基于分子结构设计的高性能聚酰亚胺的研究进展

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Abstract With the rapid development of science and technology, the materials needed in the fields of photovoltaic cells need not only good high temperature resistance, but also high light transmittance. Although polyimide (PI) material has superior high-temperature resistance than other polymers, its highly conjugated rigid molecular chains are prone to form charge transfer complex (CTC), which makes its high-temperature resistance and light transmittance become two contradictory properties. By designing the molecular structure of PI, the generation of CTC can be effectively reduced. As a result, the two kinds of contradictory properties can be balanced and the comprehensive performance of PI material can be maximized. The research of enhancing the comprehensive performance of PI materials by molecular structure design has been widely concerned by researchers at home and abroad. In this paper, the relationships between the main chain, side group, nonplanar structure and end group of PI and its performance are reviewed based on the most representative high temperature resistance and light transmission capacity of PI. The law and relation between different structures and properties are analyzed. Finally, the future development trend of PI materials is prospected.

Key words： polyimide molecular structure design thermal stability optical property

Published: 09 December 2021

CLC number:

TQ31

Fund:This work was financially supported by the National Natural Science Foundation of China(51573136), Key Project of Natural Science Foundation of Tianjin(20JCZDJC00350).

About author:: Zizhen Liu received his bachelor of engineering degree in Materials Science and Engineering from Tiangong University from September 2016 to June 2020. He has been studying at School of Materials Science and Engineering, Tiangong University from September 2020 to present. His research interest is dye-sensitized solar cells.
Xin Jin, doctor of engineering, professor. Her major is Material Science and Engineering, and her research direction is functional fiber structure and properties, nonwovens forming technology and application, fiber reinforced composites.

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	LIU Zizhen
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	WANG Wenyu
	NIU Jiarong

Cite this article:

LIU Zizhen,JIN Xin,WANG Wenyu, et al. Research Progress of High Performance Polyimides Based on Molecular Structure Design[J]. Materials Reports, 2021, 35(z2): 600-611.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2021/V35/Iz2/600

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