用于CO低温氧化负载型纳米金催化剂研究进展

doi:10.11896/j.issn.1005-023X.2017.01.019

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Abstract The catalytic oxidation of carbon monoxide (CO) at low temperature has attracted considerable attention because of its wide application in industry, environmental protection, military, and many aspects of human life, such as the exhaust abatement for CO₂ lasers, trace CO removal in enclosed atmospheres, automotive emission control, and CO preferential oxidation (PROX) for proton exchange membrane fuel cells (PEMFC). In recent years the nanosized gold catalysts for low-temperature CO oxidation become the study hotspot. The effects of gold particles size, support kinds, preparation method and preparation condition on the catalysts activity is mainly introduced. The research status of the catalytic mechanism and causes for catalyst deactivation are reviewed, and finally brief prospect over the future research directions of this field.

Key words： carbon monoxide nanosized gold catalyst supports catalytic mechnism deactivation

Published: 02 May 2018

CLC number:	TQ426.8
	O643.36

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	Articles by authors
	ZHANG Jingjing
	SUN Jie
	LI Jigang
	ZHOU Tian
	CHEN Liquan

Cite this article:

ZHANG Jingjing,SUN Jie,LI Jigang, et al. Research Progress of Supported Nanosized Gold Catalysts for Low-temperature CO Oxidation[J]. Materials Reports, 2017, 31(1): 136-142.

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http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.01.019 OR http://www.mater-rep.com/EN/Y2017/V31/I1/136

