Abstract: The attapulgite(ATP)was surface modified by γ-glycidyl etheroxy propyltrimethoxy silane coupling agent (KH-560) via the water bath method. And the poly(butylene terephthalate) (PBT) matrixed-composites filled with attapulgite were prepared by melt intercalation blending technique. The crystal structure, surface morphology, and dispersion characteristics of ATP were characterized. The mechanical properties of the composite were investigated by tensile and notch impact strength testing. The tensile fracture morphology of the composite was analyzed. In addition, the reinforcement mechanism of ATP on PBT matrix was discussed. The results show that the ATP presents a typical fiber rod structure, with a rough and uneven surface and a diameter of about 30 nm. The KH-560 is successfully grafted on the surface of ATP through dehydration and condensation based on the presence of hydroxyl groups on the surface of ATP, which results in an increase in the crystal plane spacing of ATP, refinement of crystalline grain size, and the improvement of dispersion in PBT matrix. In case of the PBT matrixed-composites filled with modified ATP by KH-560, the long organic chain of modifiers on the surface of ATP and the molecular chain of PBT infiltrate each other, which results the formation of flexible interface layer with a certain thickness. Notably, the interfacial adhesion characteristics between the ATP and PBT matrix are enhanced. When the mass fractions of acid washed ATP and modified ATP by KH-560 are 3wt%, the tensile strength of corresponding composites reaches up to 58.1 MPa and 61.4 MPa, respectively, increasing by 13.3% and 19.7% compared to pure PBT.
通讯作者:
*康成虎,通信作者,吕梁学院物理与电子信息工程系讲师。2016年于重庆文理学院材料成型及控制工程专业本科毕业,2021年于兰州理工大学材料学专业博士毕业后到吕梁学院工作至今。目前主要从事材料微结构表征、聚合物基纳米复合材料力学性能和阻燃性能等方面的研究工作。发表论文6篇,包括Journal of Vinyl and Additive Technology、Materials Research Express、Polymer Composites、Journal of Dispersion Science and Technology等。20211019@llu.edu.cn
引用本文:
康成虎. 表面修饰凹凸棒土填充PBT基复合材料的力学性能[J]. 材料导报, 2024, 38(18): 23040289-6.
KANG Chenghu. Mechanical Properties of PBT Matrixed-Composites Filled with Surface Modified Attapulgite. Materials Reports, 2024, 38(18): 23040289-6.
1 Zhang W B, He D D, Wang J L, et al. Industrial Water Treatment, 2023, 43(7), 128 (in Chinese). 张文博, 贺丹丹, 王九玲, 等. 工业水处理, 2023, 43(7), 128. 2 Guo J X, Wu Z H, Li Z, et al. China Synthetic Resin and Plastics, 2022, 39(2), 33(in Chinese). 郭俊鑫, 吴正环, 黎振, 等. 合成树脂及塑料, 2022, 39(2), 33. 3 De S F P, Ribeiro D S M J, Wetler M P, et al. Journal of Drug Delivery Science and Technology, 2021, 64, 102586. 4 Tan D F, Ning G, Pang J Y, et al. Plastics Science and Technology, 2020, 48(1), 61(in Chinese). 谭登峰, 宁淦, 庞锦英, 等. 塑料科技, 2020, 48(1), 61. 5 Gong Y J, Zhang D, He M, et al. Polymer Materials Science and Engineering, 2018, 34(6), 184 (in Chinese). 龚勇吉, 张道, 何敏, 等. 高分子材料科学与工程, 2018, 34(6), 184. 