聚膦腈微纳米材料的制备及应用

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Abstract Since the emergence of inorganic nanomaterials, a considerable attention have been attained in various fields due to the unique small size effect, surface effect, enhancement effect and so on by virtue of the small size, large surface area and high surface energy. However, their inherent composition and structure also bring a series of problems. For example, most inorganic nanomaterials cannot be degraded, and it is difficult to disperse in solvents or polymers. Surface functionalization is usually required before use, which increases the production cost. It is a good idea to use polymer micro/nanomaterials instead of inorganic nanomaterials.
Polymer micro/nanomaterials are usually prepared by self-assembly of amphiphilic molecules or polymerization on the template surface. Preparation of amphiphilic molecules is required for the self-assembly method, while the template method requires prefabrication of templates with controllable size and shape, both of which include multistep process. Therefore, it is a challenge to develop a simple strategy for polymer micro/nanoparticles with controlled size under mild conditions. Cyclophosphazene polymers, as a newly developed polymer micro/nanomaterial, can be easily formed by rapid one-step polymerization and simultaneous self-assembly process under certain environmental conditions. The stereoscopic morphology can be adjusted from zero dimensional to two-dimensional according to the composition and reaction conditions. Compared with inorganic nanomaterials, polyphosphazene micro/nanoparticles have attracted more and more attention in the fields of drug controlled release, polymer modification, lithium-ion batteries, reaction catalysis and so on because of their flexibility, multiple functions, adjustable surface characteristics and biocompatibility. In spite of this, novel polyphosphazene micro/nanoparticles with different composition and morphology still need to be further developed. For example, how to further enhance the efficiency of drug controlled release through the introduction of targeted groups or environmentally sensitive groups, how to improve the flame retardant efficiency of materials by introducing other flame retardant elements or inorganic structures, and whether polyphosphazene as a flame retardant additive can be extended to other polymer systems other than epoxy resin. These problems need to be further solved.
In this review the research progress on preparation of polyphosphazene micro/nanomaterials is summarized. The preparation conditions, preparation principles and structural characteristics of different polyphosphazene micro/nanomaterials are introduced in detail, so as to provide refe-rence for the preparation of polyphosphazene micro/nanomaterials with different composition and morphology. The application situation of polyphosphazene micro/nanomaterials in the fields of drug controlled release, flameretardancy of polymers, lithium-ion battery, reaction catalysis and so on are analyzed, and the application prospect is prospected.

Key words： polyphosphazene micro/nanoparticles preparation method controlled release flame retardancy

Published: 16 July 2021

CLC number:

TQ317

Fund:Pearl Scholar Project in Huanggang Normal University.

About author:: Lin Xie received her B.S. degree in College of Chemistry and Chemical Engineering from Huanggang Normal University in 2020 and she is pursuing her M.A. at Hubei University of Technology. She is currently pursuing her research work on flame retardant polymer nanocomposites under the supervision of Prof. Wentao He.Wentao He is currently a full professor in the College of Chemistry and Chemical Engineering at Huanggang Normal University, China. She received her PhD in the College of Chemistry and Molecular Science at Wuhan University, China, in 2010, and then moved to Natio-nal Engineering Research Center for Compounding and Modification of Polymeric Materials as an associate professor and became a full professor in 2015. She was invited to Centre for Future Materials in University of Southern Queensland in Australia to work as a visiting scholar for six months. Her research interests focus on the structure and properties of polymer nanocomposites and flame retardant polymer nanocomposites.

