地质聚合物混凝土研究现状

doi:10.11896/j.issn.1005-023X.2018.09.017

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (1896KB)
Export: BibTeX | EndNote (RIS)

Abstract Geopolymer concrete, a class of newly emerging green building materials prepared from the readily obtainable industrial solid waste, possess a variety of advantages such as low energy consumption & carbon emission and facile production process, as well as excellent compressive strength, acid and alkali resistance, freezing and thawing performance and carbonation resistance. It has displayed notable application potential, and become one of the most promising alternatives to ordinary Portland cement. This paper renders a retrospection of the domestic and overseas research endeavors, a vivid description for the raw materials, mix design, mechanical property, workability and durability of geopolymer concrete, as well as a critical discussion upon the technological problems confronting this novel and prospective engineering material.

Key words： geopolymer concrete raw materials mix design mechanical property workability durability

Published: 06 July 2018

CLC number:

TB39

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHANG Dawang
	WANG Dongmin

Cite this article:

ZHANG Dawang,WANG Dongmin. Research Status of Geopolymer Concrete[J]. Materials Reports, 2018, 32(9): 1519-1527.

URL:

http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2018.09.017 OR http://www.mater-rep.com/EN/Y2018/V32/I9/1519

1 Peng J X, Huang L, Zhao Y B, et al. Modeling of carbon dioxide measurement on cement plants[J].Advanced Materials Research,2013,610-613:2120.
2 Meyer C. The greening of the concrete industry[J].Cement & Concrete Composites,2009,31(8): 601.
3 Davidovits J. Environmentally driven geopolymer cement applications[C]∥Geopolymer 2002 Conference.Melbourne,2002:1.
4 Habert G, Lacaillerie J B D E, Roussel N. An environmental evaluation of geopolymer based concrete production: Reviewing current research trends[J].Journal of Cleaner Production,2011,19(11):1229.
5 Mclellan B C, Williams R P, Lay J, et al. Costs and carbon emissions for geopolymer pastes in comparison to ordinary portland cement[J].Journal of Cleaner Production,2011,19(9-10):1080.
6 Turner L K, Collins F G. Carbon dioxide equivalent (CO₂-e) emissions: A comparison between geopolymer and OPC cement concrete[J].Construction & Building Materials,2013,43(6):125.
7 Davidovits J. Geopolymers: Inorganic polymeric new materials[J].Journal of Thermal Analysis,1991,37(8):1633.
8 Davidovits J. Geopolymers and geopolymeric materials[J].Journal of Thermal Analysis,1989,35(2):429.
9 Zhang T, Yu Q, Wei J, et al. Preparation of high performance blended cements and reclamation of iron concentrate from basic oxygen furnace steel slag[J].Resources Conservation & Recycling,2011,56(1):48.
10 Adamiec P, Benezet J C, Benhassaine A. Pozzolanic reactivity of silico-aluminous fly ash[J].Particuology,2008,6(2):93.
11 Temuujin J, Van Riessen A, Williams R. Influence of calcium compounds on the mechanical properties of fly ash geopolymer pastes[J].Journal of Hazardous Materials,2009,167(3):82.
12 Lee S K, Stebbins J F. The degree of aluminum avoidance in aluminosilicate glasses[J].American Mineralogist,1999,84(5):937.
13 Yip C K, Lukey G C, Provis J L, et al. Effect of calcium silicate sources on geopolymerisation[J].Cement & Concrete Research,2008,38(4):554.
14 Dombrowski K, Buchwald A, Weil M. The influence of calcium content on the structure and thermal performance of fly ash based geopolymers[J].Journal of Materials Science,2007,42(9):3033.
15 Luo X C, Wang C A. Effect of calcia content on structure and pro-perties of metakaolin/blast furnace slag-based geopolymers[J].Journal of the Chinese Ceramic Society,2015,43(12):1800(in Chinese).
