尿素醇解法制备甘油碳酸酯催化剂的研究进展

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Abstract Glycerol carbonate (GC) is an important new chemical material. It is widely used in gas separation membrane, polyurethane foam, paint, detergent, etc. Using the cheap glycerol and urea as raw materials to prepare GC can effectively solve the touchy by-products of biodiesel. Besides that, the ammonia produced by the reaction can be also used to produce urea with CO₂, and can effectively realize the chemical fixation of CO₂, which is a green, economical and environmental friendly reaction process. In this paper, the catalysts for the preparation of glycerol carbonate by alcoholysis of urea was reviewed systematically. The relevant catalysts were summarized into zinc based catalysts, magnesium based catalysts, tungsten based catalysts, functionalized ionic liquid catalysts and other catalysts. In addition, the preparation methods, catalytic efficiency and corresponding reaction mechanism were summarized. Hoping to provide references for the researchers toward preparing some novel and high efficient catalysts. Finally, the development of urea alcoholysis process and the preparation of new catalysts were prospected.

Key words： glycerol carbonate glycerol urea carbon dioxide catalysts

Published: 16 July 2021

CLC number:

TQ225.52

Fund:National Natural Science Foundation of China (21666011).

About author:: Kai Wang received his bachelor's degree in June 2019 from Qingdao University of Science and Technology. In October 2020, he was admitted to Kunming University of Science and Technology for a master's degree, focusing on the research of synthesis of organic carbonate and preparation of its catalyst.Dong Feng received his Ph.D. degree in Polymer Science and Engineering from State Key Laboratory of Polymer Materials Engineering of Sichuan University in June 2020. He is currently a lecturer in the Faculty of Chemical Engineering of Kunming University of Science and Technology. He is mainly engaged in the research of processing and application of high performance polymer foam materials and multifunctional foam materials, focusing on the design and preparation of functional polymer composites and structural composites. He has published more than 20 SCI and EI papers as the first or corresponding author, and 3 authorized patents.

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	ZHAO Wenbo

Cite this article:

WANG Kai,FENG Dong,ZHAO Wenbo. Research Progress of Catalysts for Preparation of Glycerol Carbonate by Urea Alcoholysis[J]. Materials Reports, 2021, 35(Z1): 541-547.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2021/V35/IZ1/541

