玻璃微珠和ZrB<sub>2</sub>改性石英酚醛复合材料的耐烧蚀性能

doi:10.11896/cldb.19010181

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Abstract Glass beads and ZrB₂ particles were introduced into SiO₂(f)-Phenolic (S-Ph) heat resistant composite, for the sake of enhancing its erosion resistance and ablative properties. The ablation resistance of the glass beads and ZrB₂ modified S-Ph composite were measured by oxygen-acetylene ablation test, and the effects of glass beads and ZrB₂ particles on the ablation mechanism and ablation resistance of full-density and low-density S-Ph composites were analyzed and compared. As could be seen from the results, adding appropriate amount of ZrB₂ to the low-density S-Ph composites contributed to the formation of a cladding layer on the ablative surface, which was highly protective to the carbide layer and the matrix material, and capable of reducing the linear ablation rate and the mass ablation rate. The formation of cladding layer on the surface was derived from the “pining-effect” produced by ZrO₂in melted silica, as well as the reduced surface energy of melted silica by B₂O₃. The introduction of ZrO₂ particles into the full-density S-Ph composites induced the formation of porous ZrO₂layer in the ablative process, which effectively isolate the carbide layer from the ablative environment. Nevertheless, the ZrO₂ layer did not spread by melting and weakly adhered to the carbide layer, therefore it is apt to peel off in the ablative process.

Key words： glass bead ZrB₂ SiO₂ (f)-Phenolic composites ablation resistance

Published: 28 April 2019

CLC number:

TB332

Fund:This work was financially supported by the National Natural Science Foundation Youth Fund of China (51401024).

About author:: Maoyuan Li, Professor, the Ph.D. candidate in Harbin Engineering University. He is the associate director of Research Center of Materials and Assembly in the Fourth Academy of Aerospace Science and Technology, majoring in the non-metallic materials and RTM processing.

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	LI Maoyuan
	LU Lin
	DAI Zhen
	HONG Yiqiang
	CHEN Weiwei
	ZHANG Yuping
	QIAO Yingjiei

Cite this article:

LI Maoyuan,LU Lin,DAI Zhen, et al. Enhanced Ablation Resistance of Glass Beads and ZrB₂ Modified SiO₂ (f)-Phenolic Composites[J]. Materials Reports, 2019, 33(8): 1302-1306.

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http://www.mater-rep.com/EN/10.11896/cldb.19010181 OR http://www.mater-rep.com/EN/Y2019/V33/I8/1302

1 Liu S Q, Ning P S, Ding Z M. Thermosetting Resin, 2016, 31(5), 64(in Chinese).
刘世强, 宁培森, 丁著明.热固性树脂, 2016, 31(5), 64.
2 Ma C, Ma Z, Gao L H, et al. Chinese Optics, 2017, 10(2), 249(in Chinese).
马琛, 马壮, 高丽红, 等.中国光学, 2017, 10(2), 249.
3 Yu Q C, Wang H. Journal of Inorganic Materials, 2012, 27(2), 157(in Chinese).
于庆春, 万红.无机材料学报, 2012, 27(2), 157.
4 Liu D, Wu G M, Kong Z W. Journal of Applied Polymer Science, 2017, 44342, 1.
5 Bu Z Y, Hu J J, Li B G. Thermochimica Acta, 2014, 575(10), 244.
6 Sun C M, Lu D B, Sun Y. Fiber Reinforced Plastics/Composites, 2018(10), 102(in Chinese).
孙超明, 卢东滨, 孙燚. 玻璃钢/复合材料, 2018(10), 102.
7 Bian L P, Xiao J Y, Zeng J C, et al. Materials and Design, 2014, 62, 424.
8 Maria L, Gregori Edson A, Barros Gilberto P, et al. Aerospace Science Technology, 2009, 1(1), 63.
9 Sagar S. Polymer Engineering and Science, 2014, 6, 162.
10 Xiao J, Fan H T, Zhou H T. Surface Technology, 2014, 43(2), 150(in Chinese).
肖军, 樊会涛, 周惠娣.表面技术, 2014, 43(2), 150.
11 Beaudet J, Benoit G, Cormier J, et al. Materials Sciences and Applications, 2011, 2, 1399.
12 Chen L X, Feng J J, Heng J. China patent, CN201510835808.6, 2015(in Chinese).
陈立新, 冯俊君, 衡杰, 中国专利, CN201510835808.6, 2015.
13 Sun Y, Shi L P, Zhou C L, et al. Key Engineering Materials, 2016, 697, 428.
14 Guo Z H, Tian H D, Li H, et al. In:2017 IEEE Conference on Electrical Insulation and Dielectric Phenomenon 2017.
15 Krzyzak A, Kucharczyk W, Gaska J, et al. Composite Structures, 2018, 202(15), 978.
16 Bakar M, Kucharczyk W, Stawarz S. Polymers and Polymer Composites, 2016, 24(8), 617.
17 Bakar M, Kostrzewa M, Bialkowska A, et al. High Performance Polymers, 2014, 26(3), 299.
18 Alagar M, Ashok Kumar A, Mahesh K P O, et al. European Polymer Journal, 2000, 36, 2449.
19 Kucharczyk W, Dusiński D, Zurowski W, et al. Composite Structures, 2018, 183, 654.
20 Lacroix F, Allheily V, Diener K, et al. Composite Structures, 2016, 143, 220.
21 He C, Su H, Lu W, et al. Surface Technology, 2018, 47(5), 167(in Chinese).
贺晨, 苏峘, 卢鹉, 等.表面技术, 2018, 47(5), 167.
22 Park J K, Kang T J. Carbon, 2002, 40, 2125.
23 Hong C Q, Han J C, Zhang X H, et al. Composites Part B:Engineering, 2011, 43, 2389.
24 Abdalla M O, Ludwick A, Mitchell T. Polymer, 2003, 44, 7353.