POLYMERS AND POLYMER MATRIX COMPOSITES |
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Glucose Sensing and Digital Encoding of Dual-emission Carbon Dots of Difluorobenboric Acid Source |
WU Pingping, WANG Yaqin*, CHEN Tao, ZOU Wensheng
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School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei 230601, China |
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Abstract Carbon dots have many advantages, such as low cost and cytotoxicity as well as good photostability and biocompatibility. The fluorescence and phosphorescence properties as well as applications of carbon dots have always been research plumes. Herein, fluorescence/phosphorescence double-emission carbon dots were prepared via a one-pot hydrothermal method involving 3,4-difluorophenylboric acid as a carbon source. The physicochemical properties of the carbon dots were determined by studying their crystal structure, element composition, and surface electrical charging property. Organic boric acid functional groups can produce boron with a strong affinity for o-hydroxyl groups, thereby quenching the fluorescence signal due to electron transfer. Based on this, carbon dots were applied in the chemical sensing of glucose. The quenching rate ((F0-F)/F0) exhibited a good linear variation in the concentration range of 5—50 μmol/L. Moreover, because of the existence of electron deficient organic boric acid groups on the carbon atoms of 3,4-difluorophenylboric acid, the n-electrons (B-O, n→σ*), through the weak conjugation between them, enabled the solid carbon dots to have good phosphorescence properties and achieve gratifying results when applied in digital coding. Owing to their simple synthesis and good photochemical properties, the 3,4-difluorobenboric acid-derived fluorescent/phosphorescent dual-emission carbon dots showed great application potential in blood glucose sensing and digital coding.
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Published: 10 December 2023
Online: 2023-12-08
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Fund:General Project of Anhui Natural Science Foundation (1908085MB40) and Energy Storage Technology College of Anhui Jianzhu University (2021cyxy023). |
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1 Huang Q T, Lin X F, Li F M, et al. Progress In Chemistry, 2015, 27(11), 1604 (in Chinese). 黄启同, 林小凤, 李飞明, 等. 化学进展, 2015, 27(11), 1604. 2 Dong Y, Wang R, Li H, et al. Carbon, 2012, 50(8), 2810. 3 Li H T, Shi J W, Guo Y, et al. Chemical Reagents, 2022, 44(3), 422(in Chinese). 黎海涛, 施家威, 郭燕, 等. 化学试剂, 2022, 44(3), 422. 4 Nur H Z A, Siti N A S, Hazwani S, et al. Polymer Testing, 2021, 100, 107270. 5 Liu W, Li T T, Zhang B, et al. Materials Reports, 2019, 33(2), 402 (in Chinese). 刘文, 李婷婷, 张冰, 等. 材料导报, 2019, 33(2), 402. 6 Xia Y, Tong Y L, Liu D, et al. Guangzhou Chemical Industry, 2021, 49(21), 47 (in Chinese). 夏艳, 童玉莲, 刘丹, 等. 广州化工, 2021, 49(21), 47. 7 Kenta H, Satoshi H, Nick S. Journal of Photochemistry and Photobiology A: Chemistry, 2021, 415, 113310. 8 Ding S, Gao Y, Ni B, et al. Inorganic Chemistry Communications, 2021, 130, 108636. 9 Zou W S, Chen T, Lin D, et al. ACS Applied Electronic Materials, 2021, 3(6), 2661. 10 Li C, Chen Y Q, Quan Z P, et al. Materials Reports, 2023, 37(15), 22020030(in Chinese). 李晨, 陈叶青, 全志鹏, 等. 材料导报, 2023,37(15), 22020030. 11 Zhou T Y, Wang Q, Li H, et al. Journal of Molecular Science, 2021, 37(6), 501 (in Chinese). 周天越, 王权, 李皓, 等. 分子科学学报, 2021, 37(6), 501. 12 Li J, Wang Y Y, Zhang Y, et al. Journal of Shaanxi University of Science & Technology, 2021, 39(6), 103 (in Chinese). 李季, 王玉玉, 张苑, 等. 陕西科技大学学报, 2021, 39(6), 103. 13 Li M, Hu C, Yu C, et al. Carbon, 2015, 91, 291. 14 Rojas V O G, Reguel C M, Hernández F J, et al. Materialia, 2021, 19, 101182. 15 Yan P, Ai F R, Yan X L, et al.Materials Reports, 2017, 31(19), 35(in Chinese). 闫鹏, 艾凡荣, 严喜鸾, 等. 材料导报, 2017, 31(19), 35. 16 Guo T, Ma X R,Wang Q, et al. Journal of Chemical Engineering of Chinese Universities, 2021, 35(6), 1060 (in Chinese). 郭涛, 马欣如, 王群, 等. 高校化学工程学报, 2021, 35(6), 1060. 17 Wang Z, Liu Y, Zhen S, et al.Advanced science (Weinheim, Baden-Württemberg, Germany), 2020, 7(4), 1902688. 18 Das S, Alexeev V L, Sharma A C, et al. Tetrahedron Letters, 2003, 44(42), 7719. 19 Liu B, Yang K, Yang X H, et al. Chinese Medical Equipment Journal, 2021, 42(9), 88(in Chinese). 刘博, 杨焜, 魏晓慧, 等. 医疗卫生装备, 2021, 42(9), 88. 20 Chen T. Study on preparation and application of pure organic phosphorescent cluster source and long afterglow carbon dots, Master's Thesis, Anhui Jianzhu University, China, 2021 (in Chinese). 陈涛. 纯有机磷光团源长余辉碳点的制备及应用研究. 硕士学位论文, 安徽建筑大学, 2021. 21 Kumar R, Chauhan S. Ceramics International, 2022, 48(3), 2913. 22 Xia C, Zhu S, Zhang S T, et al. ACS Applied Materials & Interfaces, 2020, 12(34), 38593. 23 Yu C, Xuan T, Chen Y, et al. Journal of Alloys and Compounds, 2016, 688, 611. 24 Sarkar S, Ray U, Roy D, et al. Materials Letters, 2021, 303, 130493. 25 Kakaei K, Khodadoost S, Gholipour M, et al. Journal of Physics and Chemistry of Solids, 2021, 148, 109753. 26 Yu Q, Jiang J, Chen Z, et al. Sensors and Actuators B: Chemical, 2022, 350, 130898. 27 Zheng H, Liu L, Meng F, et al. Journal of Materials Science & Technology, 2021, 84, 86. 28 Hwang J, Yook K S, Lee J Y, et al. Dyes and Pigments, 2015, 121, 73. 29 Wang C, Chen Y, Xu Y, et al. ACS Applied Materials & Interfaces, 2020, 12(9), 10791. 30 Wu H, Qasim A M, Xiao S, et al. Surface and Coatings Technology, 2018, 352, 437. 31 Zhang H Y, Cao P S, Wang Y Y, et al. Angewandte Chemie International Edition, 2021, 60, 9500. |
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