含氟聚合物乳液的制备方法及在固液界面的应用

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Abstract The C-F bond has the lowest free energy, and the wettability of solid-liquid interface can be significantly changed by using fluorine-containing compounds, which can achieve a hydrophobic or a super-amphiphobic effect. But due to the low free energy of fluorocarbons, the dispersion of fluorocarbons in the preparation process has become a difficult problem. Especially in the polymerization, the type and cost of monomer materials also hindered the development of this field. In recent years, the development of fluorine industry has promoted the process of fluoropolymer. Abundant fluorinated monomers have made corresponding breakthroughs in the research of fluoropolymers. In the preparation of fluoropolymer emulsion, fluorinated acrylic monomers have the most widely use. In the meantime, the diversification of emulsifier and emulsion polymerization mode has also effectively solved the dispersion problem of fluoropolymer in the copolymer system. After the problems solved, scholars have synthesized many fluoropolymer emulsions with different structures and properties.Through the analysis of the preparation and application of a large number of fluoropolymer emulsions, this article summarizes and analyzes the present situation of fluoropolymer emulsion preparation systems, including the polymerization monomers, polymerization methods, emulsification systems and initiating systems. The research progress in this field is summarized and the corresponding thinking is put forward. The structure and properties of fluoropolymers, especially the interaction between fluoropolymers and nanomaterials, are also explored. The aim is to attract more scholars' attention to fluorocarbon interfacial materials. It is expected that it will play a certain theoretical and practical significance in the preparation and application of fluoropolymer emulsions.

Key words： fluoropolymer emulsion emulsion polymerization topological structures coating nanomaterials wettability

Published: 16 July 2021

CLC number:

O632.2

About author:: Lei Liang received his B.S. degree in Chemistry and M.S. degree in Applied Chemistry from Xi'an University of Petroleum in 2014 and 2018. He is currently pur-suing his Ph.D. at the Oil & Gas Field Development in China University of Petroleum (East China). He mainly engaged in the development and application of chemical additives in the process of oil and gas development. Yanling Wang received her B.S. degree in Chemistry from Nanjing University in 1991 and received her Ph.D. degree from Shandong University in 2006. From 2007 to 2011, she carried out post-doctoral research in Shengli Petroleum Administration Bureau, Shandong China. In 2006, she came as an introduction of talents to School of Petroleum Engineering, China University of Petro-leum (East China), and engaged in teaching and scientific research. Now she mainly engaged in the development and application of chemical additives in the process of oil and gas development.

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	LIANG Lei
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Cite this article:

LIANG Lei,WANG Yanling,LIU Bin, et al. A Review on the Preparation of Fluoropolymer Emulsion and Its Application in Solid-Liquid Interface[J]. Materials Reports, 2021, 35(Z1): 586-593.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2021/V35/IZ1/586

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