壳聚糖膜在渗透汽化中的研究进展

doi:10.11896/cldb.19120117

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Abstract Pervaporation membranes were extensively applied in many fields such as food, medicine, agriculture, and chemical industry as an energy efficient alternative and economy technology of separating liquid mixtures. However, most membranes suffer from the drawback of separation performance, thermal stability, acid and alkaline resistance and environmental protection in aqueous solution. Chitosan is one of the most promi-sing pervaporation membrane materials, that exhibits excellent separation performance due to its strong hydrophilicity and easy modification, good stability, wide sources and biodegradability.
However, pure chitosan membranes usually show low separation selectivity due to high swelling which limits the performance of these membranes in PV separations. To enhance the membrane performance, chitosan needs modification to get good mechanical property and achieve better selectivity towards water. Grafting, crosslinked, blending with other polymers and filling with inorganic chemicals are easy methods to adjust the structure and properties of chitosan membranes. A convenient and effective approach to improve their mechanical strength is to form a crosslinked network in the membranes. Nevertheless, this approach usually consumes vast amounts of hydrophilic groups and significantly depresses the permeation flux. Compared with pristine chitosan membranes, blended membranes have higher permselectivity and permeation flux, while they suffer more swelling for pervaporation dehydration of organics. The incorporation of a small amount of inorganic particles in the compo-site membranes not only improves the separation characteristics, but also influences the mechanical and thermal properties significantly. Howe-ver, the interface differentiation, between the chitosan and inorganic particles, and the presence of a strong agglomeration tendency of these inorganic particles make it highly critical to fabricate a suitable composite membranes. To make the chitosan membranes have more excellent comprehensive properties, researchers often adopt multiple modification methods at the same time.
This paper introduces the background and separation mechanism of pervaporation and analyzes the film formation mechanism, preparation and application of chitosan membranes. The research and development of chitosan pervaporation membranes was summarized from the perspective of organic/water and organic/organic. Finally, the future development trend was prospected in order to provide a reference for the rapid preparation of new chitosan membranes with high stability and excellent separation performance.

Key words： chitosan pervaporation membrane separation

Published: 19 January 2021

CLC number:

TQ314.1

Fund:This work was financially supported by the National Natural Science Foundation of China (51774078, 51874078, U1702253, U1508217).

About author:: Xiaoqi Liu received her M.S. degree in School of Materials Science and Engineering at Lanzhou University of Technology in 2018. She is currently pursuing her Ph.D. at the School of metallurgy, Northeastern University under the supervision of Prof. Tingan Zhang. Her research has focused on application of polymer composites in hydrometallurgy.
Ting'an Zhang, professor at School of metallurgy, Northeastern University, distinguished professor of “Kunlun scholar” of Qinghai province. His research interests are special metallurgy, metallurgical materials integration, and metallurgical reaction engineering research. He has published 10 textbooks and monographs, published more than 300 academic papers, and declared (authorized) more than 100 national invention patents.

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	LIU Xiaoqi
	ZHANG Ting'an
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	ZHAO Xinxin

Cite this article:

LIU Xiaoqi,ZHANG Ting'an,LIU Yan, et al. Research Progress of Chitosan Membranes in Pervaporation Separation[J]. Materials Reports, 2021, 35(1): 1224-1231.

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http://www.mater-rep.com/EN/10.11896/cldb.19120117 OR http://www.mater-rep.com/EN/Y2021/V35/I1/1224

