically introduced the high temperature antioxidant effect and mechanism of iridium alloys doped with a single element or multiple elements, and discussed the high-temperature mechanical properties or interfacial bonding strength. Then the comparative analysis has clarified the potential alloying elements such as Hf, Al, Zr, and Rh, which can be used for the design and development of iridium alloys under extreme high temperature service environments. These may provide a reference and point to a direction for the design and development of iridium alloys for extreme high temperature service environments and engineering applications.
Key words:  high-temperature oxidation resistance    iridium alloy    alloying modification    thermal protection
出版日期:  2025-11-10      发布日期:  2025-11-10
ZTFLH:  TB34  
通讯作者:  *王浩旭,博士,军事科学院国防科技创新研究院副研究员、硕士研究生导师。目前主要从事复合材料增材制造、高温合金制备、微系统与微纳器件等方面的研究。whx152@163.com
柳泉,博士,沈阳理工大学材料科学与工程学院副教授、硕士研究生导师。目前主要从事军用复合材料及涂层的制备和耐蚀性等方面的研究。qliu@sylu.edu.cn   
作者简介:  刘忠宇,沈阳理工大学材料科学与工程学院硕士研究生,在王浩旭、柳泉老师的指导下进行研究。目前主要研究领域为熔盐电沉积制备贵金属涂层。
引用本文:    
刘忠宇, 丁晨曦, 方镇, 吕镖, 胡振峰, 王浩旭, 柳泉. 高温防护铱合金改性的研究进展[J]. 材料导报, 2025, 39(21): 24090001-13.
LIU Zhongyu, DING Chenxi, FANG Zhen, LYU Biao, HU Zhenfeng, WANG Haoxu, LIU Quan. Research Progress on Modification of Iridium Alloys for High Temperature Protection. Materials Reports, 2025, 39(21): 24090001-13.
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https://www.mater-rep.com/CN/10.11896/cldb.24090001  或          https://www.mater-rep.com/CN/Y2025/V39/I21/24090001
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