1 Fierro-Gonzalez J C, Gates B C. Catalysis by gold dispersed on supports: The importance of cationic gold[J]. Chem Soc Rev,2008,37:2127.
2 Hutchings G J. Vapor phase hydrochlorination of acetylene: Correlation of catalytic activity of supported metal chloride catalysts[J]. J Catal,1985,96(1):292.
3 Haruta M, Kobayashi T, Sano H, et al. Novel gold catalysis for the oxidation of carbon-monoxide at a temperature ture far below 0 ℃[J]. Chem Lett,1987,2:405.
4 Haruta M, Yamada N, Kobayashi T, et al. Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon-monoxide[J].J Catal,1989,115(2):301.
5 Haruta M, Tsubota S, Kobayashi T, et al. Low-temperature oxidation of CO over gold supported on TiO₂,alpha-Fe₂O₃,and Co₃O₄[J].J Catal,1993,144:175.
6 Zhang F L. Investigation on Au/Fe₂O₃-MO_x catalysts applied in gas purification[J]. Low Temperat Specially Gas, 2013,31(4):41(in Chinese).
张凤利.Au/Fe₂O₃-MO_x催化剂在气体纯化中的应用研究[J].低温与特气,2013,31(4):41.
7 Twigg M V. Progress and future challenges in controlling automotive exhaust gas emissions[J].Appl Catal B-Environ,2007,70(1-4):2.
8 Liu J F, Chen W, Liu X W, et al. Au/LaVO₄ nanocomposite: Pre-paration, characterization, and catalytic activity for CO oxidation[J]. Nano Res,2008,1:46.
9 Souza M M V M, Ribeiro N F P, Schmal M. Influence of the support in selective CO oxidation on Pt catalysts for fuel cell application[J]. Int J Hydrogen Energ,2007,32(3):425.
10 Wang D H, Dong T X, Shi X C, et al. Deactivation mechanism of nanosized gold catalysts stored in ambient air[J]. Chinese J Catal,2007,28(7):657(in Chinese).
王东辉,董同欣,史喜成,等.纳米金催化剂的抗水性能和抗硫中毒性能[J].催化学报,2007,28(7):657.
11 Laoufi I,Saint-Lager M C,Lazzari R,et al.Size and catalytic activity of supported gold nanoparticles:An in operando study during CO oxi-dation[J]. J Phys Chem,2011,115:4673.
12 Tana, Wang F G, Li H J, et al. Influence of Au paricle size on Au/CeO₂ catalysts for CO oxidation[J]. Catal Today,2011,175:541.
13 Sun C W, Li H, Chen L Q. Study of flowerlike CeO₂ microspheres used as catalyst supports for CO oxidation reaction[J]. J Phys Chem Solids,2007,68:1785.
14 Liu X Y, Wang A Q, Zhang T, et al. Au-Cu alloy nanoparticles supported on silica gel as catalyst for CO oxidation: Effects of Au/Cu rations[J].Catal Today,2011,160:103.
15 Chen B B, Zhu X B, Crocker M, et al. FeO_x-supported gold catalysts for catalytic removal of formaldehyde at room temperature[J]. Appl Catal B,2014,154-155:73.
16 Ghosh P, Camellone M F, Fabris S. Fluxionality of Au clusters at ceria surfaces during CO oxidation:Relationships among reactivity, size, cohesion, and surface defects from DFT simulations[J]. J Phys Chem Lett,2013,4:2256.
17 Ho K Y, Yeung K L. Properites of TiO₂ support and the perfor-mance of Au/TiO₂ catalyst for CO oxidation reaction[J].Gold Bull,2007,40(1):15.
18 Aguyet T T M, Chi T Q, Yen Q T H, et al. Preparation, characterization and catalytic activity of gold nanoparticles supported on Co₃O₄[J]. Int J Nanotechnol,2013,10(3-4):334.
19 Zhao K F, Tang H, Qiao B T, et al. Highly activity of Au/γ-Fe₂O₃ for CO oxidation: Effect of support crystal phase in catalyst design[J]. ACS Catal,2015,5:3528.
20 Tabakova T, Dimitrov D, Manzoli M, et al. Impact of metal doping on the activity of Au/CeO₂ catalysts for catalytic abatement of VOCs and CO in waste gases[J].Catal Commun,2013,35:51.
21 Yang K, Huang K, He Z J, et al. Promoted effect of PANI as electron transfer promoter on CO oxidation over Au/TiO₂[J]. Appl Catal B,2014,158-159:250.
22 Liao X M, Chu W, Dai X Y, et al. Promoting effect of Fe in prefe-rential oxidation of carbon monoxide reaction(PROX) on Au/CeO₂[J]. Appl Catal A,2012,449:131.
