INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
|
|
|
|
|
The Influence of Metakaolin on the Hydration of Steam-cured Steel Slag Blended Cement |
HUANG Shiyu, HUO Binbin, CHEN Chun, ZHANG Yamei
|
Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China |
|
|
Abstract The effects of metakaolin on early hydration and mechanical properties of steam-cured steel slag blended cement-based materials (steam-cured at 60℃ for 12h) were investigated. The results show that, with the incorporation of metakaolin under the optimum dosage, the mechanical strength of steam-cured steel slag blended cement mortar is significantly enhanced, which is comparable to that of pure cement mortar. The early hydration process of steam-cured steel slag blended cement is accelerated with metakaolin, as well as the consumption of sulfate, lea-ding to the formation of AFm phases. The amount of C-S-H and C-A-S-H gel of steam-cured ternary Portland cement blends containing steel slag and metakaolin is increased while carbon aluminate is observed to fix active Al2O3, which is beneficial to the stability of ettringite. Additionally, the pore distribution of steel slag blended cement containing metakaolin under steam curing is refined, leading to a denser matrix.
|
Published: 10 March 2022
Online: 2022-03-08
|
|
Fund:National Natural Science Foundation of China (51778132) and the “333 Project” Funded by Jiangsu Province in 2020 (BRA2020221). |
|
|
1 National Bureau of Statistics of the People's Republic of China. China statistical yearbook. China Statistics Bureau Press, China, 2019(in Chinese). 中华人民共和国统计局.中国统计年鉴.中国统计局出版社,2019. 2 Xu Y, Zhang Z Z, Wang B, et al. Concrete, 2018(5),76(in Chinese). 许莹,张孜孜,王变,等. 混凝土,2018(5),76. 3 Shi C J. Journal of Materials in Civil Engineering, 2004, 16(3),230. 4 Wang Q, Yan P Y, Yang J W, et al. Construction and Building Mate-rials, 2013,47,1414. 5 Xu Y H, Lu W X, Wang X J, et al. Journal of Shanghai University (Natural Science), 2004(1),91(in Chinese). 许远辉,陆文雄,王秀娟,等.上海大学学报(自然科学版),2004(1),91. 6 Wang Q. Cementitious properties of steel slag and its role in the hydration and hardening process of complex binder. Ph.D Thesis, Tsinghua University, China, 2010(in Chinese). 王强.钢渣的胶凝性能及在复合胶凝材料水化硬化过程中的作用. 博士学位论文, 清华大学, 2010. 7 Han F H, Liu J H, He X J, et al. Journal of Southeast University,2017, 33(3),277. 8 Guo X L, Shi H S. Journal of Materials in Civil Engineering, 2013,25(12),1990. 9 Liu J, Wang D M. Powder Technology, 2017, 320,230. 10 Wild S, Khatib J M, Jones A. Cement and Concrete Research, 1996,26(10),1537. 11 Xu W W, He Z M, Liu J Z, et al. Bulletin of The Chinese Ceramic Society, 2017,36(1),20(in Chinese). 徐雯雯,贺智敏,柳俊哲,等.硅酸盐通报, 2017,36(1),20. 12 Shen P L, Lu L N, Chen W, et al. Construction and Building Materials, 2017,152,357. 13 Bai T, Song Z G, Wu Y G, et al. Ceramics International, 2018, 44(13),15706. 14 Chen Y X, Li L. Concrete, 2017(1),82(in Chinese). 陈玉香, 李璐. 混凝土, 2017(1),82. 15 Han F H,Liu R G,Wang D M,et al.Thermochimica Acta,2014,586,52. 16 Zhuang S Y, Wang Q. Cement and Concrete Research, 2021,140,106283. 17 Han F H, Zhang Z Q, Wang D M, et al. Thermochimica Acta, 2015, 605,43. 18 Martin Bohácˇ, Martin Palou, Radoslav Novotny,et al. Journal of Thermal Analysis and Calorimetry, 2017, 127(1),309. 19 Zemlicka M, Kuzielova E, Kuliffayova M, et al. Ceramics Silikaty, 2015, 59,283. 20 Kirk V, Matthew A, Tandre O, et al. Cement Concrete Composites, 2013, 39,93. 21 Wei J Q, Gencturk B.Cement and Concrete Research,2019,123,105772. 22 Li B L, Wang Y H, Yang L, et al. Journal of Sustainable Cement Based Materials, 2019, 8(6),353. 23 Tang M S, Yuan M Q, Han S F, et al. Journal of the Chinese Ceramic Society, 1979(1),35(in Chinese). 唐明述,袁美栖,韩苏芬,等.硅酸盐学报,1979(1),35. 24 Antoni M,Rossen J,Martirena F, et al. Cement and Concrete Research, 2012, 42(12),1579. 25 Scholer A, Lothenbach B, Winnefeld F, et al. Cement and Concrete Composites, 2015,55,374. 26 Kakali G, Tsivilis S, Aggeli E, et al. Cement and Concrete Research, 2000, 30(7),1073. 27 Coleman N J, Mcwhinnie W R. Journal of Materials Science, 2000, 35(11),2701. 28 Song F, Yu Z L, Yang F L, et al. Ceramics-Silikáty, 2014,58(4),269. 29 Tang J, Wei S F, Li W F,et al. Construction and Building Materials, 2019, 223,177. 30 Mo Z Y, Wang Rui, Gao X J. Construction and Building Materials, 2020, 256,119454. 31 Wu Z W, Lian H Z. High performance concrete. China Railway Publis-hing House, China, 1999(in Chinese). 吴中伟, 廉慧珍.高性能混凝土.中国铁道出版社, 1999. |
|
|
|