二维层状材料麦羟硅钠石的研究进展

doi:10.11896/cldb.201905005

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Abstract The two-dimensional layered silicate is a general name of a compound in which silicon, oxygen and other chemical elements are combined. Based on the basic structure of silicon-oxy tetrahedron, diverse silicates are formed according to various combinations. Silicate shows a wide variety, high melting point, large specific surface area, favorable creep resistance, easy for intercalation, and excellent corrosion resistance, thermal stability, chemical stability, which enable its wide application in chemical, building materials, refractories, ceramics, paper, rubber, polymer, plastics, pharmaceuticals, pesticides, textiles, cosmetics, defense and environmental protection industry.
Magadiite is a kind of sodium silicate hydrate, which belongs to layered silicate with the structural formula of Na₂Si₁₄O₂₉·nH₂O. As a novel layered silicate material, magadiite features its active Si-OH located on the interlayers surface, which is more conducive to the functional modification compared with other layered silicate like montmorillonite. In addition, it will significantly increase the interlayer charge density, thus contribute to its ion exchange capacity. Thanks to its regular laminar structure and adjustable interlayer spacing, magadiite can be used as a basic material for the assembly of multifunctional composites by introducing various functional molecules. Magadiite exhibits competitive advantages in market, owing to its favorable biocompatibility, stable structure, thicker monolayer (1.12 nm), moderate price, and the capability for artificial synthesis and generating high purity products with a controlled process.
Up to now, the primary preparation method of magadiite is hydro-thermal synthesis, the possible silicon source include diatomaceous earth, water glass, precipitated silica slurry (PPS), SiO₂-NaOH-Na₂CO₃-H₂O system, silica gel, methyl orthosilicate, tetraethylorthosilicate and so forth. The continuous progress of research has brought about more simplified preparation methods and more perfect crystal structure of products. The modification of magadiite includes organic intercalation, acidification treatment and inorganic modification. Besides, magadiite/polymer composites have also received extensively studied because of the unique structure and morphology of polymer/layered silicate composites differed from conventional polymer composites, and superior mechanical properties, heat resistance, gas-liquid barrier. With regard to the application of magadiite, it can be employed as adsorption material to adsorb heavy metal ions and organic dyes because of its higher ion exchange capacity and large specific surface area. Moreover, due to its layered structure and large specific surface area, magadiite can be used as a silicon source for the synthesis of zeolite molecular sieves, which show high hydrothermal stability and acid resistance. In addition, magadiite possesses excellent chemical stability and strong load capacity, which enable it support catalyst effectively and make the catalyst well dispersed so as to increase the catalytic performance.
In order to present the current research of magadiite at home and abroad, this article introduces the structure and properties, preparation, mo-dification and application of magadiite. While, the current researches on magadiite are not mature enough and exist certain limitations. It is believed that the magadiite own a broad prospect, if it can be applied in production practice in the future.

Key words： magadiite organic intercalation acidification treatment inorganic modification absorption catalytic material

Published: 12 March 2019

CLC number:

TQ177.1

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	GE Mingliang
	XI Zhuangzhuang
	LIANG Guodong

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GE Mingliang,XI Zhuangzhuang,LIANG Guodong. A State-of-the-art Review on the Study of Two-dimensional Layered MaterialMagadiite[J]. Materials Reports, 2019, 33(5): 754-760.

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http://www.mater-rep.com/EN/10.11896/cldb.201905005 OR http://www.mater-rep.com/EN/Y2019/V33/I5/754

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