23 Tabkova T, Avgouropoulos G, Papavasiliou J, et al. CO-free hydrogen production over Au/CeO₂-Fe₂O₃ catalysts:Part 1.Impact of the support compostion on the performance for the preferential CO oxidation reaction[J]. Appl Catal B,2011,101:256.
24 Luengnaruemitchai A, Srihamat K, Pojanavaraphan C, et al. Activity of Au/Fe₂O₃-TiO₂ catalyst for preferential CO oxidation[J]. Int J Hydrogen Energ,2015,40:13443.
25 Li S N, Zhu H Q, Qin Z F, et al. Morphologic effects of nano CeO₂-TiO₂ on the performance of Au/CeO₂-TiO₂ catalysts in low-temperature CO oxidation[J]. Appl Catal B,2014,144:498.
26 Wang L, Guo G S, Gu F B, et al. Preparation of three different sphere-like Au/CeO₂ catalysts and their activity for the CO oxidation[J]. Adv Mater Res,2010,160-162:428.
27 Zhao J B, Fu T, Li L, et al. Synthesis, characterizations and catalytic performance of nanostructure Au/Fe₂O₃[J]. Chinese J Inorg Chem,2014,30(7):1489.
28 Wu H J, Pantaleo G, Venezia A M, et al. Mesoporous silica based gold catalysts:Novel synthesis and application in catalytic oxidaion of CO and volatile organic compounds(VOCs)[J]. Catal,2013,3:774.
29 Yin H F, Ma Z, Zhu H G, et al. Evidence for and mitigation of the encapsulation of gold nanoparticles within silica supports upon high-temperature treatment of Au/SiO₂ catalysts:Implication to catalyst deactivation[J].Appl Cataly A,2010,386:147.
30 Zou X H, Li F, Qi S X, et al. A facile synthetic route for the preparation of the Au/MO_x/Al₂O₃ catalysts towards CO oxidation[J]. React Kinet Catal Lett,2006,88(1):97.
31 Wang C Y, Boucher M, Yang M, et al. ZnO-modified zirconia as gold catalyst support for the low-temperature methanol steam reforming reaction[J]. Appl Catal B,2014,154-155:142.
32 Hao Y, Mihaylov M, Icanova E,et al. CO oxidation catalyzed by gold supported on MgO:Spectroscopic identification of carbonate-like species bonded to gold during catalyst deactivation[J]. J Catal,2009,261:137.
33 Liu X Y, Wang A Q, Zhang T,et al. Catalysis by gold:New insights into the support effect[J].Nano Today,2013,8:403.
34 Ren L H, Zhang H L, Lu A H, et al. Porous silica as supports for controlled fabrication of Au/CeO₂/SiO₂ catalysts for CO oxidation: Influence of the silica nanostructures[J]. Micropor Mesopor Mat,2012,158:7.
35 Wang Z W, Wang X V, Zeng D Y, et al. Enhance catalytic activity for CO oxidation over titania supported gold catalysts that dispersed on SiO₂[J]. Catal Today,2011,160:144.
36 Qi L, Tang C J, Zhang L, et al.Influrence of cerium modification methods on catalytic performance of Au/mordenite catalysts in CO oxidation[J]. Appl Catal B,2012,127:234.
37 Tabakova T, Ilieva L, Ivanov I,et al.Influence of the preparation method and dopants nature on the WGS activity of gold catalysts supported on doped by transition metals ceria[J]. Appl Catal B,2013:136-137:70.
38 Liu W, Feng L J, Zhang C, et al. A facile hydrothermal synthesis of 3D flowerlike CeO₂ via a cerium oxalate precursor[J].J Mater Chem A,2013,1:6942.
39 Horvath A, Beck A, Stefler G, et al. Silica-supported Au nanoparticles decorated by CeO₂:Formation, morphology, and CO oxidation activity[J]. J Phys Chem C,2011,115:20388.
40 高莹,张荣斌.氧化铈制备方法对Au/CeO₂催化剂催化氧化CO反应活性的影响[C]//第十八届全国稀土催化学术会议论文集,2011.
41 Soria M A, Perez P, Carabineiro S A C, et al. Effect of the preparation method on the catalytic activity and stability of Au/Fe₂O₃catalysts in the low-temperature water-gas shift reaction[J].Appl Catal A,2014,470:45.
42 Zhang R B, Yao L J, Zhang N, et al. Acidified bentonite supported gold catalyst for CO oxidation[J].Chinses J Appl Chem,2012,29(8):926(in Chinese).
张荣斌,姚刘晶,张宁,等. 酸化膨润土负载金催化剂用于CO氧化[J].应用化学,2012,29(8):926.
