水性醇酸树脂/中空TiO<sub>2</sub>微球复合涂层的性能

doi:10.11896/cldb.20040157

Abstract
Figure/Table
References
Related Citation (5)

Download:

Full Text ( PDF ) (3701KB)
Export: BibTeX | EndNote (RIS)

Abstract Water-borne alkyd resin was prepared using soybean oleic acid, trimethyl-propane, phthalic anhydride and trimellitic anhydride as raw mate-rials. Hollow TiO₂ microspheres with different particle sizes were introduced into water-borne alkyd resin by physical blending method to obtain water-borne alkyd resin/hollow TiO₂ microspheres composite coating. The effects of particle size of hollow TiO₂ microspheres on water contact angle, salt water resistance, electrochemical properties, adhesion and pencil hardness of water-borne alkyd resin coating were investigated. The results showed that the particle size of hollow TiO₂ microspheres was played a vital role for the properties of water-borne alkyd resin coa-ting. When the particle size of hollow TiO₂ microspheres was 200 nm, the water contact angle of the composite coating reached 106°, and its salt water resistance reached more than 120 h. Compared with the coating of water-borne alkyd resin, the electrochemical impedance of the composite coating was improved two orders, which exhibited prominent anti-corrosion performance. Moreover, the adhesion and pencil hardness of the composite coating was grade 0 and 5H, respectively.

Key words： water-borne alkyd resin hollow TiO₂ microspheres electrochemical property salt water resistance property

Published: 30 September 2021

CLC number:

TQ323

Fund:This work was financially supported by the National Natural Science Foundation of China (21878181), the Key Research and Development Program of Shaanxi Province (2018ZDXM-GY-118).

About author:: Yan Bao, Shaanxi University of Science and Technology, a professor in the College of Bioresources Chemical & Materials Engineering, the list for new century excellent talents to support the Ministry of Education program, won the national May 1 women's certificates, the national worker pioneer, “high-level personnel special support program” youth talent of young and middle-aged leading science and technology innovation talents, Shaanxi Province, Shaanxi provincial youth science and technology nova, youth science May 4th youth medal nomination, Shaanxi University of Science and Technology outstanding teachers and other honorary titles. Mainly engaged in the synthesis of green leather chemicals and the role of collagen fibers, orga-nic/inorganic nanocomposite functional chemicals.

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	BAO Yan
	DING Ying
	TANG Pei
	KANG Qiaoling

Cite this article:

BAO Yan,DING Ying,TANG Pei, et al. Properties of Water-borne Alkyd Resin/Hollow TiO₂ Microsphere Composite Coating[J]. Materials Reports, 2021, 35(18): 18200-18204.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.20040157 OR http://www.mater-rep.com/EN/Y2021/V35/I18/18200

