相变材料的过冷特性及调控研究进展

doi:10.11896/cldb.19080094

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Abstract Phase change material (PCM) has a wide application prospect in the field of heat storage (cold) due to its large latent heat value, suitable phase transition temperature, and stable properties. However, phase-change materials usually have a phenomenon of supercooling, which affects the release of latent heat when the phase change material stores heat.
The addition of nucleating agents to phase change materials is the mostcommonly used method to reduce the degree of supercooling, at pre-sent. In the past years, researchers in this field have focused on screening nucleating agents with higher efficiency, better stability and lower specific gravity for different phase change materials. In addition, the method of plus disturbance can similarly reduce the supercooling degree of phase change materials, such as mechanical shock, ultrasonic radiation or electric field, which appears earlier and reduced the degree of supercooling. Considering the requirement for additional equipment support, there are few researches and applications at present. Recently, it has been shown that selecting the relevant suitable parameters, such as ultrasonic frequency and electric field, can substantially enhance the supercooling effect of phase change materials.
The microcapsule phase change material initially reduces the degree of supercooling by adding a nucleating agent before encapsulation, along with the side effect of weakening its heat storage capacity. Researchers began to concentrate on controlling the size of the microcapsule and optimizing the structure of the microcapsule shell in recent years, with a useful application prospect, which can decrease the degree of supercooling and maintain the heat storage capacity.
Supercooling characteristics of phase change materialsare introduced in this paper firstly. Then, the effects of cooling rate, shell surface and ambient temperature on the supercooling characteristics are clarified in detail. Following, different methods about reducing the degree of supercooling are allowed analyzing the advantages and disadvantages. Finally, the problems existing in the study of supercooling characteristics of phase change materials are emphasized. It is suggested that further researches are needed in establish a supercooling prediction model,actors affecting supercooling and its mechanism and improved supercooling reduction method.

Key words： phase change phase change material supercooling crystallization nucleating agent thermodynamic properties

Published: 05 November 2020

CLC number:

TB34

Fund:This work was financially supported by the National Natural Science Foundation of China (51976092), the Natural Science Foundation of Zhejiang Province, China (LY17E060001), the Natural Science Foundation of Ningbo, China (2019A610012), Science and Technology Innovation Program for College Students of Zhejiang Province (2018R405042).

About author:: Sixian Zhu received his B.E. degree in vehicle engineering from Nanjing Agricultural University in 2018. He is currently pursuing his MA.Eng. at the Faculty of Maritime and Transportation, Ningbo University. His research has focused on phase change material
Deqiu Zou, received his Ph.D. degree from Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences. He is currently an associate professor in faculty of Maritime and Transportation, Ningbo University. His research interests are phase change material (PCM) and its performance regulation.

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	ZHU Sixian
	ZOU Deqiu
	BAO Jiaming
	HE Ruijun
	WU Jinfei
	ZHANG Guotong

Cite this article:

ZHU Sixian,ZOU Deqiu,BAO Jiaming, et al. Supercooling Characteristics and Its Adjustment of Phase Change Material:
a Review[J]. Materials Reports, 2020, 34(19): 19075-19082.

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http://www.mater-rep.com/EN/10.11896/cldb.19080094 OR http://www.mater-rep.com/EN/Y2020/V34/I19/19075

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