介孔硅基分子筛吸附去除挥发性有机化合物的研究进展

doi:10.11896/cldb.19070005

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (4565KB)
Export: BibTeX | EndNote (RIS)

Abstract Volatile organic compounds (VOCs) emissions generate severe hazards to the natural environment and human health. As one of the common methods for VOCs treatment, adsorption has drawn extensive concern with its preponderance of low cost, high efficiency, recyclability and reusability. Meanwhile, mesoporous molecular sieves are considered as good candidates for adsorption material due to their distinguished characteristics of highly ordered pore structure, large specific surface area and pore volume as well as ease of functionalization, which has triggered the recent interest of researchers.
Some studies show that as common VOCs adsorbents, M41S, SBA, HMS and other silicon-based materials have excellent adsorption properties. The adsorption performance of mesoporous silicon-based molecular sieves is not only related to the pore structure of materials, but also affected by the macroscopic morphology characteristics of molecular sieves and other factors. For example, the structure improvement of mesoporous molecular sieve by introducing micropores to synthesize micro-mesoporous composite structural materials can not only improve the diffusion effect of adsorption process, but also solve the problem of single structure of molecular sieve pores, which can improve the adsorption performance of materials and enhance their hydrothermal stability. In addition, in terms of the macroscopic morphology of the same molecular sieve, the longer the pore structure is, the more conducive it is to the diffusion and adsorption of VOCs molecules.
On the other hand, water vapor is often contained in VOCs gases in practical industrial activities. Due to its hydrophilic properties, mesoporous silicon molecular sieves have limited in industrial applications. Therefore, in recent years, in addition to researching on the relationship between mesoporous silica molecular sieve absorption ability of VOCs and the structure and morphology of them, the researchers conduct the thorough research on the main environment on the surface of molecular sieves. By the method of grafting and co-condensation and other modified way of molecular sieve, researchers managed to enhance their adsorption performance in wet conditions.
In this paper, recent accomplishments and advances of the adsorption studies on meso-porous molecular sieve used for VOCs removal have been summarized in detail. In the meantime,the influence factors of molecular sieve structure, morphology and surface environment on adsorption performance are introduced, the characteristics of mesoporous molecular sieve with excellent adsorption VOCs capability are summarized, the limitations of adsorption VOCs process are pointed out.Moreover, improvement of adsorption capacity by hydrophobic modification was discussed and the future research work is prospected.

Key words： mesoporous molecular sieve volatile organic compounds adsorption hydrophobicity

Published: 14 July 2020

CLC number:

X51

Fund:This work was supported by the Fundamental Research Funds for the Central Universities (FRF-TP-18-011A3), the Beijing Science and Technology Planning Project (Z181100005418008).

About author:: Ruijie Zhuang graduated from University of Science and Technology Beijing in June 2018 with a bachelor's degree. He is now a graduate student in the School of Energy and Environmental Engineering, University of Science and Technology Beijing. At present, the main research area is the removal of VOCs by silicon-based ordered mesoporous material.
Xiaolong Tang, professor/doctoral supervisor, new century outstanding talents of the ministry of education. Currently, he is the deputy dean of the School of Energy and Environmental Engineering, University of Science and Technology Beijing and the person in charge of the academic echelon of “air pollution control and resource utilization”. He is also a member of the environmental sub-committee of China engineering education certification association and the environmental protection academic committee of China nonferrous metals society. In 2006, he received his doctor's degree from Beijing Institute of Technology (jointly trained by Tsinghua University). For a long time, he has been mainly engaged in the research and development of flue gas desulfurization and denitration technology, resource utilization of industrial waste gas, and environmental functional mate-rials. In recent years, he has presided over more than 10 research projects such as national natural science foundation of China, sub-project of national 863 program, special project of Beijing municipal commission of science and technology “capital blue sky action”, doctoral program fund of ministry of education. Published more than 240 academic papers in domestic and foreign academic journals, including 91 SCI retrieval papers; Published 1 monographs, participated in the compilation of 3 books; more than 50 invention patents have been applied, and 22 have been authorized. He was awarded five provincial and ministerial science and technology awards, 2013 new century outstanding talents of the ministry of education, 2015 Beijing University of Science and Technology May 4th medal and other honorary awards.

