尖晶石型催化剂的制备及在气态污染物净化中的应用综述

doi:10.11896/cldb.19020144

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Abstract Catalytic purification is one of the main technologies for the purification of gaseous pollutants, which plays an important role in improving and optimizing the quality of human living environment. With the continuous in-depth research of scientific researchers, the development of catalytic materials with high specific surface area, high efficiency, short reactants/product diffusion path and low energy consumption is the key point of current catalytic research.
According to the composition of catalytic materials, general catalysts can be divided into transition metal catalyst, metal oxide catalyst, sulfide catalyst, solid acid catalyst, etc. Traditional metal oxide catalysts are limited by physical and chemical properties such as inherent structure, species of reactive oxygen and less active sites exposed, it is difficult to break through the bottleneck of poor controllability and low catalytic efficiency. Research has shown that spinel metal oxide which made up of special tetrahedral and octahedral structure and composition showing excellent physical and chemical properties such as superconductivity, luminance, catalytic activity due to their controllability of structure, component, phase, valence state, morphology and defects. It occupies an important position in the application fields of dielectric, magnetic, luminescent, catalytic and other functional materials, and is regarded as a new type of highly efficient catalytic purification material for gaseous pollutants with great research and application potential.
Precipitation and hydrothermal methods are the common preparation and synthesis methods for catalyst synthesis. While the traditional synthesis methods are no longer meet the preparation needs of composite catalysts with different morphologies, configurations and multi-component. In order to prepare spinel type catalyst with strong controllability and excellent physicochemical properties, new composite preparation methods such as crystal conducting precipitation, microwave-assisted hydrothermal and self-assembly have attracted extensive attention. Mn, Co, Fe, Cr and other spinel type catalysts have been applied in the removal of gaseous pollutants, among which Mn and Co spinel type catalysts were being widely studied for their high catalytic removal efficiency and stability due to their variable valence and strong redox ability.
This paper summarizes the research progress of spinel catalyst, the structure characteristics of spinel type catalyst and the synthesis mechanism of typical preparation methods are introduced separately, and the development direction of catalytic purification of gaseous pollutants and its prospects are emphatically analyzed. Suggestions for its future theoretical and applied research are given.

Key words： spinel catalyst spatial structure synthesis mechanism catalytic purification gaseous pollutant

Published: 03 January 2020

CLC number:

X511

Fund:This work was financially supported by the National Natural Science Foundation of China (21806009)，China Postdoctoral Fund (2018M631344).

About author:: Wenjuan Zhu graduated from Shandong University of Science and Technology in June 2018 with a bachelor's degree. She is now a graduate student in the School of Energy and Environmental Engineering, University of Science and Technology Beijing. At present, the main research area is the removal of nitrogen oxides by Mn-based catalysts at low temperature;Xiaolong Tang, professor/doctoral supervisor, new century outstanding talents of the Ministry of Education. Currently, he is the deputy dean of the School of Energy and Environmental Engineering, University of Science and Technology Beijing and the person in charge of the academic echelon of “air pollution control and resource utilization”. He is also a member of the environmental sub-committee of China engineering education certification association and the environmental protection academic committee of China nonferrous metals society. In 2006, he received his doctor's degree from Beijing Institute of Technology (jointly trained by Tsinghua University). For a long time, he has been mainly engaged in the research
and development of flue gas desulfurization and denitration technology, resource utilization of industrial waste gas, and environmental functional mate-rials. In recent years, he has presided over more than 10 research projects such as National Natural Science Foundation of China, Sub-project of Natio-nal 863 Program, Special Project of Beijing Municipal Commission of Science and Technology “capital blue sky action”, doctoral program fund of ministry of education. Published more than 240 academic papers in domestic and foreign academic journals, including 91 SCI retrieval papers; Published 1 monographs, participated in the compilation of 3 books; More than 50 invention patents have been applied, and 22 have been authorized. He was awarded five provincial and ministerial science and technology awards, 2013 new century outstanding talents of the ministry of education, 2015 Beijing University of Science and Technology May 4th medal and other honorary awards.

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	ZHU Wenjuan
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	YU Qingjun
	ZHAO Shunzheng

Cite this article:

ZHU Wenjuan,GAO Fengyu,TANG Xiaolong, et al. Spinel Catalysts: Preparation Technology and Applications in Catalytic Purification of Gaseous Pollutants[J]. Materials Reports, 2020, 34(3): 3044-3055.

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http://www.mater-rep.com/EN/10.11896/cldb.19020144 OR http://www.mater-rep.com/EN/Y2020/V34/I3/3044

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