高电压钴酸锂正极材料研究进展

doi:10.11896/cldb.21070223

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Abstract Because of its high specific capacity, discharge platform, and compaction density, lithium cobalt oxide (LiCoO₂) is still the dominant cathode material for lithium-ion batteries in portable electronics such as 3C. With the development of lightweight and miniaturization of portable electronics, the requirements for high energy density and long-cycle performance of lithium-ion batteries with lithium cobalt oxide system have increased. Effective enhancement of energy density is an urgent problem requiring a solution.
The methods to improve energy density include developing new active materials with high specific capacity, increasing the compaction density, and increasing the working voltage of materials. Amongst these methods, the most effective approach is to increase the working voltage. At the upper charge cut-off voltage (>4.4 V), the amount of lithium removed fromlithium cobalt oxide increases and more active Li⁺ participates in the de-intercalation process, which significantly improves the actual gram capacity. However, several detrimental issues including irreversible phase transitions and interfacial side reactions emerge, which result in the degradation of material performance and the rapid loss of capacity. To solve these problems, researchers have modified high-voltage lithium cobalt oxide in recent years. These modifications primarily focus on bulk doping and surface coating. Bulk doping improves the structural stability of the material and delays the collapse of layered structures. Surface coating plays a significant role in alleviating the interfacial side reactions. The effective control of phase transitions and interfacial side reactions by modification is of great significance to promote the commercial development of high-voltage lithium cobalt oxide.
This review focuses on the high-voltage lithium cobalt oxide material. Its structure, preparation method, and performance degradation at high working voltage are summarized. Additionally, recent developments in bulk doping and coating modification of high-voltage lithium cobalt oxide are introduced in detail and the effects of modification on the structure and electrochemical performance of the material are deeply analyzed. Finally, the development of high-voltage lithium cobalt oxide cathode materials is also discussed.

Key words： lithium-ion battery lithium cobalt oxide doping coating

Published: Online: 2023-07-10

CLC number:

TM912

Fund:Independent Research and Development Project of State Key Laboratory of Green Building in Western China (LSZZ202020), Natural Science Basic Research Program of Shaanxi Province (2021JQ-497), Shaanxi Provincial Education Department Service Local Special Plan Project (20JC022), and Natural Science Special Project of Xi'an University of Architecture and Technology (ZR20026).

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	CHEN Xi
	YANG Chunli
	HUANG Jianglong
	ZHANG Hao
	WANG Jing

Cite this article:

CHEN Xi,YANG Chunli,HUANG Jianglong, et al. Research Progress of High Voltage Lithium Cobalt Oxide Cathode Materials[J]. Materials Reports, 2023, 37(13): 21070223-14.

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http://www.mater-rep.com/EN/10.11896/cldb.21070223 OR http://www.mater-rep.com/EN/Y2023/V37/I13/21070223

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