聚合物基水滑石-石墨烯复合阻燃材料的研究进展

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Abstract In recent years, polymer materials have been widely used in civil, industrial and construction fields. However, most of the traditional macromolecule materials are composed of hydrocarbon elements in the process of production and processing, which have potential fire hazards. Therefore, it is necessary to prepared flame retardant polymer in the production process. The common method of preparing flame retardant polymer is introduce flame retardant into polymer materials. Not only to overcome or reduce the flammability of materials, but also reduce the occurrence and spread of fire. Flame retardants are mainly divided into two types: organic and inorganic flame retardants. With the importance of environmental protection, inorganic flame retardants have been widely used in polymer processing to improve the flame retardancy for their less harmfulness, good smoke suppression effect and less pollution.
With the development of science and technology, inorganic nanomaterials have been gradually applied in daily life. Layered double hydroxides (LDH) and graphene have attracted much attention because of unique structure and special properties. LDH is a two-dimensional layered material consisting of interlayer anions and positively charged layers. It has many structural characteristics, such as adjustable variability of metal ions composition, charge density and distribution of main layers, adjustable variability of species and quantity of intercalated anions, and adjustable variability of space in layers. It is used in different fields such as flame retardant, adsorption and catalysis. Graphene is also a two-dimensional layered material. It is the thinnest and hardest nanomaterial known at present. It has excellent properties such as structural stability, superconductivity, super-high strength and excellent toughness. Graphene can be introduced into polymer because its special composition and structure, it can be widely used in flame retardant, electronic information and biomedical research fields. Therefore, two kinds of materials, LDH and graphene, have certain development prospects in the field of flame retardant. In order to further improve the flame retardant properties of polymer, many resear-chers have prepared LDH-rGO composites via different methods and introduced them into polymer system to prepare polymer-based LDH-rGO composites. The results showed that polymer-based LDH-rGO composites not only can improved flame retardant significantly, but also be widely used in batteries, adsorption, catalysis and other fields.
In this paper,we reviewed the basic properties and preparation methods of LDH-rGO and the preparation methods of polymer-based LDH-rGO composites. The application of polymer-based LDH-rGO composites in flame retardant was introduced. Finally, the future development trend of polymer-based LDH-rGO composites was prospected based on the current situation in this field and the previous research foundation of the research group.

Key words： layered double hydroxides-gaphene flame retardancy composite

Published: 25 November 2019

CLC number:	TQ630.4+3
	TQ314.1

Fund:This work was financially supported by the National Natural Science Foundation of China (21838007) and Shaanxi Innovative Talents Promotion Plan-Youth Science and Technology Nova Project (2019KJXX-011).

About author:: Wen An graduated from Baoji University of Arts and Sciences, received her Bachelor of Science Degree in June, 2017. Now She is a master student at the College of Bioresources and Materials Engineering, Shaanxi University of Science and Technology, under the gui-dance of Professor Ma Jianzhong. Her main research interests focus on the synthesis of natural product-based organic-inorganic nanocomposites.
Jianzhong Ma, doctoral supervisor, is now President of Shaanxi University of Science and Technology. He holds the position of Convener of the Light Industry Technology and Engineering Discipline Review Group of the Academic Degrees Committee of the State Council. He also undertakes over 50 items of National Key Research and Development Program, 973 pre-research Program, 863 Program, Key Program of National Natural Science Foundation and other projects. Prof. Ma is awarded several natio-nal prizes, including the first prize for the National Scientific and Technological Progress Award; the second award National Technology Invention Award and Ho Liang Ho Lee Fund Award. His current research interests primarily focus on design and synthesis of water-based polymers, key technologies of organic/inorganic nanocomposites, and technologies and applications of light and textile products. He has published 8 books, applied for 10 PCT international invention patents, authorized more than 80 national invention patents, and 4 utility model patents, as well as over 400 academic papers (more than 200 SCI/EI and 3 ESI high cited).

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Cite this article:

AN Wen,MA Jianzhong,XU Qunna. Research Progress of Polymer-based Hydrotalcite-Graphene Flame RetardantComposites[J]. Materials Reports, 2019, 33(Z2): 604-608.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2019/V33/IZ2/604

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