镁离子电池正极材料的研究现状

doi:10.11896/cldb.20050125

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Abstract Excessive consumption of traditional energy sources such as oil and natural gas has led to increasingly serious environmental pollution and ene-rgy crises. Therefore, it is imperative to develop environmentally friendly, large-scale and efficient energy storage devices to obtain intermittent energy such as wind and solar energy continuously. Among various energy storage technologies, secondary batteries have the best research and development prospects for their advantages of high energy conversion efficiency, long service life, and low cost.
In comparison with the widely studied lithium-ion batteries, the magnesium-ion batteries can theoretically provide more electrons, which makes their capacity 2 to 3 times as large as that of the lithium-ion batteries. Furthermore, magnesium-ion batteries, owing the advantages of abundant resources, environmental friendliness, non-toxicity and low prices, are considered as one potential candidate for portable devices and heavy-duty energy equipment. A lot of studies on magnesium-ion batteries have been carried out since a successful prototype of magnesium-ion battery appeared in early 2000. However, the commercial development of rechargeable magnesium-ion batteries (RMBs) is still hampered by some challenges. At present, due to the high charge density, strong polarization effect and slow diffusion kinetics of Mg²⁺, it is still a great challenge to develop cathode materials that can meet the current commercial needs.
RMBs cathode materials mainly include transition metal sulfides, transition metal oxides, polyanionic compounds and Prussian blue analogs. The transition metal sulfides have a low rigidity structure that is difficult to collapse during the charge-discharge cycle. However, some defects such as ion trapping effect and slow diffusion kinetics are found in transition metal sulfides. Transition metal oxides have higher voltage than sulfides but great structural rigidity and poor cycle performance of them can't be ignored. The polyanionic compounds with mesoporous structure are beneficial to improving the electrochemical performance of RMBs, but the conductivity needs to be improved. The Prussian blue analogue with an open and adjustable structure is conducive to the rapid deintercalation of Mg²⁺ while its compatibility with aqueous electrolytes is poor. In recent years, researchers have mainly optimized the design of cathode materials from the aspects of nanocrystallization, structural adjustment, doping modification and coating modification in response to the present challenges.
In this paper, the domestic and foreign research status of various types of RMBs cathode materials including the information of crystal structure, research status and existing problems is reviewed. Meanwhile, challenges of RMBs cathode materials are also analyzed to provide reference for synthesizing RMBs cathode materials with high energy density and high cycle stability.

Key words： magnesium-ion battery cathode material sulfide oxide polyanionic compound Prussian blue analogs

Published: Online: 2022-04-07

CLC number:

TM912

Fund:Fundamental Research Funds for the Central Universities of Chongqing University (2020CDCGCL005).

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	ZHANG Qin
	HU Yaobo
	WANG Run
	WANG Jun

Cite this article:

ZHANG Qin,HU Yaobo,WANG Run, et al. Research Status of Cathode Materials for Magnesium-Ion Batteries[J]. Materials Reports, 2022, 36(7): 20050125-11.

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http://www.mater-rep.com/EN/10.11896/cldb.20050125 OR http://www.mater-rep.com/EN/Y2022/V36/I7/20050125