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHUANG Ruijie
	YU Qingjun
	TANG Xiaolong
	YI Honghong
	HUANG Yonghai
	ZHANG Yuanyuan
	FENG Yongchao

Cite this article:

ZHUANG Ruijie,YU Qingjun,TANG Xiaolong, et al. Review on Study of Mesoporous Silicon-based Molecular Sieve in the Field of VOCs Adsorption[J]. Materials Reports, 2020, 34(15): 15013-15020.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.19070005 OR http://www.mater-rep.com/EN/Y2020/V34/I15/15013

Lv S C, Ge Y L, Zhao Q, et al.Environmental Chemistry, 2017, 36(7), 1492(in Chinese).吕双春,葛云丽,赵倩,等. 环境化学, 2017, 36(7), 1492.2 Xiong Z H, Qian F, Su R R.Environmental Science and Technology, 2013, 36(S2), 222(in Chinese).熊振华,钱枫,苏荣荣. 环境科学与技术, 2013, 36(S2), 222.3 Zhang X D, Wang Y, Yang Y Q, et al.Journal of Physical Chemistry, 2015, 31(9), 1633(in Chinese).张晓东,王吟,杨一琼,等. 物理化学学报, 2015, 31(9), 1633.4 Hu Q, Li J, Qiao S, et al. Journal of Hazardous Materials, 2009, 164(2-3), 1205.5 Qu M L. Environmental Science and Management, 2012, 37(6), 102(in Chinese).曲茉莉. 环境科学与管理, 2012, 37(6), 102.6 Lu X C, Jiang J C.Biomass Chemical Engineering, 2009, 3(1), 45(in Chinese).卢辛成,蒋剑春.生物质化学工程, 2009, 3(1), 45.7 Zhang X, Gao B, Creamer A E, et al. Journal of Hazardous Materials, 2017, 338, 102.8 Zhao X S, Ma Q, Lu G Q. Energy & Fuels, 1998, 12(6), 1051.9 Lee J W, Shim W G, Moon H. Microporous and Mesoporous Materials, 2004, 73(3), 109.10 Makowski W, Kus＇trowski P. Microporous and Mesoporous Materials, 2007, 102(1-3), 283.11 Li L, Song J, Yao X, et al. Journal of Central South University, 2012, 19(12), 3530.12 Lillo-Ródenas M A, Cazorla-Amorós D, Linares-Solano A. Adsorption, 2011, 17(3), 473.13 Hu Q, Dou B J, Tian H, et al. Microporous and Mesoporous Materials, 2010, 129(1-2), 30.14 Zhang W, Qu Z, Li X, et al. Journal of Environmental Sciences, 2012, 24(3), 520.15 Hung C, Bai H, Karthik M. Separation and Purification Technology, 2009, 64(3), 265.16 Rong W J. Study on adsorption and desorption of ketone waste gas on molecular sieve and resin. Master's Thesis, ZheJiang University of Technology, China, 2014(in Chinese).戎文娟. 酮类有机废气在分子筛和树脂上吸附—脱附性能研究.硕士学位论文,浙江工业大学, 2014.17 Huang H F, Chu X, Lu H F, et al. Journal of Chemical Engineering, 2011, 25(2), 219(in Chinese).黄海凤,褚翔,卢晗锋,等. 高校化学工程学报,2011, 25(2), 219.18 Nien K C, Chang F T, Chang M B. Journal of the Air & Waste Management Association, 2017, 67(12), 1319.19 Manjare S D, Ghoshal A K. Industrial & Engineering Chemistry Research, 2006, 45(19), 6563.20 Sui H, Liu J, He L, et al. Chemical Engineering Science, 2019, 197, 185.21 Li G J. The preparation and modification study of mesoporous MCM-48 molecular sieve and membrane. Master's Thesis,Dalian University of Technology, China, 2017(in Chinese).李桂杰. 介孔MCM-48分子筛及膜的制备与改性研究.硕士学位论文,大连理工大学, 2017.22 Leonowicz M E, Roth W J, Kresge C T, et al. Nature, 1992, 359(6397), 710.23 Zhao D, Feng J, Huo Q, et al. Science, 1998, 279(5350), 548.24 Sun H P. Study on preparation and catalytic oxidation desulfurization performance of mesoporous molecular sieve modified by metals. Master's Thesis, Northeast Petroleum University, China, 2017(in Chinese).孙洪平.金属改性介孔分子筛的制备及其催化氧化脱硫研究.硕士学位论文,东北石油大学, 2017.25 Beck J S, Vartuli J C, Roth W J, et al. Journal of the American Chemical Society, 1992, 114(27), 10834.26 Jiang T S. Studies on synthesis, characterization and catalytic properties of highly stable mesoporous molecular sieves. Ph.D. Thesis, Nanjing University of Science and Technology, China, 2005(in Chinese).姜廷顺. 高稳定性介孔分子筛的合成、表征与催化性能的研究.