尖晶石型金属氧化物的制备及光催化有机污染物降解:综述

doi:10.11896/cldb.19080015

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Abstract Most organic dyes are difficult to be photo-degraded due to their light stability. And organic dyes have been considered as an important source of water pollution now. Therefore, it is imminent to use photocatalytic technology to solve the problem of water pollution. Fortunately, metal spinel oxides semiconductor materials have been demonstrated to be an effective catalyst for the degradation of organic pollutants by using sunlight.
The spinel-type metal oxides have the characteristics of narrow band gap and absorption of visible light, and can generate electrons and holes under the irradiation of light to realize photocatalytic degradation of the organic dyes. How to regulate the photocatalytic performance of metal spinel oxides is the focus of current international and domestic research. Numerous studies have shown that the main factors affecting their catalytic performances include the following three aspects:
i. Preparation method. Various preparation methods, such as heat treatment (including thermal decomposition), hydrothermal-solvent heat, sol-gel, microwave method, self-combustion method, coprecipitation method, solid state synthesis method, electrospinning method, etc. Diffe-rent preparation methods can affect the morphology, surface area, particle size and band gap of the prepared materials, thus affecting the photocatalytic properties of the materials. For example, the surface area of ZnAl₂O₄ prepared by coprecipitation method and microwave-hydrothermal method was 94.4 m²/g and 279.7 m²/g, respectively;the forbidden band width of spinel NiFe₂O₄ prepared by using metal nitrate and metal chloride corresponded to 2.7 eV, 1.6—1.8 eV.
ⅱ.Doping the third metal. For spinel-type metal oxides with a wider band gap, the forbidden band width can be reduced by doping the third me-tal. For example, the doping of metal Mg can reduce the band gap of CoFe₂O₄ from 2.4 eV to 1.8 eV, and the doping of Ce³⁺ reduces the band gap of ZnAl₂O₄ from 3.8 eV to 2.8 eV. The doping of a small amount of Bi makes the band gap of CoFe₂O₄ drops from 1.4 eV to 1.3 eV.
ⅲ.Effective separation of photoinduced electrons and holes. In order to improve the photocatalytic activity of the spinel photocatalyst, it can be realized by doping a conductive material (such as graphene) and a metal oxide with a suitable potential (such as ZnO). The photoinduced electrons and the holes can be effectively separated to reduce the recombination rate of electron-hole pairs and to improve the catalytic activity of the photocatalyst.
There are many kinds of reported spinel-type metal oxides so far. This review classifies spinel-type metal oxides according to their metal acids. The preparation of spinel-type ferrites and aluminates, and the research progress of performance and mechanism of photocatalytic degradation of organic dyes are analyzed and summarized respectively, and the future development direction has also been prospected. It is expected that this review will play an important role in the development of a series of novel spinel photocatalysts with excellent catalytic performances.

Key words： metal spinel oxides photocatalyst organic dyes photocatalytic degrade

Published: 14 July 2020

CLC number:

X511

Fund:This work was financially supported by the National Key Research and Development Program(2018YFB1502103,2018YFB1502105), the National Natural Science Foundation of China (51971068, 51871065, 51671062, 51863005, 51462006, 51801041), Guangxi Collaborative Innovation Centre of Structure and Property for New Energy and Materials (2012GXNSFGA06002), Guangxi Major Science and Technology Special Project (AA17202030-1), Guangxi Bagui Scholar Foundation, and Guangxi Talent Small Highland.

About author:: Yujie Sun is now studying in School of Material Science and Technology, China University of Geosciences (Beijing) as a undergraduate. Under the supervision of Prof. Yuqin Liu. He has completed a project entitled "preparation of diatomite/CaFe₂O₄ and the research of its photocatalytic properties" and applied for an invention patent.
Fen Xu received her B.E. degree in chemistry from Hunan University in 1986 and received her Ph. D. degree in chemistry and physics from the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, in 2005. She learned or researched at Jena University of Germany and National Institute of Advanced Industrial Science and Technology (AIST) of Japan from 1995 to 2001. After that, she went back to China as an associate Prof. of Dalian Institute of Chemical Physics from 2001 to 2008. She was a professor of Liaoning Normal University from 2008 to 2012. Now, she works in Guilin University of Electronic Technology as a professor. Her research interests focus on advanced energy materials with more than 100 SCI papers, 6 authorized patents and 4 provincial awards.
Lixian Sun,Prof. Dr. of School of Material Science and Engineering, Guilin University of Electronic Technology. He is the Guangxi Excellent Bagui Scholar, Guangxi Excellent Expert; Fellow of Royal Society of Chemistry (FRSC); Alexander von Humboldt Fellowship, Germany; NEDO, AIST & ITIT fellow, Japan; 100 Talent Program of the Chinese Academy of Sciences; Excellent Scientist of China; Special Allowance of the State Council; 2014—2018 Cited Scholar of Elsevier in China. He received Ph.D. degree in chemistry from Hunan University in 1994, and worked as Humboldt fellow and guest professor at Jena University of Germany and National Institute of Advanced Industrial Science and Technology (AIST) of Japan, respectively, from 1995 to 2001.Then, he worked as a professor and group leader at Dalian Institute of Chemical Physics from 2001 to 2012; Since 2012,he has worked in Guilin University of Electronic Technology as a Professor, dean and director. He has served as an associate editor of Journal of Thermal Analysis & Calorimetry, editorial board of the Journal of Chemical Thermodynamics, vice chairman of Committee on Energy Storage and Power Battery of China Instruments Functional Materials Society, etc. His main research fields include energy materials, thermodynamics and bio/chemical sensors. He has published more than 400 SCI papers, got 25 authorized invent patents, and won 8 provincial awards.

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Cite this article:

SUN Yujie,LIU Yuqin,XU Fen, et al. Preparation of Metal Spinel Oxides for Photocatalytic Degradation of Organic Pollutants:a Review[J]. Materials Reports, 2020, 34(15): 15021-15032.

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http://www.mater-rep.com/EN/10.11896/cldb.19080015 OR http://www.mater-rep.com/EN/Y2020/V34/I15/15021

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