生物酶与化学催化剂结合在合成手性化合物中的应用

doi:10.11896/cldb.20040218

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Abstract Chiral compounds have already presented unique advantages in many fields, such as medicine field, material field, etc. In face of the increasingly requirements for optical pure compounds, many methods have been developed. Among them, catalytic cycle involving chemical enzyme and multienzyme attracted more and more attention due to the advantages of environment-friendly process, high selectivity, and mild conditions. In this paper, the latest development of the cyclic network for the synthesis of optically pure compounds is reviewed, including three methods. (1) Dynamic kinetic resolution (DKR): most of the research work focused on the resolution of secondary alcohols, especially aromatic secondary alcohols. However, chiral resolution of anines is still challenging problems. (2) Minor enantiomer recycling (MER): it is a new reaction mode in the field of chiral synthesis and has been successfully applied to the synthesis of chiral cyanohydrin esters and cyclic chiral amines. (3) Cyclic deracemisation (CyD): this is an attractive method for the synthesis of chiral amines.

Key words： chiral compound lipase racemization cycle

Published: 25 January 2022 Online: 2022-01-26

CLC number:	O622.3
	O622.6

Fund:National Natural Science Foundation of China (21606069) and Natural Science Foundation of Hebei Province of China (B2017202187).

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	ZHANG Yuanyuan
	WEN Yeqian

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ZHANG Yuanyuan,WEN Yeqian. Application of Biological Enzyme and Chemical Catalyst in Synthesis of Chiral Compounds[J]. Materials Reports, 2022, 36(2): 20040218-10.

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http://www.mater-rep.com/EN/10.11896/cldb.20040218 OR http://www.mater-rep.com/EN/Y2022/V36/I2/20040218

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