METALS AND METAL MATRIX COMPOSITES |
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High Temperature Oxidation Resistance Performance of NiCrAlY andNiCoCrAlYHfSi Arc Ion Plating Coating |
DU Wei1,2, SHI Qian2, DAI Mingjiang2, YI Jianhong1, LIN Songsheng2, HOU Huijun2
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1 Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093; 2 National Engineering Laboratory for Modern Materials Surface Engineering Technology, The Key Laboratory ofGuangdong for Modern Surface Engineering Technology, Guangdong Institute of New Materials,Guangzhou 510650 |
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Abstract NiCrAlY and NiCoCrAlYHfSi coatings were deposited on nickel-based superalloy DZ22B by arc ion plating. The microstructure, composition and high temperature oxidation resistance was compared, and the action of active elements in oxidation was discussed. Results show that the as-deposited coatings were mainly composed of γ′-Ni3Al/γ-Ni,β-NiAl, and α-Cr, and the addition of NiCoCr in NiCoCrAlYHfSi. After the heat treatment, the transformation of β-NiAl to γ′-Ni3Al occurred. The average oxidation rates of NiCrAlY and NiCoCrAlYHfSi coatings after 200 h were 0.072 3 g/(m2·h) and 0.052 7 g/(m2·h) at constant tempe-rature of 1 050 ℃. The α-Al2O3,NiCr2O4 and Cr2O3 phase firstly formed at the initial stage of oxidation of NiCrAlY. Cracks, holes and other defects were subsequently observed and the oxide extended to the interior of the coating along those defects. At the same time, TiO2 formed as a result of the diffusion of Ti in substrate. For NiCoCrAlYHfSi oxidation, metastable θ-Al2O3 formed at the initial stage and then transferred to stable α-Al2O3. The oxide layer is more uniform and dense compared to NiCrAlY, thus has better oxidation resistance.
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Published: 01 August 2018
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