CeO2含量对SiO2-B2O3-ZnO-K2O-BaO系彩釉玻璃基料性能的影响

doi:10.11896/cldb.19110131

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Abstract The base materials of SiO₂-B₂O₃-ZnO-K₂O-BaO enameled glass were prepared by melting method. The effects of CeO₂ addition on the phase composition, microstructure, thermal expansion coefficient, characteristic temperature and wettability with soda lime glass were investigated by XRD, SEM, comprehensive thermal analysis and high temperature wetting angle measurement. It was found that when the addition amount of CeO₂ was higher than 3wt%, there would be precipitation of CeO₂ crystal in the samples after tempering at 700 ℃. With the increase of CeO₂ content in the glass matrix, the acid resistance, wettability with soda lime glass and bending strength of the sample increased first and then decreased. When the addition amount of CeO₂ was 1wt%, the wettability between the sample and the soda lime glass was the best, and its wettability angle reached the minimum value of 45.6°. When the addition amount of CeO₂ was 3wt%, the weight loss rate of the sample in the 5wt% dilute sulfuric acid solution reached the minimum value of 2.83 mg/cm², and the acid resistance of the glass was the best. When the addition amount of CeO₂ was 4wt%, the sample had the best bending resistance, and its strength was 75.69 MPa. The results show that the base material with 2wt% CeO₂ has good comprehensive performance and good application prospect.

Key words： CeO₂ enameled glass glass base materials expansion coefficient wetting angle

Published: 02 December 2020

CLC number:

TB332

Fund:This work was financially supported by Hunan Provincial Key Research and Development Program (2017GK2254), State Key Laboratory of Key Materials and Processes for New Electronic Components (FHR-JS-201909003)

About author:: Xiangui Zhangwas admitted to Hunan University in September 2017 to pursue a master's degree.He is mainly engaged in the application research of functional glass materials,focusing on the research of enameled glaze glass base materialsXiaopan Liu is the assistant professor of Hunan University. During the working period,he presided over and participated in 3 national key projects and 4 national-level projects,completed five projects of provincial and ministerial level,six Changsha projects of Science and technology planning as chief experts,and jointly deve-loped more than 20 new material projects with enterprises.He has published one book,more than 50 related scientific research papers,and 5 authorized invention patents.His main research fields are the development of superhard material tools and the preparation of functional glass materials.

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	ZHANG Xiangui
	LIU Xiaopan
	GAO Pengzhao
	LIAO Mingya
	ZHOU Renchen

Cite this article:

ZHANG Xiangui,LIU Xiaopan,GAO Pengzhao, et al. Effect of CeO₂ Content on Properties of SiO₂-B₂O₃-ZnO-K₂O-BaO System Enameled Glass Base Materials[J]. Materials Reports, 2020, 34(22): 22042-22046.

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http://www.mater-rep.com/EN/10.11896/cldb.19110131 OR http://www.mater-rep.com/EN/Y2020/V34/I22/22042

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