1 Zhang L, Yu P, Luo Y B. Journal of Membrane Science,2007,306,93.
2 Zhang X, Wang M, Ji C H. Separation and Purification Technology,2018,203,84.
3 Chakrabarty T, Kumar M, Shahi V K. Biopolymers, Intech, UK,2010.
4 Zielińska K, Kujawski W, Chostenko A G. Separation and Purification Technology,2011,83,114.
5 Krishna Rao K S V, Subha M C S, Sairam M, et al. Journal of Applied Polymer Science,2007,103,1918.
6 Kuang S P, Wang Z Z, Liu J, et al. Journal of Hazardous Materials,2013,260,210.
7 Chen X, Yang H, Gu Z Y, et al. Journal of Applied Polymer Science,2001,79(6),1144.
8 Ngah W S W, Fatinathan S. Journal of Environmental Management,2010,91,958.
9 Liu X S. Preparation and Adsorption Properties of Chitosan blend Membranes. Master's Thesis, Dalian University of Technology, China,2008(in Chinese).
刘小帅.壳聚糖共混膜的制备及吸附性能研究.硕士学位论文,大连理工大学,2008.
10 Vatanpour V, Salehi E, Sahebjamee N, et al. Arabian Journal of Chemistry,2020,13(1),1731.
11 Qiu S, Wu L G, Shi G Z, et al. Industrial & Engineering Chemistry Research,2010,49,11667.
12 Zhang W, Pan C Y, Ge Q, et al. Journal of Membrane Science and Research,2017,3,272.
13 Xu D, Loo L S, Wang K. Journal of Polymer Science: Part B: Polymer Physics,2010,48,2185.
14 Li P, Chen H Z, Chung T S. Journal of Membrane Science,2013,434,18.
15 Yave W, Car A, Funari S S, et al. Macromolecules,2010,43,326.
16 Ong Y K, Shi G M, Le N L, et al. Progress in Polymer Science,2016,57,1.
17 Pratiwi M A, Sudrajat R W, Sutanti S, et al. Advanced Materials Research,2015,1123,182.
18 Kangwansupamonkon W, Tiewtrakoonwat W, Supaphol P, et al. Journal of Applied Polymer Science,2014,131(21),8558.
19 Agarwal S, Joachim H. Wendorff J H, et al. Polymer,2008,49,5603.
20 Li L, Yuan B, Liu S W, et al. Journal of Materials Chemistry,2012,22,8585.
21 Biranje S, Madiwale P, Adivarekar R. Journal of Polymer Research,2017,24,1.
22 Chen X. Preparation of Chitosan blend membranes and pervaporation of ethanol aqueous solution. Master's Thesis, Tianjin University, China,2008(in Chinese).
陈雪.壳聚糖膜的制备及渗透蒸发分离乙醇/水体系的研究.硕士学位论文,天津大学,2008.
23 Moulik S, Vani B, Chandrasekhar S S, Chandrasekhara, et al. Carbohydrate Polymers,2018,193,28.
24 Devi D A, Smitha B, Sridhar S, et al. Journal of Membrane Science,2005,262,91.
25 Patil M B, Aminabhavi T M. Separation and Purification Technology,2008,62,128.
26 Zhang Q G, Hu W W, Zhu A M, et al. RSC Advances,2013,3,1855.
27 Premakshi H G, Ramesh K, Kariduraganavar M Y. Chemical Engineering Research and Design,2015,94,32.
28 Ma X H, Xu Z L, Ji C Q, et al. Journal of Applied Polymer Science,2011,120,1017.
29 Liu Y L, Yu C H, Lee K R, et al. Journal of Membrane Science,2007,287,230.
30 Zhang T A, Zhai X J, Zeng M. Application of chitosan in hydrometallurgy and environmental protection, Science Press, China,2016(in Chinese).
张廷安,翟秀静,曾淼.壳聚糖在湿法冶金和环保中的应用,科学出版社,2016.
31 Lin W H. Application of nano silica composite membrane in pervaporation separation. Ph.D. Thesis, Wuhan University, China,2012(in Chinese).
林文海.纳米二氧化硅改性复合膜在渗透汽化分离中的应用.博士学位论文,武汉大学,2012.
32 Huang Y W. Preparation and pervaporation performance for polyphosphazene-based membrane. Ph.D. Thesis, Shanghai Jiao Tong University, China,2009(in Chinese).
黄亚文.基于聚膦腈渗透汽化膜的制备及分离性能研究.博士学位论文,上海交通大学,2009.
33 Shi E. Structure and pervaporation applications of composite silicone rubber(PDMS) membranes. Ph.D. Thesis, Sichun University, China,2007(in Chinese).
石尔.硅橡胶(PDMS)复合膜结构及渗透蒸发应用研究.博士学位论文,四川大学,2007.
34 Li P. Polymer Sciences,2016,2,1.
35 Alshahrani A A, Al-Zoubi H, Nghiem L D, et al. Desalination,2017,418,60.
36 Qian J. Study on preparation and properties of pervaporation membrane. Master's Thesis, Dalian University of Technology, China,2015(in Chinese).
钱江.渗透汽化膜的制备及其性能研究.硕士学位论文,大连理工大学,2015.
37 Sajankumar ji Rao U, Sreenivasulu K, Maruthi Y, et al. International Journal of Scientific and Research Publications,2016,6(6),101.
