聚酰胺6/碳纳米复合材料的研究进展

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (5512KB)
Export: BibTeX | EndNote (RIS)

Abstract Polyamide 6 (PA6) is an important thermoplastic engineering plastic has been vastly used due to its attractive and excellent comprehensive properties. PA6 macromolecular chain contains carboxyl or amino end groups and has a certain reactivity under a certain strip, and is easily modified. In recent years, with the rapid growth in nanoscience research and its applications, functional nanomaterials are synthesized and applied, to improve the electrical conductivity, thermal conductivity and mechanics, crystallization and rheology of PA6 composites, leading to their wider applications in various fields. Therefore, polyamide-based nanocomposites have become a greatly active field in studies and applications of composite materials. Nanomaterials, especially carbon nanomaterials, are such an important part of today's materials science. Since Iijima discovered carbon nanotubes in 1991, various carbon nanomaterials have attracted increasing attention in the past decades. Carbon nanomaterials, with geometric structure and particle size, are ideal structural reinforcing materials for composites owing to their extraordinary properties, such as excellent mechanical, electrical, thermal, optical, rheological, adsorption, etc. However, carbon nanomaterials have the characteristics of small particle size, large specific surface area and high surface energy. Under van der Waals force, carbon nanomaterials tend to form large aggregates in the polymeric matrix, which leads to the degradation of the composite properties. In order to improve the dispersion of carbon nanomaterials in PA6 matrix and increase their interfacial bonding, appropriate surface modification of carbon nanomaterials must be carried out to reduce the surface energy. At present, the commonly used modification methods include mechanical method, chemical grafting method, ultrasonic dispersion modification and surfactant method, and so on. The recent research progress of PA6/carbon nanocomposites, especially the preparation methods of PA6/carbon nanocomposites represented by carbon black, carbon nanotubes, and graphene, are systematically reviewed, the effects of surface modification and addition amount of carbon nanocomposites on the properties and functions of composites are reviewed. Finally, the problems of large-scale and low-cost industrial pre-paration of PA6/carbon nanocomposites with high electrical conductivity and high thermal conductivity based on achievements are proposed.

Key words： polyamide 6 carbon black carbon nanotube graphene

Published: 08 January 2021

CLC number:

TQ323.6

Fund:This work was financially supported by the National Research Program of China(2016YFB0302800).

About author:: Mengke Wang, received her B.S. degree in enginee-ring from Henan Polytechnic University in 2019. She is currently studying for a master's degree, at Donghua University and China Textile Research Institute under the supervision of Zhicheng Qiu. Her research has focused on the in-situ synthesis and structural properties of fiber-forming polyamide composites. Zhicheng Qiu, Ph.D, senior engineer of China Textile Academy, graduated from Sichuan University in 2011 in Polymer Chemistry and Physics. He is mainly engaged in the synthesis and modification of fiber-forming polymers, especially in the polyester fiber engineering technology. Up till now, 22 scientific papers were published, of which 12 papers were indexed by SCI and 3 papers were indexed by EI. 47 invention patents have been applied, including 22 granted patents in China,2 granted patent in abroad. He was won one the first prize of Chinese Textile Industry Association of Science and Technology Progress Award and one Chinese Patent Excellence Award. He was selected“Young Elite Scientists Sponsorship Program”by China Association for Science and Technology.

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	WANG Mengke
	QIU Zhicheng
	YU Chunxiao

Cite this article:

WANG Mengke,QIU Zhicheng,YU Chunxiao. Research Progress of Polyamide 6/Carbon Nanocomposites[J]. Materials Reports, 2020, 34(Z2): 555-561.

URL:

http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2020/V34/IZ2/555

1 巫晓鑫. 尼龙6和高密度聚乙烯的耐热改性及性能研究. 硕士学位论文,华南理工大学, 2013.
2 徐亮. 阻燃抗静电PA6的研究. 硕士学位论文,浙江工业大学, 2010.
3 黄秀, 刘倩, 江桂斌.分析科学学报, 2019, 35(6), 701.
4 Zhang X, Fan X, Li H, et al. Journal of Materials Chemistry, 2012, 22(45), 24081.
5 Yu J, Gröbner G, Tonpheng B, et al.Elsevier Ltd, 2011, 52(24), 5521.
6 Liu T, Phang I Y, Shen L,et al. Macromolecules, 2007, 40(24), 8812.
7 于思聪. 聚酰胺6/碳纳米管复合材料的制备及性能研究. 硕士学位论文,天津工业大学, 2017.
8 汪灵骥, 尹波, 杨鸣波,等. 塑料工业, 2018, 46(4), 59.
9 Hwang S H, Kin B J, Beak J B, et al. Composites Part B-Engineering, 2016, 100, 220.
10 林丽隽. 水性炭黑色浆的制备及性能研究. 硕士学位论文,华南理工大学, 2012.
11 胡娟. 炭黑填充尼龙6导电复合材料的制备及性能研究. 硕士学位论文,北京化工大学, 2013.
12 宋云华, 范闯, 王成忠,等.中国塑料, 2010, 24(2), 21.
13 廖恩华. 原位聚合法聚酰胺6/改性炭黑纳米复合材料的制备及其性能研究. 硕士学位论文,江西师范大学, 2012.
14 Liu Y, Xu W, Zhu J, et al. Journal of Macromolecular Science Part B-Physics, 2015, 54(4), 469.
15 Cheng H K F, Sahoo N G, Li L, et al. In: Proceedings of The 36th International Matador Conference. Univ Manchester, Manchester, United Kingdom, 2010, pp. 9.
16 邓凌云. 托辊用耐磨尼龙6复合材料的研制. 硕士学位论文,湖南大学,2013.
17 Basavaraj E, Ramaraj B, Lee J H, et al. Materials Chemistry and Phy-sics, 2013, 138(2-3), 658.
18 Koysuren O, Yesil S, Bayram G.Journal of Applied Polymer Science, 2006, 102(3), 2520.
19 赵欢, 曾雨晴, 李聪慧,等.东华大学学报(自然科学版), 2011, 37(6), 667.
20 史青. 功能尼龙6复合材料的制备及性能表征. 硕士学位论文,扬州大学, 2019.
21 Monteiro A O, Cachim P B, Costa P M F J. Diamond and Related Materials, 2014, 44, 11.
22 Meincke O, Kaempfer D, Weickmann H, et al.Polymer, 2003, 45(3), 739.
23 Ma P C, Siddiqui N A, Marom G, et al.Composites Part A-Applied Science and Manufacturing, 2010, 41(10), 1345.
24 陈甜. 多壁碳纳米管增强聚酰胺6与聚酰胺66纤维的制备及性能. 硕士学位论文,天津工业大学, 2018.
25 Ferreira T, Paiva M C, Pontes A J.Journal of Polymer Research, 2013, 20(11), 301.
26 谭丽容,颜婧,茹兰,等.塑料工业, 2011, 39(10), 112.
27 Phang I Y, Ma J H, Shen L, et al. Polymer International, 2006, 55(1), 71.
28 Naffakh M, Marco C, Gomez M A, et al.Journal of Nanoscience and Nanotechnology, 2009, 9(10), 6120.
29 刘海军. 超支化聚酰胺改性碳纳米管的制备及其对PA6性能的影响. 硕士学位论文,天津科技大学, 2015.
30 李娟. 碳纳米管/尼龙6复合材料的结构与性能研究. 硕士学位论文,浙江大学, 2006.
32 Ebbesen T W, Lezec H J, Hiura H, et al.Nature, 1996, 382(6586), 54.
33 郭宝华, 范劲松, 李金美,等.工程塑料应用, 2008(7), 5.
34 李中原, 孙红玲, 刘文涛,等.中国塑料, 2011, 25(9), 29.
35 Yu J C, Tonpheng B, Gröbner G, et al.Elsevier Ltd, 2011, 49(14), 4858.
36 Zhang Z, Cao M, Chen P, et al.Materials & Design, 2019, 177, 107835.
37 王亮, 吴唯, 邹志强,等.高分子材料科学与工程, 2019, 35(3), 42.
38 朱帅甫, 吴海宏, 张显果,等.塑料科技, 2015, 43(8), 28.
39 Sun X, Liu Z, Welsher K, et al.Nano Research, 2008, 1, 203.
40 Dixon D, Lemonine P, Hamilton J, et al.Journal of Thermoplastic Composite Materials,2015, 28(3), 372.
41 Nguyen L, Choi S M, Kim D H, et al. Macromolecular Research,2014, 22(3), 257.
42 陈美龙, 欧宝立, 郭源君,等.材料科学与工艺, 2019, 27(1), 24.
43 Zhang P P, Zhu K Y, Su L Q, et al.Advanced Materials Research, 2013, 621,31.
44 季翔. 氧化石墨烯的表面改性及其对聚酰胺6纤维的增强作用. 硕士学位论文,浙江理工大学, 2019.
45 谢翔. GO改性MCA/高流动性PA6阻燃复合材料的制备、结构及性能. 硕士学位论文,湖南工业大学, 2014.
46 Scaffaro R, Maio A.Composites Part B-Engineering, 2019, 165, 55.
47 文健. 氧化石墨烯/尼龙6复合材料结晶动力学及增韧改性研究. 硕士学位论文,华南理工大学, 2019.
48 Zhang Y, Tan J W, Stormer H L, et al.Nature, 2005, 438, 201.
49 郑丹. 氧化石墨烯/聚酰胺6纳米复合材料的制备和导电性研究. 硕士学位论文,北京化工大学, 2011.
50 Du N, Zhao C, Chen Q, et al. Materials Chemistry and Physics, 2010, 120(1),167.
51 Balandin A A, Ghosh S, Bao W, et al.Nano Letters, 2008,8(1), 902.
52 李顼珩. 三维石墨烯对聚酰胺6复合材料导热与阻燃性能的影响研究. 硕士学位论文,上海大学, 2017.
53 Ding P, Su S, Song N,et al. Carbon, 2014, 66, 576.