罗新春,汪长安.钙含量对偏高岭土/矿渣基地聚合物结构和性能的影响[J].硅酸盐学报,2015,43(12):1800.
16 Gao W Q, Du H Y, Liu J C,et al. Effect of calcium compounds on properties of F-class fly ash based geopolymer [J].Journal of the Chinese Ceramic Society,2015,43(3):334(in Chinese).
高婉琪,杜海燕,刘家臣,等.钙对F-型粉煤灰基地聚物性能的影响(英文)[J].硅酸盐学报,2015,43(3):334.
17 Liu Rengguang. Hydration mechanism and long-term performance of cement-slag complex cementitious materials[D].Beijing:Tsinghua University,2013(in Chinese).
刘仍光.水泥-矿渣复合胶凝材料的水化机理与长期性能[D].北京:清华大学,2013.
18 Assi L, Ghahari S A, Deaver E, et al. Improvement of the early and final compressive strength of fly ash-based geopolymer concrete at ambient conditions[J].Construction & Building Materials,2016,123:806.
19 Nath P, Sarker P K, Rangan V B. Early age properties of low-calcium fly ash geopolymer concrete suitable for ambient curing[J].Procedia Engineering,2015,125:601.
20 Lohani T K, Jena S, Dash K P, et al. An experimental approach on geopolymeric recycled concrete using partial replacement of indust-rial byproduct[J].International Journal of Civil & Structural Engineering,2012,1(3):141.
21 Yip C K, Deventer J S J V. Microanalysis of calcium silicate hydrate gel formed within a geopolymeric binder[J].Journal of Materials Science,2003,38(18):3851.
22 Kwon Y H, Kang S H, Hong S G, et al. Acceleration of intended pozzolanic reaction under initial thermal treatment for developing cementless fly ash based mortar[J].Materials,2017,10(3):225.
23 Shi C, Krivenko P, Roy D. Alkali-activated cements and concretes[M].New York:CRC Press,2005:200.
24 Glukhovsky V D, Zaitsev Y P V. Slag-alkaline cements and concretes: Structures, properties, technological and economic aspects of use[J].Silicates Industriels,1983,48(10):197.
25 Weng L Q, Kwesi S C, Song S H, et al.Hydrolysis kinetics of aluminates in geopolymer synthesis[J].Journal of the Chinese Ceramic Society,2005,33(3):276(in Chinese).
翁履谦,Kwesi Sagoe-Crentsil,宋申华,等.地质聚合物合成中铝酸盐组分的作用机制[J].硅酸盐学报,2005,33(3):276.
26 Sakai E, Miyahara S, Ohsawa S, et al. Hydration of fly ash cement[J].Cement & Concrete Research,2005,35(6):1135.
27 Xu H, Deventer J S J V. The geopolymerisation of alumino-silicate minerals[J].International Journal of Mineral Processing,2000,59(3):247.
28 Barbosa V F F, Mackenzie K J D, Thaumaturgo C. Synthesis and characterisation of materials based on inorganic polymers of alumina and silica: Sodium polysialate polymers[J].International Journal of Inorganic Materials,2000,2(4):309.
29 Rees C A, Provis J L, Lukey G C, et al. In situ ATR-FTIR study of the early stages of fly ash geopolymer gel formation[J].Langmuir the ACS Journal of Surfaces & Colloids,2007,23(17):9076.
30 Tempest B, Sanusi O, Gergely J, et al. Compressive strength and embodied energy optimization of fly ash based geopolymer concrete[J].Indian Journal of Science & Technology,2009,21(2):1.
31 Assi L N, Deaver E, Elbatanouny M K, et al. Investigation of early compressive strength of fly ash-based geopolymer concrete[J].Construction & Building Materials,2016,112:807.
32 Davidovits J. Geopolymers[J].Journal of Thermal Analysis and Calorimetry,1991,37(8):1633.
33 Provis J L, Duxson P, Deventer J S J V, et al. The role of mathematical modelling and gel chemistry in advancing geopolymer technology[J].Chemical Engineering Research & Design,2005,83(7):853.
34 Zhang Y S, Sun W, Zheng K R, et al. In situ quantitatively tracking the hydration process of K-PSDS geopolymer with ESEM[J].Journal of Building Materials,2004,7(1):8(in Chinese).
张云升,孙伟,郑克仁,等.ESEM追踪K-PSDS型地聚合物水泥的水化[J].建筑材料学报,2004,7(1):8.
35 Li H J. Study on Gelation mechanism of silica-alumina based mate-rials made from coal gangue[J].Materials Review,2007,21(9):91(in Chinese).
李化建.煤矸石质硅铝基材料胶凝机理的研究[J].材料导报,2007,21(9):91.