6 Yang H, Cai Z, Liu H, et al. Materials Chemistry and Physics, 2020, 241, 122334. 7 Shi J, Li M. Solar Energy, 2020, 205, 62. 8 Ren S B. Study on flame retardant properties of surface modification attapulgite/PBT composite. Master’s Thesis, Lanzhou University of Technology, China, 2021(in Chinese). 任世博. 表面改性凹凸棒石/PBT基复合材料阻燃性能的研究. 硕士学位论文, 兰州理工大学, 2021. 9 Yang G Y, Peng S W, Wang W, et al. China Plastics Industry, 2022, 50(1), 119(in Chinese). 杨光远, 彭三文, 王闻, 等. 塑料工业, 2022, 50(1), 119. 10 Wang H, Liu Q, Wu S, et al. Construction and Building Materials, 2023, 400, 132827. 11 Wu T, Dong J, Xu G, et al. Polymer, 2019, 176, 196. 12 Li Y, Zhao G, Pan G, et al. Journal of Membrane Science, 2023, 675, 121517. 13 Seyedzavvar M, Boa C, Akar S, et al. Materials Today Communications, 2021, 28, 102602. 14 Jiang L, Huang Z, Wang X, et al. Materials & Design, 2020, 196, 109175. 15 Cao Y, Xu P, Wu B, et al. Composites Science and Technology, 2020, 190, 108043. 16 Abdo D, Gleadall A, Silberschmidt V V. Engineering Failure Analysis, 2019, 105, 466. 17 Abdo D, Gleadall A, Silberschmidt V V. Composite Structures, 2019, 226, 111286. 18 Arai S, Tsunoda S, Yamaguchi A, et al. Optics & Laser Technology, 2019, 117, 94. 19 Standardization Administration of the People’s Republic of China. Plastics-determination of tensile properties-Part 1:general principles:GB/T 1040. 1-2018, China Standards Press, China, 2018 (in Chinese). 中国国家标准化管理委员会. 塑料 拉伸性能的测定 第1部分:总则:GB/T 1040. 1-2018. 中国标准出版社, 2018. 20 Standardization Administration of the People’s Republic of China. Thermoplastics pipes-determination of pendulum impact strength by the charpy method-part 1:general test method:GB/T 18743. 1-2022, Beijing:China Standards Press, 2022 (in Chinese). 中国国家标准化管理委员会. 热塑性塑料管材 简支梁冲击强度的测定 第1部分:通用试验方法:GB/T 18743. 1-2022, 中国标准出版社, 2022. 21 Yang Y, Yin Q, Xu F, et al. Thermochimica Acta, 2022, 718, 179363. 22 Zhang X G, Shi H J, Liu J, et al, Materials Reports, 2022, 36(5), 237 (in Chinese). 张晓光, 时海军, 刘杰, 等. 材料导报, 2022, 36(5), 237. 23 Han C, Zhao H, Yang T, et al. Polymer Testing, 2023, 128, 108222. 24 Dhanumalayan E, Joshi G M, Kaleemulla S, et al. Progress in Organic Coatings, 2019, 131, 17. 25 Barakat M, Reda H, Chazirakis A, et al. Polymer, 2023, 286, 126379. 26 Arai S, Tsunoda S, Yamaguchi A, et al. Additive Manufacturing, 2018, 21, 683. 27 Shui T, Li Z, Xiang D, et al. China Plastics Industry, 2023, 51(5), 95(in Chinese). 税涛, 李珍, 向东, 等. 塑料工业, 2023, 51(5), 95. 28 Li M Q, Li X F, Wang R T, et al. Materials Reports, 2023, 37(20), 229 (in Chinese). 李美琪, 李晓飞, 王瑞涛, 等. 材料导报, 2023, 37(20), 229. 29 Zheng J Z, Pei H H, Zhang G C, et al, Materials Reports, 2023, 37(7), 247(in Chinese). 郑家桢, 裴海华, 张贵才, 等. 材料导报, 2023, 37(7), 247. 30 Xu J L, An J, Kang C H, et al. Acta Materiae Compositae Sinica, 2021, 38(8), 2586 (in Chinese). 徐建林, 安静, 康成虎, 等. 复合材料学报, 2021, 38(8), 2586.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2024, Vol. 38 