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Cite this article:

XIE Lin,HE Wentao,GAO Jing. Preparation and Application of Polypolyphosphazene Micro/Nanomaterials[J]. Materials Reports, 2021, 35(Z1): 578-585.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2021/V35/IZ1/578

1 张宏伟,李爱元,沈培康.材料导报,2010(13),133.
2 Amin A M, Wang L, Wang J, et al. Designed Monomers and Polymers, 2009, 12(5), 357.
3 Wan C, Huang X. Materials Today Communications, 2017, 11, 38.
4 Zhu L, Zhu Y, Pan Y, et al. Macromolecular Reaction Engineering, 2007, 1, 45.
5 Liu W, Huang X, Wei H, et al. Journal of Materials Chemistry A, 2011, 21, 12964.
6 Chen K, Huang X, Wei H, et al. Materials Letters, 2013, 101, 54.
7 Fu J, Huang X, Zhu Y, et al. Macromolecular Chemistry and Physics, 2008, 209, 1845.
8 Fu J, Chen Z, Xu Q, et al. Carbon, 2011, 49(3), 1033.
9 Zhang S, Zhao X, Li B, et al. Journal of Hazardous Materials, 2016, 314, 95.
10 Wang Y, Mu J, Li L, et al. High Performance Polymers, 2012, 24 (3), 229.
11 Örüm S M, Demircioɡˇlu Y S. Journal of Macromolecular Science, Part A, 2019, 56 (9), 854.
12 Köhler J, Kühl S, Keul H, et al. Journal of Polymer Science Part A: Po-lymer Chemistry, 2014, 52, 527.
13 Zhu L, Xu Y, Yuan W, et al. Advanced Materials, 2006, 18, 2997.
14 张冲,耿晓维,高香迪,等.无机材料学报, 2019, 34(7), 761.
15 Li K Y, Stöver H. Journal of Polymer Science Part A-polymer Chemistry, 1993, 31, 3257.
16 Dar S U, Ali S, Hameed M U, et al. New Journal of Chemistry,2016, 40(10), 8418.
17 Ali S, Zuhra Z, Butler I S, et al. Chemical Engineering Journal, 2017, 315, 448.
18 Zhu Y, Huang X, Li W, et al. Materials Letters, 2008, 62, 1389.
19 Fu J, Wang M, Zhang C, et al. Materials Letters, 2012, 81, 215.
20 Feng Z, Fan G, Wang H, et al. Macromolular Rapid Communnication,2009, 30, 448.
21 Fu J, Huang X, Zhu L, et al. Scripta Materialia, 2008, 58, 1047.
22 Fu J, Huang X, Zhu Y, et al. Applied Surface Science,2009, 255, 5088.
23 Wang X, Wang M, Fu J, et al. Journal of Nanoparticle Research,2013, 15, 1853.
24 Huang X, Wei W, Zhao X, et al. Chemical Communications,2010, 46, 8848.
25 Chen K, Wan C, Wei W, et al. Materials Letters, 2015, 139, 93.
26 Hu Y, Meng L, Niu L, et al. Acs Applied Material Interfaces,2013, 5, 4586.
27 Hu Y, Meng L, Niu L, et al. Langmuir,2013, 29, 9156.
28 Zhang J, Qiu L, Li X, et al. Small 2007, 3 (12), 2081.
29 陈争艳, 颜红侠, 刘天野, 刘超.高分子材料科学与工程, 2015, 31(10), 185.
30 Chen K, Huang X, Tang X, et al. Journal of Macromolecular Science, Part B: Physics, 2012, 51, 269.
31 赵师师, 贺梦, 宋文尧, 张冲, 徐建中, 马海云.高等学校化学学报, 2017, 38(12), 2337.
32 Zhang Z, Han Z, Pan Y T, et al. Chemical Engineering Journal, 2020, 395, 125076.
33 Qiu S, Wang X, Yu B, et al. Journals of Hazardous Materials, 2017, 325, 327.
34 Malkappa K, Ray S S. ACS Omega,2019, 4, 9615.
35 Qiu S, Hu Y, Shi Y, et al. Composites Part A: Applied Science and Manufacturing,2018, 114, 407.
36 Zhou X, Qiu S, Xing W, et al. Acs Applied Materials Interfaces, 2017, 9(34), 29147.
37 Zhang J, Huang X, Wei H, et al. Journal of Solid State Electrochemistry,2012, 16, 101.
38 Gao P, Fu J, Yang J, et al. Physical Chemistry Chemical Physics,2009, 11, 11101.
39 We W, Lu R, Ye W, et al. Langmuir, 2016, 32, 1707.