1 Andrews J L, Mukherjee A, Yoo H D, et al. Chemistry,2018,4(3),564.
2 Canepa P, Gautam G S, Hannah D C, et al. Chemical Reviews, 2017, 117(5), 4287.
3 Pang Q, Sun C, Yu Y, et al. Advanced Energy Materials, 2018, 8(19), 1800144.
4 Ding J, Du Z, Gu L, et al. Advanced Materials, 2018, 30(26), 1800762.
5 Gregory T D, Hoffman R J, Winterton R C. Journal of the Electrochemical Society, 1990, 137(3), 775.
6 Aurbach D, Lu Z, Schechter A, et al. Nature,2000,407(6805),724.
7 Huie M M, Bock D C, Takeuchi E S, et al. Coordination Chemistry Reviews, 2015, 287, 15.
8 Muldoon J, Bucur C B, Gregory T. Chemical Reviews, 2014, 114(23), 11683.
9 Song J, Sahadeo E, Noked M, et al. Journal of Physical Chemistry Letters, 2016, 7(9), 1736.
10 Yoo H D, Shterenberg I, Gofer Y, et al. Energy & Environmental Science, 2013, 6(8), 2265.
11 Wang L, Vullum P E, Asheim K, et al. Nano Energy, 2018, 48, 227.
12 Wang L, Jiang B, Vullurn P E, et al. ACS Nano, 2018, 12(3), 2998.
13 Levi E, Gofer Y, Aurbach D. Chemistry of Materials,2010,22(3),860.
14 Cheng Y, Shao Y, Raju V, et al. Advanced Functional Materials, 2016, 26(20), 3446.
15 Rong Z, Malik R, Canepa P, et al. Chemistry of Materials, 2015, 27(17), 6016.
16 Peng B, Liang J, Tao Z, et al. Journal of Materials Chemistry, 2009, 19(19), 2877.
17 Feng Z Z, Yang J, NuLi Y N, et al. Electrochemistry Communications, 2008, 10(9), 1291.
18 NuLi Y N, Zheng Y P, Wang F, et al. Electrochemistry Communications, 2011, 13(10), 1143.
19 Zhao X, Zhao Z, Miao Y. Materials Research Bulletin, 2018, 101, 1.
20 Richard J, Benayad A, Colin J F, et al. Journal of Physical Chemistry C, 2017, 121(32), 17096.
21 Levi M D, Lancri E, Levi E, et al. Solid State Ionics, 2005, 176(19-22), 1695.
22 Levi E, Lancry E, Mitelman A, et al. Chemistry of Materials, 2006, 18(23), 5492.
23 Levi E, Gershinsky G, Aurbach D, et al. Chemistry of Materials, 2009, 21(7), 1390.
24 Wan L F, Wright J, Perdue B R, et al. Physical Chemistry Chemical Physics, 2016, 18(26), 17326.
25 Levi M D, Gizbar H, Lancry E, et al. Journal of Electroanalytical Chemistry, 2004, 569(2), 211.
26 Thoele F, Wan L F, Prendergast D. Physical Chemistry Chemical Physics, 2015, 17(35), 22548.
27 Liu B, Luo T, Mu G, et al. ACS Nano, 2013, 7(9), 8051.
28 Lancry E, Levi E, Gofer Y, et al. Chemistry of Materials, 2004, 16(14), 2832.
29 Lancry E, Levi E, Mitelman A, et al. Journal of Solid State Chemistry, 2006, 179(6), 1879.
30 Saha P, Jampani P H, Datta M K, et al. Journal of the Electrochemical Society, 2014, 161(4), A593.
31 Murgia F, Antitomaso P, Stievano L, et al. Journal of Solid State Chemistry, 2016, 242, 151.
32 Aurbach D, Suresh G S, Levi E, et al. Advanced Materials, 2007, 19(23), 4260.
33 Amatucci G G, Badway F, Singhal A, et al. Journal of the Electrochemical Society, 2001, 148(8), A940.
34 Emly A, Van der Ven A. Inorganic Chemistry, 2015, 54(9), 4394.
35 Tao Z L, Xu L N, Gou X L, et al. Chemical Communications, 2004, 18, 2080.
36 Amir N, Vestfrid Y, Chusid O, et al. Journal of Power Sources, 2007, 174(2), 1234.
37 Sun X, Bonnick P, Nazar L F. ACS Energy Letters, 2016, 1(1), 297.
38 Novak P, Imhof R, Haas O. Electrochimica Acta, 1999, 45(1-2), 351.
39 Novak P, Desilvestro J. Journal of the Electrochemical Society, 1993, 140(1), 140.
40 Gu Y, Katsura Y, Yoshino T, et al. Scientific Reports, 2015, 5, 986.
41 Li X L, Li Y D. Journal of Physical Chemistry B, 2004, 108(37), 13893.
42 Liang Y, Feng R, Yang S, et al. Advanced Materials,2011,23(5),640.
43 Yang S, Li D, Zhang T, et al. Journal of Physical Chemistry C, 2012, 116(1), 1307.
