锂离子电池用石墨类负极材料结构调控与表面改性的研究进展

doi:10.11896/cldb.19080114

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Abstract Lithium ion batteries (LIBs), which are new generation of green energy storage and conversion devices, have wide application and huge economic value. The performance of LIBs is determined by many factors with one of them being the type of anode material. Specifically, the microstructure and surface properties of the anode play a significant role in determining the performance for the battery. Among all reported carbon-based anode materials, graphite materials are the most widely used for commercial LIBs. However, the inherent disadvantages of graphite anode materials such as low reversible capacity, poor ion diffusion dynamics and electrolyte compatibility as well as high volume expansion prevent further improvement on the energy density, high current multiplier performance and cycle stability for LIBs.
Therefore, it is desirable to improve the properties of graphite anode materials in order to produce high performance LIBs. Many research efforts have been made to modify the graphite anode through surface coating, chemical modification, element doping and microcrystalline structure optimization. The main methods are: ⅰ. using surface coating to build core-shell construction, and improve the compatibility between anode mate-rials and electrolyte; ⅱ. using chemical modification to control interface chemical properties, enhance the stability of SEI film (electrode/electrolyte interface film) on the surface of negative electrode material; ⅲ. doping other element in materials to adjust the electronic state and electrical conductivity of graphite microcrystalline surface, and strengthen the behavior of lithium-ion's intercalation and deintercalation of anode materials; ⅳ. optimizing microcrystalline structure to build 3D cascade nanometer channels, improve the transmission path of lithium ions, and improve the energy storage capacity and rate capability of anode materials.
In this paper, the current research status and development of graphite anode materials in structural regulation and surface modification are reviewed and the development trend of such anode materials is prospected. This short review is expected to provide some guidance for the development of new carbon-based anode materials, particularly graphite based materials, for high-performance LIBs.

Key words： lithium battery electrode materials graphite anode materials structure regulation surface modification

Published: 14 July 2020

CLC number:	TB34
	TM911

Fund:This work was supported by the National Natural Science Foundation of China (51974110, U1803114), Key Scientific and Technological Project of Henan Province (202102210183), the Fundamental Research Funds for the Universities of Henan Province (NSFRF180313), Young Key Teacher Foundation of Henan Province's Universities (2017GGJS052), the Education Department Science Foundation of Henan Province (19A440002) and the National College Student Innovation and Entrepreneurship Training Program (201910460033, 201810460018).

About author:: Baolin Xing received his Ph.D. degree in mineral processing engineering from the College of Chemistry and Chemical Engineering, Henan Polytechnic University, in December 2011. He is a visiting scholar at University of Newcastle in Australia from September 2014 to September 2015, and study as postdoctoral research at Zhengzhou University from 2017 to 2019. He is currently a professor in Henan Polytechnic University. His research interests include preparation and application of functional carbon materials as well as comprehensive utilization of mineral resources.
Changliang Shi received his Ph.D. degree in mineral processing engineering from the College of Chemistry and Chemical Engineering, Henan Polytechnic University, in June 2013. He is currently an associate professor in Henan Polytechnic University, and studies as postdoctoral researcher in Do-Fluoride Chemical Co., Ltd.His research interests are comprehensive utilization of mineral resources and spent lithium-ion batteries recycling.

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	XING Baolin
	BAO Ti'ao
	LI Xusheng
	SHI Changliang
	GUO Hui
	WANG Zhenshuai
	HOU Lei
	ZHANG Chuanxiang
	YUE Zhihang

Cite this article:

XING Baolin,BAO Ti'ao,LI Xusheng, et al. Research Progress on Structure Regulation and Surface Modification of Graphite Anode Materials for Lithium Ion Batteries[J]. Materials Reports, 2020, 34(15): 15063-15068.

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http://www.mater-rep.com/EN/10.11896/cldb.19080114 OR http://www.mater-rep.com/EN/Y2020/V34/I15/15063

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