1 Li C L, Theo V, Bart R, et al.Polymer International, 2019, 806(14), 110.
2 Amo B D, Romagnoli R, Vetere V F, et al.Corrosion Reviews, 2011, 14(1-2), 121.
3 Christel P, Jesus F O, Maxime R, et al.Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 536, 114.
4 Murillo E A. Journal of Applied Polymer Science, 2020, 137, 209.
5 Li C, Veldhuis T, Reuvers B, et al.Polymer International, 2020, 256(56), 968.
6 Wang C C, Lin G, Pae J H, et al.Journal of Coatings Technology, 2012, 72(904), 55.
7 Teng Y, Wen J L, Tao Z, et al. Journal of Functional Materials, 2015, 558 (78), 24.
8 Rokicki G, Lukasik L.Surface Coatings International Part B:Coatings Transactions, 2011, 84(3), 223.
9 Zhong X, Sun H.Chemical Materials for Construction, 2007, 23(5), 17.
10 Abdulagatov A I, Yan Y, Cooper J R, et al.ACS Applied Materials & Interfaces, 2011, 3(12), 4593.
11 Bachmann W E, Wick L B.Journal of the American Chemical Society, 1950, 72(5), 2000.
12 Qiang Z H, Chen X L, Zhao J H, et al.Paint Coatings Industry, 2019, 49(5), 22.
13 Mishra V K, Patel K I.Journal of Dispersion Science and Technology, 2015, 36(7), 1036.
14 Wang Q, Pellegrene B, Soucek M D.Industrial & Engineering Chemistry Research, 2018, 57(36), 12018.
15 El-Bindary A, Kiwaan H, Shoair A G, et al.Pigment & Resin Technology, 2019, 49(2), 102.
16 Pathan S, Ahmad S.ACS Sustainable Chemistry & Engineering, 2016, 4, 3062.
17 Dong W W, Yi Y.Modern Paint & Finishing, 2013, 16 (3), 1(in Chinese).
董维维, 易英. 现代涂料与涂装, 2013, 16(3), 1.
18 Uzoh C F,Obodo N J, Onukwuli O D.Journal of King Saud University Engineering Sciences, 2016, 30(1), 12.
19 Bao Y, Kang Q L.Journal of Inorganic Materials, 2017,32 (6), 581 (in Chinese).
鲍艳, 康巧玲. 无机材料学报, 2017, 32(6), 581.
20 Saravari O, Phapant P, Pimpan V.Journal of Applied Polymer Science, 2005, 96(4), 1170.
21 Kienle R H, Ferguson C S.Industrial & Engineering Chemistry, 2013, 21(4), 349.
22 Hovey A G.Industrial & Engineering Chemistry, 2013, 25(6), 613.
23 Kordzangeneh S, Naghibi S, Esmaeili H.Journal of Materials Engineering and Performance, 2018, 27(1), 219.
24 Hofland A.Progress in Organic Coatings, 2012, 73(4), 274.
25 Zheng S L, Li C, Fu Q T, et al.Materials & Design, 2016, 93, 261.
26 Sun H G, Xiao H H, Song W, et al.Journal of Alloys and Compounds, 2019, 805, 984.
27 Wang G Y, Wen S G, Wang J H, et al.Journal of Shanghai University of Engineering Science, 2019, 33(3), 219 (in Chinese).
王光宇, 温绍国, 王继虎, 等. 上海工程技术大学学报, 2019, 33(3), 219.
28 Mishra V K,Patel K I. Journal of Dispersion Science and Technology, 2015, 36(7), 1036.
29 Godfrey O O, Ifijen I H, Mohammed F U, et al.Heliyon, 2019, 5(5), 1639.
30 William W, Blont J R, Thauming K U O. U. S. patent, 5378757, 2017.
31 Zhou L Q, Pan C Y, Liu S B, et al.Modern Paint & Finishing, 2011, 12(10), 19 (in Chinese).
周丽琼, 潘春跃, 刘寿兵, 等. 现代涂料与涂装, 2011, 12(10), 19.
32 Shi C. China Paint, 2013, 34(22), 2697.
33 Zhong X, Sun H.Green Building, 2007, 23(5), 17 (in Chinese).
钟鑫, 孙慧. 绿色建筑, 2007, 23(5), 17.
34 Billiani J, Gobce M. U. S. patent, 5698625, 2017.
35 Shui X, Shen Y, Fei G, et al.Journal of Applied Polymer Science, 2015, 132(5), 2011.
36 Rahman O U, Bhat S I, Yu H, et al.ACS Sustainable Chemistry & Engineering, 2017, 5(11), 9725.
37 Elrebii M, Boufi S.Journal of Industrial & Engineering Chemistry, 2014, 20(5), 3631.
38 Elrebii M, Kamoun A, Boufi S.Progress in Organic Coatings, 2015, 87, 222.
39 Das P, Sharma N, Puzari A, et al.Polymer Bulletin, 2020,78(4), 214.
40 Rui G, Wang H H. Wang G Q, et al.Applied Surface Science, 2019, 481, 960.
41 Chiplunkar P P, Pratap A P.Progress in Organic Coatings, 2016, 93, 61.
42 Hubert J C, Klaasen R P, Muizebelt W J, et al.Journal of Coatings Technology, 2017, 69(869), 59.
43 Hirt R C, Stafford R W, King F T, et al.Analytical Chemistry, 2015, 27(2), 226.
44 Kurt L, Acar I, Gamze G.Progress in Organic Coatings, 2014, 77(5), 949.
45 Irfan M, Bhat S I, Ahmad S.ACS Sustainable Chemistry & Engineering, 2018, 6(25), 14820.
46 Dannenberg H, Bradley T F, Evans T W.Industrial and Engineering Chemistry, 2014, 41(8), 1709.
47 Flores S, Flores A, Carlos C, et al.Progress in Organic Coatings, 2019, 136, 105.
48 Yin X, Duan H, Wang X, et al.Progress in Organic Coatings, 2014, 77(3), 674.
49 Aung M M, Li W J, Lim H N.Industrial & Engineering Chemistry Research, 2020, 59(5), 1753.
50 Biermann U, Butte W, Holtgrefe R, et al.European Journal of Lipid Science & Technology, 2010, 112(1), 103.
51 Challinor J M.Journal of Analytical & Applied Pyrolysis, 2011, 18(3-4), 233.
52 Li P H, Li P L, Zhu G J.Modern Chemical Industry, 2016, 26(589), 236.
53 Muizebelt W J, Hubert J C, Venderbosch R A M.Progress in Organic Coatings, 2017, 24(1-4), 263.
54 Uschanov P, Heiskanen N, Mononen P, et al.Progress in Organic Coa-tings, 2008, 63(1), 92.
55 Wang Y, Lv B, Wang E, et al.Journal of Functional Materials and Devices, 2011(5), 450.
王毅, 吕滨, 王恩德, 等. 功能材料与器件学报, 2011(5), 450.
56 Huang Q, Liu C, Chen S, et al.Progress in Organic Coatings, 2015, 87, 189.
57 Hadzich A, Flores S, Caprari J, et al.Progress in Organic Coatings, 2018, 117(25), 35.