36 Zhang Y S, Sun W, et al, Lin W. In suit quantitatively tracking the hydration process of interfacial transition zone between coarse aggregate and K-PSDS geopolymer matrix with ESEM [J].Journal of the Chinese Ceramic Society,2005,33(8):276(in Chinese).
张云升,孙伟,林玮,等.用环境扫描电镜原位定量追踪K-PSDS型地聚合物混凝土界面区的水化过程[J].硅酸盐学报,2003,31(8):806.
37 Miranda J M, Fernández-Jiménez A, González J A, et al. Corrosion resistance in activated fly ash mortars[J].Cement & Concrete Research,2005,35(6):1210.
38 Chang J J. A study on the setting characteristics of sodium silicate-activated slag pastes[J].Cement & Concrete Research,2003,33(7):1005.
39 Lee W K W, Deventer J S J V. Effects of anions on the formation of aluminosilicate gel in geopolymers[J].Industrial & Engineering Chemistry Research,2002,41(18):4550.
40 Bilim C, Karahan O, Ati C D, et al. Influence of admixtures on the properties of alkali-activated slag mortars subjected to different curing conditions[J].Materials & Design,2013,44:540.
41 Tailby J, Mackenzie K J D. Structure and mechanical properties of aluminosilicate geopolymer composites with Portland cement and its constituent minerals[J].Cement & Concrete Research,2010,40(5):787.
42 Nicholson C, Murray B, Fletcher R, et al. Novel geopolymer materials containing borate and phosphate structural units[C]∥World Congress Geopolymer 2005.Saint Quentin,2005:140.
43 Shi C, Li Y. Investigation on some factors affecting the characteristics of alkali-phosphorus slag cement[J].Cement & Concrete Research,1989,19(4):527.
44 Kukko H, Mannonen R. Chemical and mechanical properties of alkali-activated blast furnace slag (f-concrete)[M].Australian:Nordic Concrete Research,1982:52.
45 Bakharev T, Sanjayan J G, Cheng Y B. Effect of admixtures on properties of alkali-activated slag concrete[J].Cement & Concrete Research,2000,30(9):1367.
46 Douglas E, Brandstetr J. A preliminary study on the alkali activation of ground granulated blast-furnace slag[J].Cement & Concrete Research,1990,20(5):746.
47 Wang S D, Scrivener K L, Pratt P L. Factors affecting the strength of alkali-activated slag[J].Cement & Concrete Research,1994,24(6):1033.
48 Puertas F, Palomo A, Fernandez-Jimenez A, et al. Effect of superplasticisers on the behaviour and properties of alkaline cements[J].Advances in Cement Research,2003,15(1):23.
49 Kong D L Y, Sanjayan J G. Effect of elevated temperatures on geopolymer paste, mortar and concrete[J].Cement & Concrete Research,2010,40(2):334.
50 Criado M, Palomo A, Fernández-Jiménez A, et al. Alkali activated fly ash: Effect of admixtures on paste rheology[J].Rheologica Acta,2009,48(4):447.
51 Palacios M, Puertas F. Effect of superplasticizer and shrinkage-reducing admixtures on alkali-activated slag pastes and mortars[J].Cement & Concrete Research,2005,35(7):1358.
52 Palacios M, Puertas F. Stability of superplasticizer and shrinkage-reducing admixtures in high basic media[J].Materiales de Construcción,2004,54(276):65.
53 Bakharev T, Sanjayan J G, Cheng Y B. Effect of admixtures on properties of alkali-activated slag concrete[J].Cement & Concrete Research,2000,30(9):1367.
54 Lloyd N A, Rangan B V. Geopolymer concrete with fly ash[J].Australian Journal of Structural Engineering,2010,21(3):1493.
55 Anuradha R, Sreevidya V, Venkatasubramani R, et al. Modified guidelines for geopolymer concrete mix design using Indian standard[J].Asian Journal of Civil Engineering,2012,13(3):353.
56 Ferdous M W, Kayali O, Khennane A. A detailed procedure of mix design for fly ash based geopolymer concrete[C]∥4th Asia-Pacific Conference on FRP in Structures.Melbourne,2013:11.
57 Pavithra P, Reddy M S, Dinakar P, et al. A mix design procedure for geopolymer concrete with fly ash[J].Journal of Cleaner Production,2016,133:117.
