可溶液加工对称A-D-A有机小分子太阳能电池给体材料研究进展

doi:10.11896/cldb.20070075

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Abstract Since the 20th century, with the advancement of science and technology, the shortage of traditional fossil energy has brought a series of environmental problems and the development of pollution-free renewable energy has become a hot-topic research all over the world. Traditio-nal solar cells based on inorganic semiconducting materials such as silicon, have demerits of complicated production process, highcost and environmental pollution. In the past decades, the research of organic small molecule solar cells with good photoelectric performance have received extensive attention in the field of organic photovoltaics, presenting huge potential in modern photoelectrical applications.At present, the power conversion efficiency of organic solar cells based on small molecules have been boosted over 16%—17%.
As an important part of the active layer in organic solar cells, electron donor materials are key components for further industrial application in organic photovoltaics. Solution-processable small molecule donor materials effectively combined with electron acceptor materials are able to not only optimize the light absorption capacity of the device but also adjust the electrochemical energy level of both materials, which is critical to improve the photoelectric conversion efficiency of solar cells. At present, organic small molecule donor materials can be classified into asymmetric electron push-pull molecule and symmetric donor-acceptor-donor (or acceptor-donor-acceptor molecule, A-D-A molecule). Among them, symmetrical molecules based on thiophene derivatives have get much attention due to their good conjugated planar structure, high charge transfer mobility and molecular structure modifiability.
In this paper, solution-processable donor materials with symmetric A-D-A structures, including oligopolythiophene, benzodithiophene, diketopyrrolopyrrole, dithienosilole and porphyrin donor materials, are summarized. The aim of this paper is to expound the research progress of existing donor materials, compare and analyze the advantages and disadvantages of various small molecule donor materials, and forecast the development trend and research prospect of small molecule donor materials in the field of organic photovoltaics.

Key words： small molecule solar cell donor material active layer power conversion efficiency

Published: Online: 2022-05-24

CLC number:

TM914.4

Fund:National Natural Science Foundation of China (21762033), Natural Science Foundation of Inner Mongolia (2021MS02025 ,2021 MS05047), High-level Funding Project of Ministry of Human Resources and Social Security of China, High-level Project of Inner Mongolia Normal University (2015YJRC001).

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	Articles by authors
	FAN Hongzhi
	ALTAN Bolag
	Alata
	NING Jun
	Tana
	Tegusi

Cite this article:

FAN Hongzhi,ALTAN Bolag,Alata, et al. Research Progress of Solution-Processable Symmetric A-D-A Small Molecule Donor Materials for Organic Solar Cells[J]. Materials Reports, 2022, 36(10): 20070075-11.

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http://www.mater-rep.com/EN/10.11896/cldb.20070075 OR http://www.mater-rep.com/EN/Y2022/V36/I10/20070075

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