38 Li B B, Xu Z L, Alsalhy Q F, et al. Desalination,2006,193,171.
39 Zhang W, Yu Z J, Qian Q F, et al. Journal of Membrane Science,2010,348,213.
40 Wang X S, An Q F, Zhao F Y, et al. Cellulose,2014,21,3597.
41 Suhas D P, Aminabhavi T M, Jeong H M, et al. RSC Advances,2015,5,100984.
42 Xing R S, Wu H, Zhao C H, et al. Chemical Engineering & Technology,2016,39(5),969.
43 Yang D, Li J, Jiang Z Y, et al. Chemical Engineering Science,2009,64,3130.
44 Zheng P Y, Ye C C, Wang X S, et al. Journal of Membrane Science,2016,510,220.
45 Zhao C H, Wu H, Li X S, et al. Journal of Membrane Science,2013,429,409.
46 Ma J, Zhang M H, Wu H, et al. Journal of Membrane Science,2010,348,150.
47 Sunitha K, Satyanarayana S V, Sridhar S. Carbohydrate Polymers,2012,87,1569.
48 Xu Z, Liu G Z, Ye H, et al. Journal of Membrane Science,2018,563,625.
49 Nikbakht Fini M, Soroush S, Montazer-Rahmati M M. Membranes,2018,8(4),119.
50 Zuo J, Hua D, Maricar V, et al. Journal of Applied Polymer Science,2018,135(24),45086.
51 Pulyalina A, Polotskaya G, Goikhman M, et al. Scientific Reports,2017,8415,1.
52 Sajjan A M, Premakshi H G, Kariduraganavar M Y. Journal of Industrial and Engineering Chemistry,2015,25,151.
53 Han Y J, Wang K H, Lai J Y, et al. Journal of Membrane Science,2014,463,17.
54 Varghese J G, Kittur A A, Rachipudi P S, et al, Journal of Membrane Science,2010,364,111.
55 Liu Y L, Yu C H, Ma L C, et al. Journal of Membrane Science,2008,311,243.
56 Khan J R, Muhammad S, Ahmed W. Pakistan Journal of Engineering and Applied Science,2015,16,67.
57 Hyder M N, Chen P. Journal of Membrane Science,2009,340,171.
58 Zhang S Y. Study on the Reinforcement of Esterification of N-butyl action and the removal of trace phenol from water by Pervaporation. Ph.D. Thesis, Guangxi University, China,2017(in Chinese).
张时雨.渗透汽化强化乙酸丁酯酯化反应及水中微量苯酚脱除过程研究.博士学位论文,广西大学,2017.
59 Li Q. Application of natural polymer materials in separation of caprolactam-water system by pervaporation membrane. Ph.D. Thesis, Wuhan University, China,2009(in Chinese).
李琴.天然高分子材料在渗透汽化膜分离己内酰胺-水体系中的应用.博士学位论文,武汉大学,2009.
60 Mortaheb H R, Ghaemmaghami F, Mokhtarani B. Chemical Engineering Research & Design,2012,90,409.
61 Liu K, Fang C J, Li Z Q, et al. Journal of Membrane Science,2014,451,24.
62 Lu L Y, Sun H L, Peng F B, et al. Journal of Membrane Science,2006,281,245.
63 Chen J H, Dong X F, He Y S. RSC Advances,2016,6,60765.
64 Zhang X L, Qian L P, Wang H T, et al. Separation and Purification Technology,2008,63,434.
65 Wang L, Han X L, Li J D, et al. Chemical Engineering Journal,2011,171,1035.
66 Han J L, Xu P Y, Zhou K, et al. Journal of Membrane Science,2014,464,72.
67 Billy M, Costa A R D, Lochon P, et al. Journal of Membrane Science,2010,348,389.
68 Teli S B, Calle M, Li N W. Journal of Membrane Science,2011,371,171.
69 Cheng X X, Pan F S, Wang M R, et al. Journal of Membrane Science,2017,541,329.
70 Adewuyi S, Jacob J M, Olaleye O O, et al. Carbohydrate Polymers,2016,151,1235.
71 Thi T, Trang C, Nhung N T, et al. Engineering,2011,3,110.
72 Liu G Z, Shen J, Liu Q, et al. Journal of Membrane Science,2018,548,548.
73 Yuan J, Liao F F, Guo Y N, et al. Progress in Chemistry,2019,31(1),144(in Chinese).
袁静,廖芳芳,郭雅妮,等.化学进展,2019,31(1),144.
74 Lia B B, Xua Z L, Qusay A F, et al. Desalination,2006,193,171.
75 Li T T. Synthesis of chitosan derived materials and their adsorption mec-hanisms for Pb(Ⅱ) and acid orange 7 from aqueous solutions. Ph.D. Thesis, Hunan University, China,2016(in Chinese).
李婷婷,壳聚糖衍生材料制备及其对水中铅和酸性橙7的吸附机理研究.博士学位论文,湖南大学,2016.
76 Dang M Y, Zhang T A, Wang P. Crosslinked chitosan resin, Chemical Industry Press,2009(in Chinese).
党明岩,张廷安,王娉.交联壳聚糖树脂,化学工业出版社,2009.
77 Ju J. Preparation of modified chitosan membranes and pervaporation of ethonal/water solution. Master's Thesis, Guangxi University, China,2012(in Chinese).
居瑾.壳聚糖改性膜的制备及其乙醇/水溶液渗透汽化分离.硕士学位论文,广西大学,2012.