博士学位论文,南京理工大学, 2005.27 Wang H L. Synthesis and characterization of MCM-41 mesoporous molecular sieves. Master's Thesis, Inner Mongolia University of Science and Technology, China, 2012(in Chinese).王欢龙. MCM-41分子筛的合成及性能的研究.硕士学位论文,内蒙古科技大学, 2012.28 Dai J Q. Synthesis of meso-microporous molecular sieves and their performance of VOCs adsorption.Master's Thesis, South China University of Technology, China, 2017(in Chinese).戴际强. 介微双孔沸石分子筛的合成及其VOCs吸附性能研究.硕士学位论文,华南理工大学, 2017.29 Ryoo R, Kim J M, Ko C H, et al.The Journal of Physical Chemistry, 1996, 100(45), 17718.30 Janus R, Wądrzyk M, Natkański P, et al.Journal of Industrial and Engineering Chemistry, 2019, 71, 465.31 Meng X, Lu D, Tatsumi T.Microporous and Mesoporous Materials, 2007, 105(1-2), 15.32 Qiao N, He C, Zhang X, et al.Journal of Porous Materials, 2018,26(1), 59.33 Zhang W W, Qu Z, Li X Y, et al. Journal of Environmental Sciences, 2012, 24(3), 520.34 Kim S, Ida J, Guliants V V, et al. The Journal of Physical Chemistry B, 2005, 109(13), 6287.35 Luo C. Synthesis, characterizations, structural analysis and catalytic pro-perties of IEZ-MCM-50. Master's Thesis, East China Normal University, 2013(in Chinese).罗琛. 从高结晶度MCM-50构建新型拓扑结构的微孔沸石分子筛及结构解析.硕士学位论文,华东师范大学, 2013.36 Huang T H,Zhao Y J, Tian Z F, et al. Journal of Physical Chemistry, 2014, 30(12), 2307(in Chinese).黄天辉,赵玉娟,田兆福,等.物理化学学报, 2014, 30(12), 2307.37 Wang H, Rong X, Han L, et al. RSC Advances, 2015, 5(8), 5695.38 Huang H F, Chu X, Lu H F, et al.China Environmental Science, 2010, 30(4), 442(in Chinese).黄海凤,褚翔,卢晗锋,等. 中国环境科学, 2010, 30(4), 442.39 Zhou Z H. Research on synthesis of MCM-48/ZSM-5 composite molecular sieve and membrane. Master's Thesis, Dalian University of Technology, China, 2009(in Chinese).周志华. MCM-48/ZSM-5复合分子筛及膜的制备研究.硕士学位论文,大连理工大学,2009.40 Xie Z Y,Xie Q, Li J P,et al. Environmental Chemistry, 2010, 29(6), 1048(in Chinese).谢遵园,谢倩,李军平,等.环境化学, 2010, 29(6), 1048.41 Yan X, Liu F, Gao Y, et al.Petroleum Journal (Petroleum Processing), 2016, 32(6), 1090(in Chinese).闫茜,刘芳,高雅,等.石油学报(石油加工), 2016, 32(6), 1090.42 Liao Y R.Synthesis of hierarchical zeolites and their performance of to-luene adsorption and desorption. Master's Thesis, Zhejiang University, China, 2018(in Chinese).廖苑如. 多级孔分子筛的制备及其对甲苯吸—脱附性能的研究.硕士学位论文,浙江大学, 2018.43 Qin Y, Wang H, Wang Y, et al. Procedia Environmental Sciences, 2013, 18, 366.44 Kubo S, Kosuge K. Langmuir, 2007, 23(23), 11761.45 Kosuge K, Kubo S, Kikukawa N, et al. Langmuir, 2007, 23(6), 3095.46 Jin W Y, Wang Y J, Wang X L,et al. Industrial Catalysis, 2009, 17(11), 12(in Chinese).金炜阳,王月娟,王雪俐,等.工业催化, 2009, 17(11), 12.47 He Y Y. Adsorption and photocatalytic degradation properties of highly hydrophobic molecular sieve supported TiO2 for phthalic ester. Master's Thesis, South China University of Technology,2014(in Chinese).何音韵.强疏水化介孔分子筛负载TiO2对邻苯二甲酸酯的吸附与光催化降解特性.硕士学位论文,华南理工大学,2014.48 Hoffmann F, Cornelius M, Morell J, et al. Angewandte Chemie International Edition, 2006, 45(20), 3216.49 Li H Y, Hua W M, He Q G, et al.Chinese Journal of Inorganic Chemistry, 2007(6), 1093(in Chinese).李惠云,华伟明,何其戈,等.无机化学学报, 2007(6), 1093.50 Dou B, Hu Q, Li J, et al. Journal of Hazardous Materials, 2011, 186(2-3), 1615.51 Batonneau-Gener I, Yonli A, Trouvé A, et al. Separation Science and Technology, 2010, 45(6), 768.52 Janus R, Wądrzyk M, Natkański P, et al. Journal of Industrial and Engineering Chemistry, 2019, 71, 465.53 Liu Y, Lin H, Mou C. Langmuir, 2004, 20(8), 3231.54 Hu Q, Li J J, Hao Z P, et al. Chemical Engineering Journal, 2009, 149(1-3), 281.55 Liu S, Chen J, Peng Y, et al. Chemical Engineering Journal, 2018, 334, 191.56 Liu S, Peng Y, Chen J, et al. Journal of Materials Chemistry A, 2018, 6(28), 13769.