纳米纤维素材料在重金属废水治理中的应用

doi:10.11896/cldb.21030120

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Abstract Cellulose, which is the most widely found natural polymer material, has attracted significant attention in the fields of energy, environment and materials science. Nanocellulose-based heavy metal adsorbent materials, which are prepared by combining renewable biomass materials with nanotechnology, are degradable, regeneratable and environmentally friendly. In addition, they show high adsorption capacity and selective adsorption. Therefore, their synthesis has attracted significant research attention for heavy metal treatment technology.
However, for natural nanocellulose, a large number of hydrogen bonds are formed by hydroxyl groups in aqueous media, which reduce the adsorption and specific adsorption capacities of the material. Therefore, active groups or metal oxides are introduced during the preparation of nanocellulose-based adsorbent materials through chemical modification and enzymatic treatment, among other methods, to improve the dispersion, specific adsorption performance, and adsorption capacity of the materials. In contrast, high-performance composites can be obtained by compounding natural nanocellulose with natural minerals, organic materials, and graphene oxide. The chemical modification of nanocellulose materials has been investigated extensively; however, the enzymatic treatment has not been investigated in detail yet. Specifically, the limited stu-dies so far have focused on the reaction processes and products of specific enzymatic treatments; however, there is a lack of studies focusing on multiple adaptations and engineering applicability analysis. In practical applications, nanocellulose is often directly made into powder adsorbents; however, it is also prepared as gel, hybrid, or composite materials. In some cases, it is further processed into water purification materials, such as nanofiltration membranes, filter papers, and filters.
This paper briefly introduces the latest research progress in the field of nanocellulose-based heavy metal adsorbent materials from the viewpoints of preparation technology, adsorption mechanism, modification enhancement, and application form. This paper focuses on the modification mechanisms, process paths, and application performances of chemical modification and enzymatic treatment of nanocellulose-based adsorbent materials, and it analyzes the common application forms of these materials. Finally, based on the current status of research, this paper discusses the development trend of nanocellulose-based heavy metal adsorbent materials for the treatment of wastewater containing heavy metals to provide references for their applications for heavy metal removal.

Key words： heavy metal nanocellulose adsorbent material modification composite material

Published: Online: 2023-03-27

CLC number:	O636.9
	X703

Fund:National Science and Technology Support Program (2015BAL02B04), the Technology Project of China Housing and Urban Rural Development Ministry (2015-K7-012) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

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	TAO Zhengkai
	JING Zhaoqian
	WANG Zheng

Cite this article:

TAO Zhengkai,JING Zhaoqian,WANG Zheng. Application of Nanocellulose Materials for the Treatment of Wastewater Containing Heavy Metals[J]. Materials Reports, 2023, 37(6): 21030120-8.

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http://www.mater-rep.com/EN/10.11896/cldb.21030120 OR http://www.mater-rep.com/EN/Y2023/V37/I6/21030120

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