INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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A Method for Improving the Efficiency of Tin-based Perovskite Solar Cells by Low Temperature Annealing Treatment |
YU Haiyan1, XU Fangxian1, ZHANG Shuai1,2,*, YUAN Ningyi1,2, DING Jianning2,3
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1 School of Materials Science and Engineering, Changzhou University,Changzhou 213161, Jiangsu, China 2 Jiangsu Photovoltaic Science and Engineering Collaborative Innovation Center, Changzhou 213161,Jiangsu, China 3 School of Mechanical Engineering, Yangzhou University,Yangzhou 225000,Jiangsu, China |
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Abstract Iin-based perovskite has been considered as a candidate material to replace lead based perovskite because of its ideal band gap and high carrier efficiency. However, the rapid crystallization rate has been one of the obstacles limiting the photoelectric conversion of tin-based perovskite solar cells. A simple and low-cost method is used here. After spinning perovskite film is annealed at low temperature, and then annealed at 90 ℃. The objective is to slow down the growth of perovskite crystals in the process of crystallization without changing the type of perovskite crystals and introducing new components. By this method, the light absorption efficiency of perovskite thin films is improved, the surface hole defects are reduced, and the carrier recombination in the device is reduced. Equipment filling coefficient increased by 29.84%, efficiency increased from 3.645% to 5.38%.
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Published: 10 December 2023
Online: 2023-12-08
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Fund:National Natural Science Foundation of China (51602031) and Science and Technology Support Project of Changzhou (CE20215025). |
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