METALS AND METAL MATRIX COMPOSITES |
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Advances in High Corrosion Resistant Rebar for Ocean Engineering |
QIN Fangcheng1, QI Haiquan1, MENG Zhengbing1, CHEN Ping1, HUANG Yuhong2
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1 College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, Guangxi, China 2 Guangxi Shenglong Metallurgical Co.,Ltd., Fangchenggang 538004, Guangxi, China |
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Abstract With the implementation of the development strategy of national maritime power and seaward economy, the rapid development of major marine projects in Beibu gulf, the south China seas and the ASEAN coastal areas is facilitated. As an important basic material for marine construction, maritime reinforced concrete has been widely used in coastal infrastructures including ports and wharves, cross-sea bridges, subsea tunnel, artificial island, offshore drilling platform, etc. The increasing market demand of rebar for ocean engineering is also given. Due to the complex marine environment such as high temperature, high humidity and high salt and fog, problems including corrosion, paint peeling, cracking and rapid functional failure of steel bar materials are presented. The durability and service life of concrete and marine enginee-ring structures are directly related to the corrosion resistance of rebar. The new challenges to the traditional ocean engineering materials are proposed. Thus, it is urgent to conduct a study on the corrosion resistance of marine steel bar materials. The numerous investigation and fruitful results of the corrosion behavior and structural durability of steel reinforcement in marine engineering have been carried out by scholars at home and abroad in the last decade. The traditional low carbon steel rebar with limited corrosion-resistance are mainly characterized by uniform corroding in a large area. The bonding force between rebar and concrete structure is reduced, and the rust swelling, cracking and spalling are caused. Due to the local pitting, the critical concentration of Cl- is high and the corrosion rate is low in the stainless steel rebar. However, the total content of Cr and Ni is as high as 20%, leading to the high cost. For the coated/plated steel rebar, the corrosion of concrete and its surrounding erosion media are prevented. However, the cracking tendency increases with the concrete strength and the thickness of protective layer increasing. The low alloyed rebar is mainly characterized by the double layer passivation films, high Cl- corrosion-resistance and high stability of rust layer, of which Cr and Ni increase the passivation interval and provide high stability of rust layer, and its corrosion rate is far lower compared with that in low carbon steel rebar. Therefore, the increasing applications of alloyed marine steel rebar with high corrosion-resistance in the major projects such as ports, wharves, and cross-sea bridges are achieved. In this paper, the advances in rebar materials for ocean engineering are summarized; the characteristics, microstructures, corrosion behavior and properties, and the corrosion mechanisms in the rebar are expounded; the change rule of microstructure of rebar rust layer in the actual marine corrosion conditions is clarified; the corrosion resistant mechanisms in low alloying rebar are revealed. The existing problems in the high corrosion resistant rebar research are pointed out. Furthermore, the necessity of developing low alloyed rebar and its research direction in corrosion resistance properties are put forward to provide theoretical basis for the research and application of high corrosion resistant rebar.
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Published: 25 March 2022
Online: 2022-03-21
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Fund:National Natural Science Foundation of China (51875383), Innovation and Driven Project of Guangxi (GK AA18242007), Natural Science Foundation of Guangxi (2019GXNSFAA245051, 2018GXNSFBA281056) and Research Foundation of Guilin University of Technology (GUTQDJJ2017140). |
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