温度和甲酸镍含量对制备Zn-Ni合金渗层的影响

doi:10.11896/cldb.21120065

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (11930KB)
Export: BibTeX | EndNote (RIS)

Abstract In order to improve the anti-corrosion performance of sherardizing layer, zinc-nickel alloy cementation layer was prepared by adding nickel formate in the sherardizing process. The effects of temperature (400 ℃,450 ℃,500 ℃,550 ℃,600 ℃)and nickel formate content(0 g,15 g,44 g,75 g,103 g) on the formation process of the infiltration layer are analyzed. Scanning electron microscope (SEM, equipped with EDS spectrum) and X-ray diffractometer (XRD) were used to analyze the cross-sectional morphology and phase composition of different samples; lectrochemical polarization curve and impedance spectroscopy (EIS) were used to characterize the different the electrochemical behavior of the sample in 3.5wt% NaCl solution, and the corrosion resistance of the cementation layer was tested by a neutral salt spray experiment; the hardness of different phase layers from the surface of the cementation layer to the substrate was tested by a micro Vickers hardness tester. The results show that: with the increase of temperature, the cementation layer is thickens obviously and the surface hardness of the cemented layer decreases; with the increase of nickel formate content, the cementation layer is thins obvlously, and the diffraction peaks of ZnO and Fe₃ZnC_0.5 phase are significantly enhanced, and the intermediate phase of the cementation layer's hardness value increases; temperature and nickel formate content have no obvious effect on the self-corrosion potential. The corrosion current density increases with the increase of temperature, and obviously decreases with the increase of nickel formate content; the sample impedance arc radius and the resistance of the cementation layer increases with the increase of nickel formate content; the higher the nickel formate content, the less white rust appears in the salt spray test, and the time for red rust appears to be significantly longer. In summary, the addition of nickel formate significantly improves the structure of the sherardized layer, and significantly improves the corrosion resistance of the cementation layer. It is of positive significance to promote the application of zinc-nickel alloy co-cementation technology.

Key words： Zn-Ni co-cementation layer electrochemical behavior micro-hardness of the coating corrosion resistance content of nickel formate

Published: 25 August 2023 Online: 2023-08-14

CLC number:

TG147.445

Fund:National Natural Science Foundation of China (52161013).

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	XU Penghui
	WANG Shengmin
	LE Linjiang
	XIAO Min
	ZHAO Xiaojun

Cite this article:

XU Penghui,WANG Shengmin,LE Linjiang, et al. Effect of Temperature and Nickel Formate Content on the Preparation of Zn-Ni Cementation Layer[J]. Materials Reports, 2023, 37(16): 21120065-8.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.21120065 OR http://www.mater-rep.com/EN/Y2023/V37/I16/21120065