44 Liang Y, Yoo H D, Li Y, et al. Nano Letters, 2015, 15(3), 2194.
45 Liu Y, Jiao L, Wu Q, et al. Journal of Materials Chemistry A, 2013, 1(19), 5822.
46 Liu Y, Jiao L, Wu Q, et al. Nanoscale, 2013, 5(20), 9562.
47 Liu Y, Fan L Z, Jiao L. Journal of Power Sources, 2017, 340, 104.
48 Pereira-Ramos J P, Messina R, Perichon J. Journal of Electroanalytical Chemistry, 1987, 218(1-2), 241.
49 Shklover V, Haibach T, Ried F, et al. Journal of Solid State Chemistry, 1996, 123(2), 317.
50 Jiao L F, Yuan H T, Si Y C, et al. Journal of Power Sources, 2006, 156(2), 673.
51 Jiao L F, Yuan H T, Wang Y J, et al. Electrochemistry Communications, 2005, 7(4), 431.
52 Jiao L F, Yuan H T, Si Y C, et al. Electrochemistry Communications, 2006, 8(6), 1041.
53 Imamura D, Miyayama M. Solid State Ionics, 2003, 161(1-2), 173.
54 Imamura D, Miyayama M, Hibino M, et al. Journal of the Electrochemical Society, 2003, 150(6), A753.
55 Bervas M, Klein L C, Amatucci G G. Solid State Ionics, 2005, 176(37-38), 2735.
56 Stojkovic I, Cvjeticanin N, Markovic S, et al. Acta Physica Polonica A, 2010, 117(5), 837.
57 Lee S H, DiLeo R A, Marschilok A C, et al. ECS Electrochemistry Letters, 2014, 3(8), 87.
58 Lee C Y, Marschilok A C, Subramanian A, et al. Physical Chemistry Chemical Physics, 2011, 13(40), 18047.
59 Tang P E, Sakamoto J S, Baudrin E, et al. Journal of Non-Crystalline Solids, 2004, 350, 67.
60 Kim R H, Kim J S, Kim H J, et al. Journal of Materials Chemistry A, 2014, 2(48), 20636.
61 Perera S D, Archer R B, Damin C A, et al. Journal of Power Sources, 2017, 343, 580.
62 Du X, Huang G, Qin Y, et al. RSC Advances, 2015, 5(93), 76352.
63 An Q, Li Y, Yoo H D, et al. Nano Energy, 2015, 18, 265.
64 Park O K, Cho Y, Lee S, et al. Energy & Environmental Science, 2011, 4(5), 1621.
65 Kumagai N, Komaba S, Sakai H, et al. Journal of Power Sources, 2001, 97, 515.
66 Zhang R, Yu X, Nam K W, et al. Electrochemistry Communications, 2012, 23, 110.
67 Rasul S, Suzuki S, Yamaguchi S, et al. Solid State Ionics, 2012, 225, 542.
68 Rasul S, Suzuki S, Yamaguchi S, et al. Electrochimica Acta, 2012, 82, 243.
69 Wang M, Yagi S. Journal of Alloys and Compounds, 2020, 820, 153135.
70 Sinha N N, Munichandraiah N. Electrochemical and Solid State Letters, 2008, 11(11), 23.
71 Kurihara H, Yajima T, Suzuki S. Chemistry Letters, 2008, 37(3), 376.
72 Fong C, Kennedy B J, Elcombe M M. Zeitschrift Fur Kristallographie, 1994, 209(12), 941.
73 Yuan C, Zhang Y, Pan Y, et al. Electrochimica Acta, 2014, 116, 404.
74 Malavasi L, Ghigna P, Chiodelli G, et al. Journal of Solid State Chemistry, 2002, 166(1), 171.
75 Zhang R, Arthur T S, Ling C, et al. Journal of Power Sources, 2015, 282, 630.
76 Okamoto S, Ichitsubo T, Kawaguchi T, et al. Advanced Science, 2015, 2(8), 1500072.
77 Cabello M, Alcantara R, Nacimiento F, et al. Crystengcomm, 2015, 17(45), 8728.
78 Ling C, Mizuno F. Chemistry of Materials, 2013, 25(15), 3062.
79 Liu M, Rong Z, Malik R, et al. Energy & Environmental Science, 2015, 8(3), 964.
80 Wang H G, Yuan S, Ma D L, et al. Energy & Environmental Science, 2015, 8(6), 1660.
81 Wang Z, Ruan Z, Ng W S, et al. Small Methods, 2018, 2(10), 1800150.
82 Spahr M E, Novak P, Haas O, et al. Journal of Power Sources, 1995, 54(2), 346.
83 Pandey G P, Agrawal R C, Hashmi S A. Journal of Solid State Electrochemistry, 2011, 15(10), 2253.
84 Gershinsky G, Yoo H D, Gofer Y, et al. Langmuir, 2013, 29(34), 10964.
85 Incorvati J T, Wan L F, Key B, et al. Chemistry of Materials, 2016, 28(1), 17.
