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| Temperature- and Glucose-responsive Behaviors of P(NIPAAm-co- AAPBA-co-HPM-co-TMSPM) Quaternary Copolymers |
| YANG Lei1,WANG Lemin1,LI Jiaxing1,FAN Xiaoguang2,HAO Haoran1,PEI Hongjie1, SAN Jianan1,XUE Junwen1
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1 College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001;
2 College of Engineering, Shenyang Agricultural University, Shenyang 110866 |
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Abstract The P(NIPAAm-co-AAPBA-co-HPM-co-TMSPM) quaternary copolymers were synthesized by free radical polymerization of N-isopropylacrylamide (NIPAAm),3-acrylamidophenylboronic acid (AAPBA), hydroxypropyl methacrylate (HPM) and 3-trimethoxysilylpropyl methacrylate (TMSPM). Fourier transform infrared (FTIR) spectrometry, nuclear magnetic resonance hydrogen (1H-NMR) spectroscopy and dynamic light scattering (DLS) technique were used to analyze and identify the chemical structure, molecular composition and responsive behaviors of the copolymers. The results indicated that the resultant copolymers with short chains, were composed of NIPAAm, AAPBA, HPM and TMSPM in the designed molar ratios of reactants, and they displayed excellent dual-response towards temperature and glucose.
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Published: 20 July 2018
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2018, Vol. 32 