1 Lu Y P, Yu F Z.Shendu, Machinery Industry Press, China, 1985, pp. 18 (in Chinese).
卢燕平, 于福洲.渗镀, 机械工业出版社, 1985,pp. 18.
2 Zhang X H, Yu S R, Liu Y, et al.Surface Technology, 2020, 49(11), 141 (in Chinese).
张潇华, 于思荣, 刘彦, 等.表面技术, 2020, 49(11), 141.
3 Zhang S Q, Zhang Y Q, Yu H Y, et al.Railway Engineering, 2021, 61(2), 122 (in Chinese).
张松琦, 张远庆, 于毫勇, 等.铁道建筑, 2021, 61(2), 122.
4 Liang Y, Zhou Y L, Sheng Z Q, et al.China Surface Engineering, 2020, 33(2), 65 (in Chinese).
梁义, 周云龙, 盛忠起, 等.中国表面工程, 2020, 33(2), 65.
5 Zhang J N, Peng Y, Cheng X Q. In:2015 2nd Marine Material Corrosion and Protection Conference. Beijing, 2015, pp. 3 (in Chinese).
章嘉能, 彭阳, 程学群. 2015第二届海洋材料与腐蚀防护大会. 北京, 2015, pp. 3.
6 Sun F. Research on powder sherardizing and dacromet composite protection technology.Master's Thesis, Xi'an University of Technology, China, 2016 (in Chinese).
孙菲. 粉末渗锌与达克罗复合防护技术研究. 硕士学位论文, 西安理工大学, 2016.
7 Gur A M, Krasnikov K A, Zemlyakov S A, et al.Metallurgist, 2021, 65, 3.
8 Lin N M, Zhao L L, Liu Q, et al.Journal of Physics and Chemistry of Solids, 2019, 129, 387.
9 Li L B, Li Z X, Liu L T, et al.Rare Metal Materials and Engineering, 2021, 50(5), 1743 (in Chinese).
李龙博, 李争显, 刘林涛, 等.稀有金属材料与工程, 2021, 50(5), 1743.
10 Zhuang G S, Ma Y, Xu Y, et al.Heat Treatment of Metals, 2000(12), 25 (in Chinese).
庄光山, 马勇, 徐英, 等.金属热处理, 2000 (12), 25.
11 Li C H. Process and properties of Zn-Al co-cementation on medium carbon steel.Master's Thesis, Hebei University of Technology, China, 2017 (in Chinese).
李春红. 中碳钢Zn-Al共渗工艺及性能研究. 硕士学位论文, 河北工业大学, 2017.
12 He Z X, Su X P, Peng H P, et al.China Surface Engineering, 2016, 29(6), 44 (in Chinese).
何祖新, 苏旭平, 彭浩平, 等.中国表面工程, 2016, 29(6), 44.
13 Peng H P, Xu N, He Z X, et al.Journal of Changzhou University(Natural Science Edition), 2019, 31(4),39 (in Chinese).
彭浩平, 徐宁, 何祖新, 等.常州大学学报(自然科学版), 2019, 31(4), 39.
14 Abou-Krisha M M, Assaf F H, Ei-Naby S A, et al.Arabian Journal of Chemistry, 2016, 9(2), 1349.
15 Zhang X, Wang S L, Long J M, et al.Materials Reports, 2013, 27(14), 120 (in Chinese).
张秀, 王少龙, 龙晋明, 等.材料导报, 2013, 27(14), 20.
16 Fratesi R, Ruffini N, Bellezze T, et al.Surface and Coatings Technology, 2002, 157(1), 34.
17 Dai H B, Wang G B.Surface Technology, 1996(1), 9. (in Chinese)
戴洪斌, 王国.表面技术, 1996(1), 9.
18 Wang A B. Study on properties of Fe-Ni alloy prepared by laser and magnetic field assisted electro-deposition. Master's Thesis, Jiangsu University, China, 2020 (in Chinese).
王安斌. 激光和磁场辅助电沉积制备铁镍合金及其性能研究. 硕士学位论文, 江苏大学, 2020.
19 Zhang Q, Zhang X H, Cheng L, et al.Modern Paint and Finishing, 2020, 23(7), 11 (in Chinese).
张琪, 张潇华, 成琳, 等.现代涂料与涂装, 2020, 23(7), 11.
20 Dong R H, Li M S, Wang X C, et al.Journal of Shandong University(Engineering Science), 2008, 38(6), 91 (in Chinese).
董瑞华, 李木森, 王修春, 等.山东大学学报(工学版), 2008, 38(6), 91.
21 Gao C. Sherardizing process and its effect on microstructure and corrosion resistance.Master's Thesis, Hebei University of Technology, China, 2015 (in Chinese).
高聪. 粉末渗锌工艺及其对组织和耐蚀性的影响. 硕士学位论文, 河北工业大学, 2015.
22 Liu Q, Wang J H, Peng H P, et al.Materials Reports, 2012, 26(16), 83 (in Chinese).
刘赛, 王建华, 彭浩平, 等.材料导报, 2012, 26(16), 83.
23 Li M F, Zhang J Q, Zhou C G, et al.Surface and Coatings Technology, 2018, 337(15), 68.
24 Norihiko L O, Daisuke K, Masahiro I, et al.Scripta Materialia, 2013, 69(4), 307.
25 Mccafferty E, Zettlemoyer A C.Journal of Physical Chemistry, 1967, 71(8), 2444.
26 Zhang Q, Liu G C, Liu C Y, et al.Materials Protection, 2011, 44(5), 66 (in Chinese).
章强, 刘贵昌, 刘重阳, 等.材料保护, 2011, 44(5), 66.
27 Vourlias G, Piatofidis N, Chaliampalias D, et al.Surface and Coatings Technology, 2006, 200(22-23), 6594.
28 Peng S, Xie S K, Lu J T, et al.Journal of Alloys and Compounds, 2017, 728(25), 1002.