1 Wang A, Li H, Zhang H, et al.Materials, 2019, 12(1), 83.
2 Wu Y, Song X, Zhang J, et al.Journal of the Taiwan Institute of Chemical Engineers, 2018, 87, 131.
3 Demirel Y.International Journal of Chemical Reactor Engineering, 2011, 9(1), 2319.
4 Wang A, Li H, Pan H, et al.Fuel Processing Technology, 2018, 181, 259.
5 Rokicki G, Rakoczy P, Parzuchowski P, et al.Green Chemistry, 2005, 7(7), 529.
6 Hu J, Li J, Gu Y, et al.Applied Catalysis A: General, 2010, 386, 188.
7 George J, Patel Y, Pillai S M, et al.Journal of Molecular Catalysis A: Chemical, 2009, 304(1-2), 1.
8 Vieville C, Yoo J W, Pelet S, et al.Catalysis Letters, 1998, 56, 245.
9 Hu Y, Zhou B, Wang C.Accounts of Chemical Research, 2018, 51(3), 816.
10 Pagliaro M, Ciriminna R, Kimura H, et al.Cheminform, 2007, 46(24), 4434.
11 Sakakura T, Choi J C, Yasuda H.Cheminform, 2007, 38(36), 2365.
12 Park J H, Choi J S, Woo S K, et al.Applied Catalysis A General, 2012, 433-434, 35.
13 Turney T W, Patti A, Gates W, et al.Green Chemistry, 2013, 15, 1925.
14 Oprescu E E, Stepan E, Rosca P, et al.Revista de Chimie, 2012, 63(6), 621.
15 Fujita S I, Yamanishi Y, Arai M. Journal of Catalysis, 2013, 297, 137.
16 Rubio-Marcos F, Calvino-Casilda V, Bañares M A, et al.Journal of Catalysis, 2010, 275(2), 288.
17 Ryu Y B, Kim J S, Kim K H, et al. Research on Chemical Intermediates, 2016, 42(1), 83.
18 Nguyen-Phu H, Park C Y, Shin E W.Applied Catalysis A: General, 2018, 552, 1.
19 Nguyen-Phu H, Shin E W. Applied Catalysis A: General, 2018, 561, 28.
20 Nguyen-Phu H, Shin E W.Journal of Catalysis, 2019, 373, 147.
21 Manjunathan P, Ravishankar R, Shanbhag G V.ChemCatChem, 2016, 8(3), 631.
22 Lü Y Y, Jiang Y, Zhou Q, et al.Journal of Solid State Chemistry, 2017, 256, 93.
23 Kondawar S E, Potdar A S, Rode C V.RSC Advances, 2015, 5, 16452.
24 Kondawar S E, Mane R B, Vasishta A, et al.Applied Petrochemical Research, 2017, 7(1), 41.
25 Marakatti V S, Halgeri A B. RSC Advances, 2015, 5(19), 14286.
26 Jagadeeswaraiah K, Kumar C R, Prasad P S S, et al.Catalysis Science & Technology, 2014, 4(9), 2969.
27 Martín-González M S, Fernández J F, Rubio-Marcos F, et al. Journal of Applied Physics, 2008, 103(8), 083905.
28 Zhang P, Liu L, Fan M, et al. RSC Advances, 2016, 6(80), 76223.
29 Rubio-Marcos F, Calvino-Casilda V, Bañares M A, et al.ChemCatChem, 2013, 5(6), 1431.
30 Liu X, Zhang H, Chang F, et al.Current Organic Chemistry, 2016, 20(7), 761.
31 Singh D, Ganesh A, Mahajani S.Clean Technologies and Environmental Policy, 2015, 17(4), 1103.
32 Fernandes G P, Yadav G D.Catalysis Today, 2018, 309, 153.
33 Hammond C, Lopez-Sanchez J A, Mohd H A R, et al.Dalton Transactions, 2011, 40(15), 3927.
34 Mohd H A R, He Q, Lopez-Sanchez J A, et al.Catalysis Science & Technology, 2012, 2(9), 1914.
35 Sun Y, Tong X, Wu Z, et al.Energy Technology, 2014, 2(3), 263.
36 Wang D, Zhang X, Cong X, et al.Applied Catalysis A: General, 2018, 555, 36.
37 Lopez T, Bosch P, Ramos E, et al. Langmuir, 1996, 12(1), 189.
38 Yamaguchi T, Wang Y, Komatsu M, et al.Catalysis Surveys from Japan, 2002, 5(2), 81.
39 Montouillout V, Massiot D, Douy A, et al. Journal of the American Ceramic Society, 1999, 82(12), 3299.
40 Yadav G D, Ajgaonkar N P, Varma A.Journal of Catalysis, 2012, 292, 99.
41 Hashmi A S K, Hutchings G J.Angewandte Chemie International Edition, 2006, 45(47), 7896.
42 Porta F, Prati L.Journal of Catalysis, 2004, 224(2), 397.
43 Dimitratos N, Lopez-Sanchez J A, Morgan D, et al. Catalysis Today, 2007, 122(3-4), 317.
44 Jagadeeswaraiah K, Kumar C R, Prasad P S S, et al.Applied Catalysis A: General, 2014, 469, 165.
45 Srinivas M, Raveendra G, Parameswaram G, et al.Journal of Chemical Sciences, 2015, 127(5), 897.
46 Jagadeeswaraiah K, Ramesh Kumar C, Rajashekar A, et al.Catalysis Letters, 2016, 146(3), 692.
47 Narkhede N K, Patel A U. RSC Advances, 2015, 5(65), 52801.
48 Narkhede N, Patel A.Applied Catalysis A: General, 2016, 154.
49 Kumar C R, Jagadeeswaraiah K, Prasad P S S, et al.Chemcatchem, 2012, 4(9), 1360.
50 Srikanth A, Viswanadham B, Kumar V P, et al.Applied Petrochemical Research, 2016, 6(2), 145.
51 Babu M S, Srivani A, Parameswaram G, et al.Catalysis Letters, 2015, 145(9), 1784.
52 Kozhevnikova E F, Derouane E G, Kozhevnikov I V.Chemical Communications, 2002 (11), 1178.
53 Corma A, Martınez A, Martınez C.Journal of Catalysis, 1996, 164, 422.
54 Rao K T V, Prasad P S S, et al.Journal of Molecular Catalysis A: Chemical, 2011, 337(1-2), 17.
55 Kumar C R, Prasad P S S, Lingaiah N. Molecular Catalysis, 2011, 350(1-2), 83.
56 Kim D W, Park M S, Selvaraj M, et al. Research on Chemical Interme-diates, 2011, 37(9), 1305.
57 Kim D W, Kim M J, Roshith K, et al.Korean Journal of Chemical Engineering, 2014, 31(6), 972.
58 Kim D W, Park K A, Kim M J, et al. Applied Catalysis A: General, 2014, 473, 31.
59 Lee S D, Park M S, Kim D W, et al. Catalysis Today, 2014, 232, 127.
60 Chen J, Wang C, Dong B, et al.Chinese Journal of Catalysis, 2015, 36(3), 336.
61 Zhang H, Li H, Pan H, et al.Energy Conversion and Management, 2017, 138, 45.
62 Valkenberg M H, DeCastro C, Hölderich W F.Green Chemistry, 2002, 4(2), 88.
63 Wang L, Ma Y, Wang Y, et al.Catalysis Communications, 2011, 12(15), 1458.
64 Zhang J, He D. Reaction Kinetics, Mechanisms and Catalysis, 2014, 113(2), 375.
65 Luo W, Sun L, Yang Y, et al. Catalysis Science & Technology, 2018, 8(24), 6468.
66 Climent M J, Corma A, Frutos P D, et al.Journal of Catalysis, 2010, 269(1), 140.
67 Aresta M, Dibenedetto A, Nocito F, et al. Journal of Catalysis, 2009, 268(1), 106.
68 Indran V P, Zuhaimi N A S, Deraman M A, et al.RSC Advances, 2014, 4(48), 25257.
69 Zuhaimi N A S, Indran V P, Deraman M A, et al.Applied Catalysis A: General, 2015, 502, 312.
70 Suyatmo R I D, Sulistyo H, Sediawan W B.Jurnal Bahan Alam Terbarukan, 2017, 6(2), 143.
71 Wang D, Zhang X, Liu C, et al.Mechanisms and Catalysis, 2015, 115(2), 597.