86 Mao M, Gao T, Hou S, et al. Chemical Society Reviews, 2018, 47(23), 8804.
87 Wan L F, Incorvati J T, Poeppelmeier K R, et al. Chemistry of Mate-rials, 2016, 28(19), 6900.
88 Kaveevivitchai W, Jacobson A J. Chemistry of Materials, 2016, 28(13), 4593.
89 Jin J, Wu L, Huang S, et al. Small Methods, 2018, 2(11), 1800171.
90 Chatterjee S, Sengupta S, Saha-Dasgupta T, et al. Physical Review B, 2009, 79(11), 115103.
91 Heath J, Chen H, Islam M S. Journal of Materials Chemistry A, 2017, 5(25), 13161.
92 Feng Z, Yang J, NuLi Y, et al. Journal of Power Sources, 2008, 184(2), 604.
93 NuLi Y N, Yang J, Wang J L, et al. Journal of Physical Chemistry C, 2009, 113(28), 12594.
94 NuLi Y N, Yang J, Li Y, et al. Chemical Communications, 2010, 46(21), 3794.
95 Nuli Y N, Yang J, Zheng Y P, et al. Journal of Inorganic Materials, 2011, 26(2), 129.
96 Mori T, Masese T, Orikasa Y, et al. Physical Chemistry Chemical Physics, 2016, 18(19), 13524.
97 Truong Q D, Devaraju M K, Honma I. Journal of Power Sources, 2017, 361, 195.
98 Li Y, Nuli Y N, Yang J, et al. Chinese Science Bulletin, 2011, 56(4-5), 386.
99 Orikasa Y, Masese T, Koyama Y, et al. Scientific Reports, 2014, 4, 5622.
100 Zheng Y P, NuLi Y N, Chen Q, et al. Electrochimica Acta, 2012, 66, 75.
101 Chen X, Bleken F L, Lovvik O M, et al. Journal of Power Sources, 2016, 321, 76.
102 Delmas C, Nadiri A, Soubeyroux J L. Solid State Ionics, 1988, 28, 419.
103 Ong S P, Chevrier V L, Hautier G, et al. Energy & Environmental Science, 2011, 4(9), 3680.
104 Shi J J, Yin G Q, Jing L M, et al. International Journal of Modern Physics B, 2014, 28(26), 1450176.
105 Kang J, Chung H, Doh C, et al. Journal of Power Sources, 2015, 293, 11.
106 Goodenough J B, Hong H Y P, Kafalas J A. Materials Research Bulletin, 1976, 11(2), 203.
107 Yin S C, Grondey H, Strobel P, et al. Journal of the American Chemical Society, 2003, 125(34), 10402.
108 Anuar N K, Adnan S B R S, Mohamed N S. Ceramics International, 2014, 40(8), 13719.
109 Imanaka N, Okazaki Y, Adachi G. Journal of Materials Chemistry, 2000, 10(6), 1431.
110 Makino K, Katayama Y, Miura T, et al. Journal of Power Sources, 2001, 99(1-2), 66.
111 Huang Z D, Masese T, Orikasa Y, et al. RSC Advances, 2015, 5(12), 8598.
112 Makino K, Katayama Y, Miura T, et al. Journal of Power Sources, 2001, 97, 512.
113 Makino K, Katayama Y, Miura T, et al. Journal of Power Sources, 2002, 112(1), 85.
114 Takahashi H, Takamura H. Materials Integration, 2012, 508, 291.
115 Zeng J, Yang Y, Lai S, et al. Chemistry-A European Journal, 2017, 23(66), 16898.
116 Cabello M, Alcantara R, Nacimiento F, et al. Electrochimica Acta, 2017, 246, 908.
117 Mizuno Y, Okubo M, Hosono E, et al. Journal of Materials Chemistry A, 2013, 1(42), 13055.
118 Wessells C D, Peddada S V, Huggins R A, et al. Nano Letters, 2011, 11(12), 5421.
119 Kim D M, Kim Y, Arumugam D, et al. ACS Applied Materials & Interfaces, 2016, 8(13), 8554.
120 Wessells C D, Huggins R A, Cui Y. Nature Communications, 2011, 2, 550.
121 Buser H J, Schwarzenbach D, Petter W, et al. Inorganic Chemistry, 1977, 16(11), 2704.
122 Wang R Y, Wessells C D, Huggins R A, et al. Nano Letters, 2013, 13(11), 5748.
123 Novak P, Scheifele W, Joho F, et al. Journal of the Electrochemical Society, 1995, 142(8), 2544.
124 Yu L, Zhang X G. Journal of Colloid and Interface Science, 2004, 278(1), 160.
125 Sun X, Bonnick P, Duffort V, et al. Energy & Environmental Science, 2016, 9(7), 2273.
126 Xu Y, Deng X, Li Q, et al. Chem, 2019, 5(5), 1194.
127 Sun X, Duffort V, Mehdi B L, et al. Chemistry of Materials, 2016, 28(2), 534.