INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Ferroelastic Domain Switching Toughening: a Potential High-temperature Toughening Mechanism for Ceramic Coatings |
DU Jinping, WANG Yanfei*, LIU Rongjun, WAN Fan
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Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, National University of Defense Technology, Changsha 410073,China |
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Abstract Ceramic, an irreplaceable material which is used in high temperature and other extreme environmental conditions, has excellent high temperature stability. However, its intrinsic brittleness has seriously restricted the wide application, especially the application in extremely high temperature environment. For example, ceramics can act as thermal barrier coatings (TBCs) for high-performance aero engines. Toughening mechanism of ceramics available at high temperature is relatively scarce, and its high temperature toughening has become a key problem to be solved. Different from the traditional toughening methods of introducing fibers or whiskers, ferroelastic domain switching toughening, an effective toughening mechanism at high temperature, mainly uses the switching process of ferroelastic domain under external force to dissipate the energy driving crack growth. Therefore, it is quite suitable for the toughening of high-temperature ceramic coatings. This article, based on the basic principles of ferroelasticity and ferroelastic domain switching, reviews some progress of ferroelastic domain switching achieved in recent years, and discusses its relative advantages and development prospects. In addition, this article focuses on a detailed introduction of common ferroelastic phases such as yttria-stabilized zirconia(YSZ), rare earth aluminate, rare earth niobate and rare earth tantalate, and prospects the application of related materials. Finally, taking rare earth zirconates as the representative, the research progress of ferroelastics as a second toughening phase is introduced.
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Published: 10 September 2022
Online: 2022-09-10
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Fund:Steadily Supporting Scientific Research of Administration of Science, Technology and Industry for National Defense (WDZC20195500504) and Key Laboratory Foundation of Equipment Pre-research (6142907200303). |
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