43 Xian C N, Li H, Chen L Q,et al. Morphological and catalytic stabi-lity of mesoporous peony-like ceria[J]. Micropor Mesopor Mat,2010,142(1):202.
44 Del R E, Lopez-Haro M L, Cies J M, et al. Dramtic effect of redox pre-treatments on the CO oxidation activity of Au/Ce_0.5Tb_0.12Zr_0.38-O_2-x catalysts prepared by deposition-precipitation with urea:A nano-nanalytical and nano-strucural study[J]. Chem Commun,2013,49:6722.
45 Collins S E, Cies J M, Rio E D, et al. Hydrogen interaction with a ceria-zirconia supported gold catalyst. Influence of CO co-adsorption and pretreatment condition[J]. J Phys Chem C,2007,111:14371.
46 Li Z X, Shi F B, Li L L, et al. A facile route to orded mesoporous-alumina-supported catalysts,and their catalytic activities for CO oxidation[J]. Phys Chem Chem Phys,2011,33:2488.
47 Sayari S A, Carley A F, Taylor S H, et al. Au/ZnO and Au/Fe₂O₃ catalysts for CO oxidation at ambient temperature:Comments on the effect of synthesis conditions on the preparation of high activity catalysts prepared by copercipitation[J].Top Catal,2007,44(1-2):123.
48 Sakwarathorn T, Luengnaruemitchai A, Pongstabodee S. Preferential CO oxidation in H₂-rich steam over Au/CeO₂ catalysts prepared via modified deposition-precipitaion[J]. J Ind Eng Chem,2011,17:747.
49 Huang J, Xue C J, Wang B F, et al. Gold-supported tin dioxide nanocatalysts for low temperature CO oxidation:Prepareation, cha-racterization and DRIFTS study[J].React Kinet Mech Cat,2013,108:403.
50 Moreau F, Bond G C, Taylor A O. Gold on titania catalysts for the oxidation of carbon monoxide: Control of pH during preparation with various gold contents[J]. J Catal,2005,231:105.
51 Zhang R R, Ren L H, Lu A H, et al. Influence of pretreatment atmospheres on the activity of Au/CeO₂ catalyst for low-temperature CO oxidation[J]. Catal Commun,2011,13:18.
52 Holgado J P, Ternero F, Cruz V M G, et al. Promotional effect of the base metal on bimetallic Au-Ni/CeO₂ catalyst prepared from core-shell nanoparticles[J].ACS Catal,2013,3:2169.
53 Yu K, Wu Z C, Zhao Q R, et al. High-temperature-stable Au@SnO₂ core/shell supported catalyst for CO oxidation[J]. Phys Chem Lett,2008,112:2244.
54 Qi J, Chen J, Li G D, et al. Facile synthesis of core-shell Au@CeO₂ nanocomposites with remarkalby enhanced catalytic activity for CO oxidation[J]. Energ Environ Sci,2012,5:8973.
55 Ma Z, Dai S. Design of novel structured gold nanocatalysts[J]. ACS Catal,2011,1:805.
56 Qu Z P, Ke G Z, Wang Y, et al. Investigation of factors influencing the catalytic performance of CO oxidation over Au-Ag/SBA-15 catalyst[J]. Appl Surf Sci,2013,277:293.
57 Tan W, Deng J G, Xie S H, et al. Ce_0.6Zr_0.3Y_0.1O₂ nanorod supported gold and palladium alloy nanoparticles: High-performance catalysts for toluene oxidation[J]. Nanoscale,2015,7:8510.
58 Li L, Chai S H, Binder A, et al. Synthesis of MCF-supported AuCo nanoparticle catalysts and the catalytic performance for the CO oxidation reaction[J]. RSC Adv,2015,5:100212.
59 Zhang L, Kim H Y, Henkelman G. CO oxiation at the Au-Cu interface of bimetallic nanoclusters supported on CeO₂(111)[J]. Phys Chem Lett,2013,4:2943.
60 Liao X M, Caps V, Chu W, et al. Highly stable bimetallic Au-Cu supported on Al₂O₃ for selective CO oxidation in H₂-rich gas: Effect of Cu/Au atomic ratio and sensitive influence of particle size[J].RSC Adv,2016,6:4899.
61 Wang L C, Jin H J, Widmann D, et al. Dynamic studies of CO oxidation on nanoporous Au using a TAP reactor[J].J Catal,2011,278:219.
62 Kameoka S, An P T. CO oxidation over a fine porous gold catalyst fabricated by selective leaching from an orderd AuCu₃ intermetallic compound[J]. Catal Lett,2008,121(3):337.