58 Montes C, Gomez S A, Khadka N, et al. Statistical software to improve the accuracy of geopolymer concrete mix design and proportioning[C]∥2013 World of Coal Ash Conference.Lexington,2013:18.
59 Duxson P, Provis J L. Designing precursors for geopolymer cements[J].Journal of the American Ceramic Society,2010,91(12):3864.
60 Jamkar S S, Ghugal Y M, Patankar S V. Effect of fly ash fineness on workability and compressive strength of geopolymer concrete[J].Indian Concrete Journal,2013,87(4):57.
61 Patankar S V, Ghugal Y M, Jamkar S S. Mix design of fly ash based geopolymer concrete[J].Advances in Structural Engineering,2015,3:1619.
62 Diaz E I, Allouche E N. Recycling of fly ash into geopolymer concrete:Creation of a database[C]∥Green Technologies Conference.USA,2010:1.
63 Garcia-Lodeiro I, Palomo A, Fernández-Jiménez A, et al. Compatibility studies between N-A-S-H and C-A-S-H gels. Study in the ternary diagram Na₂O-CaO-Al₂O₃-SiO₂-H₂O[J].Cement & Concrete Research,2011,41(9):923.
64 Adam A. Strength and durability properties of alkali activated slag and fly ash-based geopolymer concrete[D].Melbourne:RMIT University,2009:12.
65 Bernal S A, Provis J L, Walkley B, et al. Gel nanostructure in alkali-activated binders based on slag and fly ash, and effects of accele-rated carbonation[J].Cement & Concrete Research,2013,53(2):127.
66 Bernal S A, Nicolas R S, Myers R J, et al. MgO content of slag controls phase evolution and structural changes induced by accelerated carbonation in alkali-activated binders[J].Cement & Concrete Research,2013,57(3):33.
67 Criado M, Palomo A, Fernández-Jiménez A. Alkali activation of fly ashes. Part 1: Effect of curing conditions on the carbonation of the reaction products[J].Fuel,2005,84(16):2048.
68 Bakharev T, Sanjayan J G, Cheng Y B. Resistance of alkali-activated slag concrete to carbonation[J].Cement & Concrete Research,2001,31(31):1277.
69 Puertas F, Palacios M, Vázquez T. Carbonation process of alkali-activated slag mortars[J].Journal of Materials Science,2006,41(10):3071.
70 Bernal S A, Gutiérrez R M D, Provis J L. Engineering and durability properties of concretes based on alkali-activated granulated blast furnace slag/metakaolin blends[J].Construction & Building Materials,2012,33(7):99.
71 Fu Y, Cai L, Wu Y. Freeze-thaw cycle test and damage mechanics models of alkali-activated slag concrete[J].Construction & Building Materials,2011,25(7):3144.
72 Doleal J, kvára F, Svoboda P, et al. Concrete based on fly ash geopolymers[J].Construction & Building Materials,2006,29(3):1.
73 kvára F, Jílek T, Kopecky＇ L. Geopolymer materials based on fly ash[J].Ceramics Silikaty,2005,49(3):195.
74 Brooks R, Bahadory M, Tovia F, et al. Properties of alkali-activated fly ash: High performance to lightweight[J].International Journal of Sustainable Engineering,2010,3(3):211.
75 Rostami H, Brendley W. Alkali ash material: A novel fly ash-based cement[J].Environmental Science & Technology,2003,37(15):3454.
76 Rangan B V. Geopolymers[M].Australian:Woodhead Publishing,2009:211.
77 Tennakoon C, Shayan A, Sanjayan J G. Influence of binder on alkali reactivity of aggregates in geopolymer concrete[C]∥Concrete 27th National Biennial Conference of the Concrete Institute of Australia.Australia,2015:1089.
78 Gifford P M, Gillott J E. Alkali-silica reaction (ASR) and alkali-carbonate reaction (ACR) in activated blast furnace slag cement (ABFSC) concrete[J].Cement & Concrete Research,1996,26(1):21.
79 Krivenko P, Drochytka R, Gelevera A, et al. Mechanism of preventing the alkali-aggregate reaction in alkali activated cement concretes[J].Cement & Concrete Composites,2014,45(1):157.
80 Sagoe-Crentsil K, Weng L. Dissolution processes, hydrolysis and condensation reactions during geopolymer synthesis: Part Ⅱ. High Si/Al ratio systems[J].Journal of Materials Science,2007,42(9):3007.