63 Xu C X, Su J X, Xu X H, et al. Low temperature CO oxidation over unsupported nanoporous gold[J]. J Am Chem Soc,2007,129:42.
64 Yan T, Redman D W, Yu W Y, et al. CO oxidation on inverse Fe₂O₃/Au(111) model catalysts[J]. J Catal,2012,294:216.
65 Mandal S, Santra C, Bando K K, et al. Aerobic oxidation of benzyl alcohol over mesoporous Mn-doped ceria supported Au nanoparticle catalyst[J]. J Mol Catal A,2013,378:47.
66 Li L, Wang A Q, Qiao B T, et al. Origin of the high activity of Au/FeO_x for low-temperature CO oxidtion:Direact evidence for a redox mechanism[J]. J Catal,2013,299:90.
67 Si R R, Liu J F, Yang K, et al. Temperature-programed surface reaction study of CO oxidation over Au/TiO₂ at low temperature: An insight into nature of the reaction process[J]. J Catal,2014,311:71.
68 Green I X, Tang W, Neurock M, et al. Spectroscopic observation of dual catalytic sites during oxidation of CO on a Au/TiO₂ catalyst[J]. Science,2011,333:736.
69 Remediakis I N, Lopez N, et al. CO oxidation on rutile-supported Au nanoparticles[J]. Angew Chem Int Ed, 2005,44(12):1824.
70 Gong J, et al. Cheminform abstract: Surface science investigation of oxidative chemistry on gold[J]. Chem Inform,2009,41(3):1063.
71 Widmann D, Behm R J. Active oxygen on a Au/TiO₂ catalyst:Formation, stability, and CO oxidation activity[J]. Angew Chem Int Ed,2011,50:10241.
72 Guzman J, et al. Spectroscopic evidence for the supply of reactive oxygen during CO oxidation catalyzed by gold supported on nanocrystalline CeO₂[J]. J Am Chem Soc,2005,127(10):3286.
73 Li M J, Wu Z L, Overbury S H. CO oxidation on phosphate-supported Au catalysts:Effect of support reducibility on surface reaction[J]. J Catal,2011,278:133.
74 Widmann D,Behm R J. Activation of molecular oxygen and the nature of the active oxygen species for CO oxidation on oxide supported Au catalysts[J]. Accounts Chem Res,2014,47(3):740.
75 Min B K, Friend C M. Heterogeneous gold-based catalysis for green chemistry: Low-temperature CO oxidation and propene oxidation[J]. Chem Rev,2007,10:2709.
76 Choudhary T V, Goodman D W. Oxidation catalysis by supported gold nano-clusters[J].Top Catal,2002,21(1):25.
77 Jia M L,Li X, Zhao R G T, et al.Activity and deactivation behavior of Au/LaMnO₃ catalysts for CO oxidation[J]. J Rare Earth,2011,29(3):213.
78 Cardenas L F, Wang X D, Lamey D. An examination of catalyst deactivaton in p-chloronitrobenzene hydrogenation over supported gold[J].Chem Eng J,2014,255:695.
79 Solkina Y S, Reshetnikov S I, Estrada M, et al. Evaluation of gold on alumina catalyst deactivation dynamics during α-pinene isomerization[J]. Chem Eng J,2011,176-177:42.
80 Hernandez J A, Gomez S A, Zepeda T A, et al. Insight into the deactivation of Au/CeO₂ catalysts studied by in situ spectroscopy during the CO-PROX reaction[J]. ACS Catal,2015,5:4003.
81 Rio E D, Collins S E, Aguirre A, et al. Reversible deactivation of a Au/Ce_0.62Zr_0.38O₂ catalyst in CO oxidation: A systematic study of CO₂-triggered carbon inhibition[J]. J Catal,2014,316:210.
82 Sudarsanam P, Mallesham B, Reddy P S. Nano-Au/CeO₂ catalysts for CO oxidation:Influence of dopants (Fe,La and Zr) on the physicochemical properties and catalytic activity[J]. Appl Catal B,2014,144:900.
83 Abian M, Gimenez L J, Bilbao R, et al. Effect of different concentration levels of CO₂ and H₂O on the oxidation of CO: Experiments and moldeling[J]. P Combus Inst,2011,33:317.
84 Zhang S, Li X S, Chen B B, et al. CO oxidation activity at room temperature over Au/CeO₂ catalysts: Disclosure of induction period and humidity effect[J]. ACS Catal,2014,4:3481.